ROWLEY BIOCHEMICAL INSTITUTE -- CANADA BALSAM 70% ======================================================= MSDS Safety Information ======================================================= FSC: 6550 NIIN: 00-112-2100 MSDS Date: 03/06/1991 MSDS Num: BNSXN Product ID: CANADA BALSAM 70% MFN: 01 Responsible Party Cage: 2R404 Name: ROWLEY BIOCHEMICAL INSTITUTE Address: ROUTE 1 City: ROWLEY MA 01969 Info Phone Number: 508-948-2067 Emergency Phone Number: 800-424-9300 (CHEMTREC) Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 2R404 Name: ROWLEY BIOCHEMICALS INSTITUTE Address: RT 1 City: ROWLEY MA 01969 Phone: CHEMTREC 800-424-9300 ======================================================= Item Description Information ======================================================= Item Name: CANADA TURPENTINE IN XYLENE Unit of Issue: BT UI Container Qty: 1 Type of Container: BOTTLE ======================================================= Ingredients ======================================================= Cas: 8021-28-1 Name: CANADA BALSAM % Wt: 70 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 1330-20-7 RTECS #: ZE2100000 Name: XYLENES (O-,M-,P- ISOMERS) (SARA III) % Wt: 25.2 Other REC Limits: NONE RECOMMENDED OSHA PEL: 100 PPM/150 STEL ACGIH TLV: 100 PPM/150STEL;9192 EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50 (RAT) IS UNKNOWN Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: IRRITANT! HARMFUL IF INHALED OR SWALLOWED. CONTACT WITH LIQUID MAY BE IRRITATING TO SKIN AND EYES. Explanation Of Carcinogenicity: NONE SPECIFIED BY MANUFACTURER. Signs And Symptions Of Overexposure: EYES: REDNESS, TEARING, DISCOMFORT. SKIN: REDNESS, ITCHING, DISCOMFORT. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INGESTED: DO NOT INDUCE VOMITING! CALL A DOCTOR. SKIN: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES. INHALED: REMOVE PERSON TO FRESH AIR. ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION IF NECESSARY.CALL DOCTOR. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ELIMINATE ALL SOURCES OF IGNITION. WEAR SUITABLE PROTECTIVE GEAR. ABSORB SPILL ON INERT MATERIAL SUCH AS SAND. SCOOP UP AND PLACE IN A SUITABLE CONTAINER FOR DISPOSAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: KEEP TIGHTLY SEALED IN A COOL, DRY PLACE. DO NOT EXPOSE TO TEMPERATURES OVER 95F. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: CALC Flash Point: >27.2C, 81.F Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. USE WATER SPRY TO KEEP FIRE EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard: VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE NORMALLY REQUIRED. IF TLV/PEL EXCEEDED; USE NIOSH/MSHA APPROVED RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS. IF RESPIRATORY PROTECTION IS USED; A PROGRAM IN ACCORDANCE WITH 29 CFR 1910.134 M UST BE IMPLEMENTED. Ventilation: EXPLOSION-PROOF LOCAL OR GENERAL EXHAUST TO MAINTAIN PEL/TLV. Protective Gloves: RUBBER Eye Protection: SAFETY GLASSES/CHEMICAL SPLASH GOGGLES Other Protective Equipment: EYE WASH STATION & SAFETY SHOWER; APPROVED WORK CLOTHES Work Hygienic Practices: WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health: USE CARE WHEN HANDLING. MANUFACTURER MSDS DID NOT GIVE FLASH POINT; HOWEVER TOTAL ITEM RECORD SAYS MATERIAL IS "FLAMMABLE". ALSO CAUTION IN HANDLING/STORAGE SECTION SAYS DO NOT STORE ABOVE 95F INDICAT ES HIGHLY FLAMMABLE LIQUID. ======================================================= Physical/Chemical Properties ======================================================= HCC: F3 Decomp Text: UNKNOWN Appearance and Odor: CLEAR, PALE YELLOW OR GREEN LIQUID; PINE SCENT ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT, SPARKS, SOURCES OF IGNITION. Materials To Avoid: STRONG OXIDIZING AGENTS Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NONE SPECIFIED BY MANUFACTURER. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: ESTIMATED FLASHPOINT ADDED BY DLA(LEVIEN) ON 18-MAY-99.IT IS BASED ON THE LITERATURE FLASHPOINT FOR XYLENE.PER TELECON WITH DEBBIE, ON 11-MAY-99, AT 978-739-4883, INGRED #1, FIR BALSAM CANADA IS A RESINOUS EXUDATE, WHICH HAS BEEN DISSOLVED IN XYLENE(INGRED #2). ======================================================= Transportation Information ======================================================= Responsible Party Cage: 2R404 Trans ID NO: 48192 Product ID: CANADA BALSAM 70% MSDS Prepared Date: 03/06/1991 Review Date: 05/17/1999 MFN: 1 Tech Entry NOS Shipping Nm: CANADA FIR BALSAM IN XYLENE Net Unit Weight: UNKNOWN Limited Quantity IND: Y Multiple KIT Number: 0 Review IND: Y Unit Of Issue: BT Container QTY: 1 Type Of Container: BOTTLE Additional Data: EXEMPTED HAZARDOUS MATERIAL IN SMALL QTY IAW 49CFR173.4,IATA 2.7.5.1,AFJMAN A19.1.LIMITED QTY IAW IM DG 18.3. ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: HIA IMO Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. o IMDG Page Number: 3345 UN Number: 1993 UN Hazard Class: 3.3 IMO Packaging Group: III Subsidiary Risk Label: - EMS Number: 3-07 MED First Aid Guide NUM: T ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: CANADA BALSAM 70% Cage: 2R404 Company Name: ROWLEY BIOCHEMICALS INSTITUTE Street: RT 1 City: ROWLEY MA Zipcode: 01969 Health Emergency Phone: 800-424-9300 (CHEMTREC) Label Required IND: Y Date Of Label Review: 09/11/1992 Status Code: C Label Date: 09/11/1992 Year Procured: 1978 Origination Code: F Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMMABLE MATERIAL. MAY BE POISONOUS IF INHALED OR ABSORBED THROUGH SKIN. VAPORS MAY CAUSE DIZZINESS OR SUFFOCATION. CONTACT MAY IRRITATE OR BURN SKIN AND EYES. FIRE MAY PRODUCE IRRITATING OR POISONOU S GASES. RUNOFF FROM FIRE CONTROL OR DILUTION WATER MAY CAUSE POLLUTION. KEEP TIGHTLY SEALED IN A COOL, DRY PLACE. DO NOT EXPOSE TO TEMPERATURES OVER 95F. FIRST AID: INGESTED: DO NOT INDUCE VOMITING! CALL A DOCTOR. SKIN: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. EYES: FLUSH WITHLOTS OF WATER FOR 15 MINUTES. INHALED: REMOVE PERSON TO FRESH AIR. ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION IF NECESS ARY. CALL DOCTOR. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.