SIGMA CHEMICAL COMPANY -- D2286 DIETHANOLAMINE ACS REAGENT ======================================================= MSDS Safety Information ======================================================= FSC: 6550 MSDS Date: 05/19/1997 MSDS Num: CFGRF LIIN: 00F054184 Product ID: D2286 DIETHANOLAMINE ACS REAGENT MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST Box: 14508 City: SAINT LOUIS MO 63178-5000 Info Phone Number: 314-771-5765/800-325-3010 Emergency Phone Number: 314-771-5765/800-325-3010 Review Ind: Y Published: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST City: ST LOUIS MO 63178 ======================================================= Contractor Summary ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST City: ST LOUIS MO 63178 Phone: 314-771-5765 ======================================================= Ingredients ======================================================= Cas: 111-42-2 RTECS #: KL2975000 Name: DIETHANOLAMINE, DIETHYLOLAMINE, DIOLAMINE, 2,2'-IMINODIETHANOL *97-2* Other REC Limits: 3 PPM ACGIH TLV: 13 MG/CUM EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50(RAT): 620 UL/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: HARMFUL IF INGESTED, INHALED/ABSORBED THROUGH SKIN. INHALATION: EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT & MAY RESULT IN EDEMA OF THE LARYNX & BRONCHI, CHEMICA L PNEUMONITIS & PULMONARY EDEMA. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: SPASM, INFLAMMATION, BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA, VOMITING. First Aid: EYES/SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CAS ES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: EVACUATE AREA. SHUT OFF SOURCES OF IGNITION. WEAR SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. ABSORB ON SAND/VERMICULITE & PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA & WASH SITE AFTER MATER IAL PICKUP IS COMPLETE. Waste Disposal Methods: DISSLOVE/MIX W/A COMBUSTIBLE SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER, IAW/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL DRY PLACE. KEEP TIGHTLY CLOSED. Other Precautions: AVOID PROLONGED/REPEATED EXPOSURE. DON'T GET IN EYES, SKIN/CLOTHING. DON'T BREATHE VAPOR. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 280F Extinguishing Media: CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM. Fire Fighting Procedures: WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: CHEMICAL FUME HOOD Protective Gloves: CHEMICAL RESISTANT Eye Protection: SAFETY GOGGLES Other Protective Equipment: PROTECTIVE CLOTHING, SAFETY SHOWER & EYE BATH. Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 422.6F M.P/F.P Text: 80.6-87.8F Spec Gravity: 1.097 Appearance and Odor: COLORLESS LIQUID W/WHITE SOLID ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: AIR Materials To Avoid: OXIDIZING AGENTS, COPPER, COPPER ALLOYS, ZINC, GALVANIZED IRON, ACID. Hazardous Decomposition Products: THERMAL COMBUSTION: CO, CO2 & NITROGEN OXIDES. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: D2286 DIETHANOLAMINE ACS REAGENT Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY Street: 3050 SPRUCE ST City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765/800-325-3010 Label Required IND: Y Date Of Label Review: 10/12/1999 Status Code: A Origination Code: G Hazard And Precautions: HARMFUL IF INGESTED, INHALED/ABSORBED THROUGH SKIN. INHALATION: EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT & MAY RESULT IN EDEMA OF THE LARYNX & BRONCHI, CHEMICA L PNEUMONITIS & PULMONARY EDEMA. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.