SIGMA CHEMICAL COMPANY -- 09530 3-AMINO-1 2 4-TRIAZOLE ======================================================= MSDS Safety Information ======================================================= FSC: 6850 MSDS Date: 07/01/1995 MSDS Num: CHMTK LIIN: 00F056223 Product ID: 09530 3-AMINO-1 2 4-TRIAZOLE MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST Box: 14508 City: SAINT LOUIS MO 63178-5000 Info Phone Number: 314-771-5765/800-325-3010 Emergency Phone Number: 314-771-5765/800-325-3010 Review Ind: Y Published: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST City: ST LOUIS MO 63178 ======================================================= Contractor Summary ======================================================= Cage: 60928 Name: ALDRICH CHEMICAL CO INC Address: 1001 WEST ST PAUL AVE Box: 355 City: MILWAUKEE WI 53233 Phone: 414-273-3850 Cage: 63181 Name: FLUKA CHEMICAL CORP Address: 1001 WEST ST PAUL City: MILWAUKEE WI 53233 Phone: 414-273-3850 Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST City: ST LOUIS MO 63178 Phone: 314-771-5765 ======================================================= Ingredients ======================================================= Cas: 61-82-5 RTECS #: XZ3850000 Name: 3-AMINO-1,2,4-TRIAZOLE, AMINOTRIAZOLE, AMITROLE (SUSPECTED HUMAN CARCINOGEN BY ACGIH, IARC, & NTP) *98-1* OSHA PEL: 0.2 MG/CUM ACGIH TLV: 0.2 MG/CUM EPA Rpt Qty: 10 LBS DOT Rpt Qty: 10 LBS ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50(RAT): 1100 MG/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: HARMFUL IF SWALLOWED, INHALED/ABORBED THROUGH SKIN. CAUSES EYE & SKIN IRRITATION. INHALATION: MATERIAL IS IRRTATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. MAY ALTER GENETIC MATERIAL; EMBRYO/FE TUS. MAY AFFECT THE LIVER & KIDNEYS. MAY CAUSE CANCER Explanation Of Carcinogenicity: SEE INGREDIENTS. Signs And Symptions Of Overexposure: IRRITATION First Aid: EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY. INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN MEDICAL ATTEN TION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: EVACUATE AREA. WEAR SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. WEAR DISPOSABLE COVERALLS & DISCARD THEM AFTER USE. SWEEP UP, PLACE IN A BAG & HOLD FOR WASTE DISPOSAL. VENTILATE AREA & WASH SITE AFTER M ATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISSOLVE/MIX THE MATERIAL W/A COMBUSTIBLE SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER SCRUBBER. DISPOSE OF IAW/LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. KEEP TIGHTLY CLOSED. WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES & EYE/FACE PROTECTION. Other Precautions: DON'T BREATHE DUST. AVOID ALL CONTACT. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY, CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM Fire Fighting Procedures: WEAR SELF CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES. Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves: CHEMICAL RESISTANT Eye Protection: SAFETY GOGGLES Other Protective Equipment: PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH Work Hygienic Practices: REMOVE/DISCARD CONTAMINATED CLOTHING & SHOES. WASH THOROUGHLY AFTER HANDLING. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 302-307.4F Appearance and Odor: OFF-WHITE CHIPS ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG ACIDS, ACID CHLORIDES/ACID ANHYDRIDES, ALUMINUM, COPPER, IRON & IRON SALTS Hazardous Decomposition Products: CO, CO2, NITROGEN OXIDES Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 09530 3-AMINO-1 2 4-TRIAZOLE Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY Street: 3050 SPRUCE ST City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765/800-325-3010 Label Required IND: Y Date Of Label Review: 10/12/1999 Status Code: A Origination Code: G Hazard And Precautions: HARMFUL IF SWALLOWED, INHALED/ABORBED THROUGH SKIN. CAUSES EYE & SKIN IRRITATION. INHALATION: MATERIAL IS IRRTATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. MAY ALTER GENETIC MATERIAL; EMBRYO/FE TUS. MAY AFFECT THE LIVER & KIDNEYS. MAY CAUSE CANCER ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.