ALDRICH CHEMICAL SUB OF SIGMA- -- CADMIUM SULFATE HYDRATE, 99% ======================================================= MSDS Safety Information ======================================================= FSC: 6810 MSDS Date: 08/20/1993 MSDS Num: BTBKM LIIN: 00F032955 Product ID: CADMIUM SULFATE HYDRATE, 99% MFN: 01 Responsible Party Cage: 60928 Name: ALDRICH CHEMICAL CO SUB OF SIGMA-ALDRICH Address: 1001 W ST PAUL AVE Box: 355 City: MILWAUKEE WI 53201 Info Phone Number: 414-273-3850/FAX 414-273-4979 Emergency Phone Number: 800-325-5832-S/800-231-8327-A Review Ind: Y Published: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 60928 Name: ALDRICH CHEMICAL CO INC Address: 1001 WEST ST PAUL AVE Box: 355 City: MILWAUKEE WI 53233 ======================================================= Contractor Summary ======================================================= Cage: 60928 Name: ALDRICH CHEMICAL CO INC Address: 1001 WEST ST PAUL AVE Box: 355 City: MILWAUKEE WI 53233 Phone: 414-273-3850 ======================================================= Ingredients ======================================================= Cas: 15244-35-6 Name: CADMIUM SULFATE HYDRATE *93-4* % Wt: 99 ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50 (RAT): 280 MG/KG Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHALATION:HARMFUL IF INHALED. IRRITATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. INGESTION: HARMFUL IF SWALLOWED. CHRONIC EFFECTS: CARCINOGEN. DAMAGES TO THE KIDNEYS, LUNGS Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: INHALATION: NAUSEA, HEADACHE, VOMITING First Aid: EYES/SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. WHILE REMOVING CONTAMINATED CLOTHING & SHOES. INHALATION: REMOVE TO FRESH AIR, IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DI FFICULT, GIVE OXYGEN. INGESTION: WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. OBTAIN MEDIAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. WEAR DISPOSABLE COVERALLS & DISCARD THEM AFTER USE. SWEEP UP, PLACE IN A BAG & HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA & WASH SPILL S ITE AFTER MATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. Handling And Storage Precautions: KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONCOMBUSTIBLE Extinguishing Media: USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures: WEAR SCBA & PROTECTIVE CLOTHING TO PROVENT CONTACT W/SKIN & EYES. Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT Ventilation: CHEMICAL FUME HOOD Protective Gloves: CHEMICAL RESISTANT Eye Protection: SAFETY GOGGLES Other Protective Equipment: PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH, Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 3.090 Appearance and Odor: WHITE CRYSTALLINE POWDER ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: OXIDIZING AGENTS Hazardous Decomposition Products: SULFUR OXIDES Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: CADMIUM SULFATE HYDRATE, 99% Cage: 60928 Company Name: ALDRICH CHEMICAL CO INC Street: 1001 WEST ST PAUL AVE PO Box: 355 City: MILWAUKEE WI Zipcode: 53233 Health Emergency Phone: 800-325-5832-S/800-231-8327-A Label Required IND: Y Date Of Label Review: 02/14/1994 Status Code: C Label Date: 02/14/1994 Origination Code: F Chronic Hazard IND: Y Eye Protection IND: YES Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: INHALATION:HARMFUL IF INHALED. IRRITATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. INGESTION: HARMFUL IF SWALLOWED. CHRONIC EFFECTS: CARCINOGEN. DAMAGES TO THE KIDNEYS, LUNGS. TARGET ORGANS: RES PIRATORY TRACT & DIGESTIVE TRACT, LUNGS, KIDNEYS ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.