1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2  

Division of Facilities Services
DOD Hazardous Material Information (ANSI Format) 
For Cornell University Convenience Only



1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2



      Section 1 - Product and Company Identification Section 9 - Physical & 
      Chemical Properties 
      Section 2 - Compositon/Information on Ingredients Section 10 - Stability & 
      Reactivity Data 
      Section 3 - Hazards Identification Including Emergency Overview Section 11 
      - Toxicological Information 
      Section 4 - First Aid Measures Section 12 - Ecological Information 
      Section 5 - Fire Fighting Measures Section 13 - Disposal Considerations 
      Section 6 - Accidental Release Measures Section 14 - MSDS Transport 
      Information 
      Section 7 - Handling and Storage Section 15 - Regulatory Information 
      Section 8 - Exposure Controls & Personal Protection Section 16 - Other 
      Information 



The information in this document is compiled from information maintained by the 
United States Department of Defense (DOD). Anyone using this information is 
solely reponsible for the accuracy and applicability of this information to a 
particular use or situation. 
Cornell University does not in any way warrant or imply the applicability, 
viability or use of this information to any person or for use in any situation. 


Section 1 - Product and Company Identification 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Product Identification: 1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2
Date of MSDS: 03/24/1989 Technical Review Date: 07/06/1995
FSC: 6850 NIIN: LIIN: 00N014295
Submitter: N EN
Status Code: C
MFN: 01
Article: N
Kit Part: N

Manufacturer's Information
Manufacturer's Name: ALDRICH CHEMICAL CO
Post Office Box: 355
Manufacturer's Address1: 
Manufacturer's Address2: MILWAUKEE, WI 53201
Manufacturer's Country: US
General Information Telephone: 414-273-3850
Emergency Telephone: N/P
Emergency Telephone: N/P
MSDS Preparer's Name: N/P
Proprietary: N
Reviewed: N
Published: Y
CAGE: 60928
Special Project Code: N

Contractor Information
Contractor's Name: ALDRICH CHEMICAL CO INC
Post Office Box: 355
Contractor's Address1: 1001 WEST ST PAUL AVE
Contractor's Address2: MILWAUKEE, WI 53233
Contractor's Telephone: 414-273-3850
Contractor's CAGE: 60928



Section 2 - Compositon/Information on Ingredients 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Ingredient Name: 1,4-DIAZABICYCLO(2,2,2)OCTANE (TRIETHYLENE DIAMINE, 97%)
Ingredient CAS Number: 280-57-9 Ingredient CAS Code: M
RTECS Number: HM0354200 RTECS Code: M
=WT: =WT Code: 
=Volume: =Volume Code: 
>WT: >WT Code: 
>Volume: >Volume Code: 
<WT: <WT Code: 
<Volume: <Volume Code: 
% Low WT: % Low WT Code: 
% High WT: % High WT Code: 
% Low Volume: % Low Volume Code: 
% High Volume: % High Volume Code:
% Text: 97
% Enviromental Weight: 
Other REC Limits: N/K
OSHA PEL: NOT APPLICABLE OSHA PEL Code: M
OSHA STEL: OSHA STEL Code: 
ACGIH TLV: NOT APPLICABLE ACGIH TLV Code: M
ACGIH STEL: N/P ACGIH STEL Code: 
EPA Reporting Quantity: 
DOT Reporting Quantity: 
Ozone Depleting Chemical: N




Section 3 - Hazards Identification, Including Emergency Overview
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Health Hazards Acute & Chronic: ACUTE:HARMFUL IF INGESTED, OR INHALED. MATL IS 
EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS MEMBRANES & UPPER RESP TRACT, EYES AND 
SKIN. INHALATION MAY BE FATAL AS RESULT OF SPASM, INFLAMMATION & EDEMA O F 
LARYNX & BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY EDEMA. 

Signs & Symptoms of Overexposure: 
BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, 
HEADACHE, NAUSEA AND VOMITING. 

Medical Conditions Aggravated by Exposure: 
NONE SPECIFIED BY MANUFACTURER. 

