Material Safety Data Sheet Acid Solution (Iron Stain) ACC# 88142 Section 1 - Chemical Product and Company Identification MSDS Name: Acid Solution (Iron Stain) Catalog Numbers: 58005A Synonyms: Muriatic acid. Company Identification: Fisher Diagnostics Fisher Scientific Company, LLC 8365 Valley Pike Middletown, VA 22645-0307 For information, call: 800-524-0294 Emergency Number: 800-524-0294 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 Section 2 - Composition, Information on Ingredients CAS#Chemical NamePercentEINECS/ELINCS 7732-18-5Water95 231-791-2 7647-01-0Hydrochloric acid5 231-595-7 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: colorless liquid. Danger! Causes eye and skin burns. Causes digestive and respiratory tract burns. Corrosive to metal. Target Organs: None. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: No information found. Section 4 - First Aid Measures Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately. Do NOT allow victim to rub eyes or keep eyes closed. Skin: Get medical aid immediately. Remove contaminated clothing and shoes. Flush skin with plenty of soap and water. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Get medical aid if irritation or symptoms occur. Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Contact with metals may evolve flammable hydrogen gas. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Do NOT get water inside containers. Flash Point: Not applicable. Autoignition Temperature: Not applicable. Explosion Limits, Lower:Not available. Upper: Not available. NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 0 Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Large spills may be neutralized with dilute alkaline solutions of soda ash (sodium carbonate, Na2CO3), or lime (calcium oxide, CaO). Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Do not get water inside containers. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Discard contaminated shoes. Storage: Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits Chemical NameACGIHNIOSHOSHA - Final PELs Waternone listednone listed none listed Hydrochloric acid2 ppm Ceiling50 ppm IDLH 5 ppm Ceiling; 7 mg/m3 Ceiling OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for this chemical. Hydrochloric acid: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. Section 9 - Physical and Chemical Properties Physical State: Liquid Appearance: colorless Odor: Pungent odor. pH: Not available. Vapor Pressure: 14 mm Hg @ 20 C Vapor Density: 0.7 (Air=1) Evaporation Rate:>1 (Butyl Acetate=1) Viscosity: Not available. Boiling Point: 212 deg F Freezing/Melting Point:Not available. Decomposition Temperature:Not available. Solubility: Complete in water. Specific Gravity/Density:1.0-1.2 (Water=1) Molecular Formula:HCl Molecular Weight:36.46 Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, light, contact with water. Incompatibilities with Other Materials: Alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), amides (e.g. butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates (e.g. carbanolate, carbofuran), caustics (e.g. ammonia, ammonium hydrozide, calcium hydroxide, potassium hydroxide, sodium hydroxide), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g. butyl acetate, ethyl acetate, propyl formate), ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)), fluorides (inorganic, e.g. ammonium fluoride, calcium fluoride, cesium fluoride), halogenated organics (e.g. dibromoethane, hexachlorobenzene, methyl chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (e.g. acetone, acetophenone, MEK, MIBK), mercaptans and other organic sulfides (e.g. butyl mercaptan, carbon disulfide, methanethiol), metals (alkali and alkaline, e.g. cesium, potassium, sodium), metals as powders (e.g. hafnium, raney nickel), metals as non-powders (e.g. brass, bronze, iron), metals and metal compounds (toxic, e.g. beryllium, lead acetate, nickel carbonyl, tetraethyl lead), nitrides (e.g. potassium nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl cyanide), hydrocarbons (aliphatic, unsaturated, e.g. cyclopentene, ethylene, heptene), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), phenols and cresols (e.g. carbolic acid, creosote, cresol, phenol, resorcinol), organophosphates, phosphothioates (e.g. methylparathion, parathion, phorate, thionazin), sulfides (inorganic, e.g. ferric sulfide, lead sulfide, sodium sulfide), epoxides (e.g. butyl glycidyl ether), combustible and flammable materials (e.g.. Hazardous Decomposition Products: Hydrogen chloride, hydrogen gas. Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS#: CAS# 7732-18-5: ZC0110000 CAS# 7647-01-0: MW4025000; MW4031000 LD50/LC50: CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg; CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation, mouse: LC50 = 20487 mg/m3/5M; Inhalation, mouse: LC50 = 3940 mg/m3/30M; Inhalation, mouse: LC50 = 8300 mg/m3/30M; Inhalation, rat: LC50 = 3124 ppm/1H; Inhalation, rat: LC50 = 60938 mg/m3/5M; Inhalation, rat: LC50 = 7004 mg/m3/30M; Inhalation, rat: LC50 = 45000 mg/m3/5M; Inhalation, rat: LC50 = 8300 mg/m3/30M; Oral, rabbit: LD50 = 900 mg/kg; Carcinogenicity: CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 7647-01-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: No data available. Teratogenicity: No data available. Reproductive Effects: No data available. Neurotoxicity: No data available. Mutagenicity: No data available. Other Studies: No data available. Section 12 - Ecological Information No information available. Section 13 - Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. Section 14 - Transport Information US DOTCanada TDG Shipping Name:No information available.No information available. Hazard Class: UN Number: Packing Group: Section 15 - Regulatory Information US FEDERAL TSCA CAS# 7732-18-5 is listed on the TSCA inventory. CAS# 7647-01-0 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. SARA CERCLA Hazardous Substances and corresponding RQs CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ SARA Section 302 Extremely Hazardous Substances CAS# 7647-01-0: 500 lb TPQ SARA Codes CAS # 7647-01-0: acute. Section 313 This material contains Hydrochloric acid (CAS# 7647-01-0, 5%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Clean Air Act: CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: CAS# 7647-01-0 is considered highly hazardous by OSHA. STATE CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 7647-01-0 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 7732-18-5: No information available. CAS# 7647-01-0: 1 Canada - DSL/NDSL CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7647-01-0 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of E. Canadian Ingredient Disclosure List CAS# 7647-01-0 is listed on the Canadian Ingredient Disclosure List. Section 16 - Additional Information MSDS Creation Date: 2/27/1998 Revision #4 Date: 8/06/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.