Material Safety Data Sheet 2-Aminobiphenyl, 98% ACC# 02539 Section 1 - Chemical Product and Company Identification MSDS Name: 2-Aminobiphenyl, 98% Catalog Numbers: AC103220000, AC103220050, AC103220250 Synonyms: 2-Phenylaniline; 2-Biphenylamine. Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 For information in North America, call: 800-ACROS-01 For emergencies in the US, call CHEMTREC: 800-424-9300 Section 2 - Composition, Information on Ingredients CAS#Chemical NamePercentEINECS/ELINCS 90-41-52-Aminobiphenyl98 201-990-9 92-67-14-Aminobiphenyl1.6 202-177-1 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: brown crystals. This product contains 4-aminodiphenyl, a cancer-suspect agent. Target Organs: None known. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Laboratory experiments have resulted in mutagenic effects. Possible risk of irreversible effects. Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Flash Point: > 110 deg C (> 230.00 deg F) Autoignition Temperature: 450 deg C ( 842.00 deg F) Explosion Limits, Lower:Not available. Upper: Not available. NFPA Rating: 1 - health, 1 - flammability, 0 - instability Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - Handling and Storage Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. See 29CFR 1910.1003 for specific regulatory requirements applying to areas containing a listed carcinogen, signs, training, reports, and medical surveillance programs. Exposure Limits Chemical NameACGIHNIOSHOSHA - Final PELs 2-Aminobiphenyl none listed none listed none listed 4-Aminobiphenyl Skin - potential significant contribution to overall exposure by the cutaneous r oute none listed (Cancer suspect agent - see 29 CFR 1910.1011) OSHA Vacated PELs: 2-Aminobiphenyl: No OSHA Vacated PELs are listed for this chemical. 4-Aminobiphenyl: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Crystals Appearance: light purple - brown Odor: Not available. pH: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: 299 deg C Freezing/Melting Point:50 - 53 deg C Decomposition Temperature:Not available. Solubility: Slightly soluble. Specific Gravity/Density:Not available. Molecular Formula:C12H11N Molecular Weight:169.23 Section 10 - Stability and Reactivity Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - Toxicological Information RTECS#: CAS# 90-41-5: DU8850000 CAS# 92-67-1: DU8925000 LD50/LC50: CAS# 90-41-5: Oral, rabbit: LD50 = 1020 mg/kg; Oral, rat: LD50 = 2340 mg/kg; . CAS# 92-67-1: Oral, mouse: LD50 = 205 mg/kg; Oral, rabbit: LD50 = 690 mg/kg; Oral, rat: LD50 = 500 mg/kg; . Carcinogenicity: CAS# 90-41-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 92-67-1: ACGIH: A1 - Confirmed Human Carcinogen California: carcinogen, initial date 2/27/87 NTP: Known carcinogen IARC: Group 1 carcinogen Epidemiology: No data available. Teratogenicity: No data available. Reproductive Effects: No data available. Mutagenicity: No data available. Neurotoxicity: No data available. Other Studies: Section 12 - Ecological Information No information available. Section 13 - Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. Section 14 - Transport Information US DOTCanada TDG Shipping Name:Not regulated as a hazardous materialNo information available. Hazard Class: UN Number: Packing Group: Section 15 - Regulatory Information US FEDERAL TSCA CAS# 90-41-5 is listed on the TSCA inventory. CAS# 92-67-1 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs CAS# 92-67-1: 1 lb final RQ; 0.454 kg final RQ SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS # 92-67-1: delayed. Section 313 This material contains 4-Aminobiphenyl (CAS# 92-67-1, 1.6%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Clean Air Act: CAS# 92-67-1 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 90-41-5 can be found on the following state right to know lists: Pennsylvania, Massachusetts. CAS# 92-67-1 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. California Prop 65 WARNING: This product contains 4-Aminobiphenyl, a chemical known to the state of California to cause cancer. California No Significant Risk Level: CAS# 92-67-1: 0.03 ęg/day NSRL European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. R 40 Limited evidence of a carcinogenic effect. R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety Phrases: S 36/37 Wear suitable protective clothing and gloves. S 61 Avoid release to the environment. Refer to special instructions /safety data sheets. WGK (Water Danger/Protection) CAS# 90-41-5: No information available. CAS# 92-67-1: No information available. Canada - DSL/NDSL CAS# 90-41-5 is listed on Canada's NDSL List. CAS# 92-67-1 is listed on Canada's NDSL List. Canada - WHMIS WHMIS: Not available. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 92-67-1 is listed on the Canadian Ingredient Disclosure List. Section 16 - Additional Information MSDS Creation Date: 6/30/2000 Revision #2 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.