LD50 LC50 Mixture: LD50:(ORL,RAT)1700 MG/KG;(SEE SUPP DATA)

  Route of Entry Indicators: 
  Inhalation: YES 
  Skin: NO 
  Ingestion: NO
  Carcenogenicity Indicators 
  NTP: NO 
  IARC: NO 
  OSHA: NO
Carcinogenicity Explanation: NOT RELEVANT 



Section 4 - First Aid Measures 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


First Aid: 
EYES:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MIN. ASSURE ADEQ 
FLUSHING BY SEPARATING LIDS W/FINGERS. SKIN:IMMED FLUSH W/COPIOUS AMTS OF WATER 
FOR 15 MIN WHILE REMOVING CONTAM CLTHG & SHOES . WASH CONTAM CLTHG BEFORE REUSE. 
INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP),CALL MD. 
INGEST:RINSE MOUTH W/WATER. DO NOT INDUCE VOMIT. DRINK 8-10 OZ OF WATER. CALL MD 
IMMED (FP N). 



Section 5 - Fire Fighting Measures 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Fire Fighting Procedures: 
WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT TO PREVENT CONTACT 
WITH SKIN AND EYES. 
Unusual Fire or Explosion Hazard: 
NOT APPLICABLE 
Extinguishing Media: 
WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM.
Flash Point: Flash Point Text: >122F,>50C

  Autoignition Temperature: 
  Autoignition Temperature Text: N/A 
  Lower Limit(s): N/K 
  Upper Limit(s): N/K


Section 6 - Accidental Release Measures 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Spill Release Procedures: 
WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. SWEEP UP, 
PLACE IN BAG & HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA & 
WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPL ETE. 



Section 7 - Handling and Storage 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Handling and Storage Precautions: 

Other Precautions: 




Section 8 - Exposure Controls & Personal Protection 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Repiratory Protection: 
WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. 
Ventilation: 
USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves: 
CHEMICAL RESISTANT GLOVES.
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE BATH.
Work Hygenic Practices: WASH HANDS THOROUGHLY AFTER USE AND BEFORE EATING, 
DRINKING, SMOKING OR USING SANITARY FACILITIES (FP N).
Supplemental Health & Safety Information: LD50-LC50 MIX:LD50:(ORL,RBT)1100 
MG/KG; LD50:(ORL,GPG)2250 MG/KG. 



Section 9 - Physical & Chemical Properties 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


HCC: C2
NRC/State License Number: 
Net Property Weight for Ammo: 
Boiling Point: Boiling Point Text: N/K
Melting/Freezing Point: Melting/Freezing Text: 316F,158C
Decomposition Point: Decomposition Text: N/K
Vapor Pressure: 2.9 @ 50C Vapor Density: N/K
Percent Volatile Organic Content: 
Specific Gravity: N/K
Volatile Organic Content Pounds per Gallon: 
pH: 12
Volatile Organic Content Grams per Liter: 
Viscosity: N/P
Evaporation Weight and Reference: N/K
Solubility in Water: SOLUBLE
Appearance and Odor: MOIST WHITE CRYSTALLINE POWDER. SHARP, AMMONIA-LIKE ODOR 
(FP N).
Percent Volatiles by Volume: N/K
Corrosion Rate: N/K



Section 10 - Stability & Reactivity Data 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Stability Indicator: YES
Materials to Avoid: 
STRONG OXIDIZING AGENTS, STRONG ACIDS.
Stability Condition to Avoid: 
PROTECT FROM MOISTURE.
Hazardous Decomposition Products: 
TOXIC FUMES OF:CO, CO*2, NO*X.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization: 
NOT RELEVANT



Section 11 - Toxicological Information 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Toxicological Information: 
N/P 



Section 12 - Ecological Information 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Ecological Information: 
N/P 



Section 13 - Disposal Considerations 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Waste Disposal Methods: 
DISSOLVE OR MIX MATERIAL W/COMBUSTIBLE SOLVENT AND BURN IN CHEMICAL INCINERATOR 
EQUIPPED W/AFTERBURNER AND SCRUBBER. DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL 
REGULATIONS. 



