Material Safety Data Sheet 1,3-Diaminopropane ACC# 05189 Section 1 - Chemical Product and Company Identification MSDS Name: 1,3-Diaminopropane Catalog Numbers: AC112350000, AC112350010, AC112352500, AC219800000, AC219801000, AC219805000 AC219805000 Synonyms: DAP; alpha,omega-Propanediamine; Trimethylenediamine; 1,3-Propanediamine; TMEDA. Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 For information in North America, call: 800-ACROS-01 For emergencies in the US, call CHEMTREC: 800-424-9300 Section 2 - Composition, Information on Ingredients CAS#Chemical NamePercentEINECS/ELINCS 109-76-21,3-Diaminopropane>99 203-702-7 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: clear, colorless liquid. Flash Point: 24 deg C. Danger! Causes eye and skin burns. Causes digestive and respiratory tract burns. May be fatal if absorbed through the skin. Flammable liquid and vapor. Harmful if swallowed. Hygroscopic (absorbs moisture from the air). Target Organs: Respiratory system, eyes, skin. Potential Health Effects Eye: Causes eye burns. Skin: May be fatal if absorbed through the skin. Causes skin burns. Amines have been known to cause skin irritation/corrosion and allergic skin reaction. Ingestion: Harmful if swallowed. Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Chronic exposure may cause effects similar to those of acute exposure. Section 4 - First Aid Measures Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Get medical aid immediately. Skin: POISON material. In case of contact, get medical aid immediately. Immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Flash Point: 24 deg C ( 75.20 deg F) Autoignition Temperature: 350 deg C ( 662.00 deg F) Explosion Limits, Lower:2.80 vol % Upper: 15.20 vol % NFPA Rating: (estimated) Health: 3; Flammability: 3; Instability: 0 Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapor. Storage: Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Store protected from moisture. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Ventilation fans and other electrical service must be non-sparking and have an explosion-proof design. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Exposure Limits Chemical NameACGIHNIOSHOSHA - Final PELs 1,3-Diaminopropane none listed none listed none listed OSHA Vacated PELs: 1,3-Diaminopropane: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Liquid Appearance: clear, colorless Odor: Amine odor pH: Not available. Vapor Pressure: 11.5 mm Hg @ 25 deg C Vapor Density: 2.6 (air=1) Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: 140 deg C @ 760 mm Hg Freezing/Melting Point:-12 deg C Decomposition Temperature:Not available. Solubility: Soluble. Specific Gravity/Density:0.880 g/cm3 Molecular Formula:C3H10N2 Molecular Weight:74.13 Section 10 - Stability and Reactivity Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Amines absorb carbon dioxide from the air to form carbamate salts. Conditions to Avoid: Ignition sources, excess heat, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents, acids, carbon dioxide, acid anhydrides, acid chlorides. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS#: CAS# 109-76-2: TX6825000 LD50/LC50: CAS# 109-76-2: Draize test, rabbit, eye: 1 mg Severe; Oral, rat: LD50 = 350 uL/kg; Skin, rabbit: LD50 = 200 uL/kg; . Oral, rat: LD50 = 350 uL/kg = 308 mg/kg.; Skin, rabbit: LD50 = 200 uL/kg = 176 mg/kg. Carcinogenicity: CAS# 109-76-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: No information found Teratogenicity: No information found Reproductive Effects: TDLo(Intraperitoneal,mouse) = 264 mg/kg; Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus); Specific Developmental Abnormalities - musculoskeletal system. Mutagenicity: No information found Neurotoxicity: No information found Other Studies: Section 12 - Ecological Information No information available. Section 13 - Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. Section 14 - Transport Information US DOTCanada TDG Shipping Name:AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.AMINES LIQUID CORROSIVE FLAMMABLE (1,3-DIAMINOPROPANE) Hazard Class:88(3) UN Number:UN2734UN2734 Packing Group:IIII Section 15 - Regulatory Information US FEDERAL TSCA CAS# 109-76-2 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs None of the chemicals in this material have an RQ. SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS # 109-76-2: immediate, fire. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 109-76-2 can be found on the following state right to know lists: Pennsylvania, Massachusetts. California Prop 65 California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T C Risk Phrases: R 10 Flammable. R 22 Harmful if swallowed. R 24 Toxic in contact with skin. R 35 Causes severe burns. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 25 Avoid contact with eyes. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 33 Take precautionary measures against static discharges. S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr otection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 9 Keep container in a well-ventilated place. WGK (Water Danger/Protection) CAS# 109-76-2: 2 Canada - DSL/NDSL CAS# 109-76-2 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of B3, D1B, E. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 109-76-2 is listed on the Canadian Ingredient Disclosure List. Section 16 - Additional Information MSDS Creation Date: 4/27/1999 Revision #5 Date: 9/14/2006 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.