Section 14 - MSDS Transport Information 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Transport Information: 
N/P 



Section 15 - Regulatory Information 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


SARA Title III Information: 
N/P 
Federal Regulatory Information: 
N/P 
State Regulatory Information: 
N/P 



Section 16 - Other Information 
1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2 


Other Information: 
N/P 

HMIS Transportation Information 
Product Identification: 1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2
Transporation ID Number: 19525
Responsible Party CAGE: 60928
Date MSDS Prepared: 03/24/1989
Date MSDS Reviewed: 08/12/1991
MFN: 08/12/1991
Submitter: N TN
Status Code: C

  Container Information 
  Unit of Issue: NK 
  Container Quantity: NK 
  Type of Container: 
  Net Unit Weight: 
Article without MSDS: N
Technical Entry NOS Shipping Number: 
Radioactivity: 
Form: 
Net Explosive Weight: 
Coast Guard Ammunition Code: 
Magnetism: N/P
AF MMAC Code: 
DOD Exemption Number: 
Limited Quantity Indicator: 
Multiple Kit Number: 0
Kit Indicator: N
Kit Part Indicator: N
Review Indicator: Y
Additional Data: 



Department of Transportation Information 
DOT Proper Shipping Name: CORROSIVE SOLIDS, N.O.S.
DOT PSN Code: DWZ
Symbols: G
DOT PSN Modifier: 
Hazard Class: 8
UN ID Number: UN1759
DOT Packaging Group: II
Label: CORROSIVE
Special Provision(s): 
Packaging Exception: 154
Non Bulk Packaging: 212
Bulk Packaging: 240
Maximimum Quanity in Passenger Area: 15 KG
Maximimum Quanity in Cargo Area: 50 KG
Stow in Vessel Requirements: A
Requirements Water/Sp/Other: 

IMO Detail Information 
IMO Proper Shipping Name: CORROSIVE SOLID, N.O.S. o
IMO PSN Code: ESJ
IMO PSN Modifier: 
IMDG Page Number: 8151
UN Number: 1759
UN Hazard Class: 8
IMO Packaging Group: I/II/III
Subsidiary Risk Label: -
EMS Number: 8-15
Medical First Aid Guide Number: 760

IATA Detail Information 
IATA Proper Shipping Name: CORROSIVE SOLID, N.O.S. *
IATA PSN Code: HMF
IATA PSN Modifier: 
IATA UN Id Number: 1759
IATA UN Class: 8
Subsidiary Risk Class: 
UN Packaging Group: II
IATA Label: CORROSIVE
Packaging Note for Passengers: 814
Maximum Quantity for Passengers: 15KG
Packaging Note for Cargo: 816
Maximum Quantity for Cargo: 50KG
Exceptions: 

AFI Detail Information 
AFI Proper Shipping Name: CORROSIVE SOLID, N.O.S.
AFI Symbols: *
AFI PSN Code: HMF
AFI PSN Modifier: 
AFI UN Id Number: UN1759
AFI Hazard Class: 8
AFI Packing Group: II
AFI Label: 
Special Provisions: P5
Back Pack Reference: A12.4

HAZCOM Label Information 
Product Identification: 1,4-DIAZABICYCLO(2.2.2)OCTANE,97% D2780-2
CAGE: 60928
Assigned Individual: N
Company Name: ALDRICH CHEMICAL CO INC
Company PO Box: 355
Company Street Address1: 1001 WEST ST PAUL AVE
Company Street Address2: MILWAUKEE, WI 53233 US
Health Emergency Telephone: 
Label Required Indicator: Y
Date Label Reviewed: 06/04/1991
Status Code: C
Manufacturer's Label Number: 
Date of Label: 06/04/1991
Year Procured: N/K
Organization Code: G
Chronic Hazard Indicator: N/P
Eye Protection Indicator: YES
Skin Protection Indicator: YES
Respiratory Protection Indicator: YES
Signal Word: WARNING
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None


8/8/2002 5:56:42 PM