ALDRICH CHEMICAL INC -- DIETHYLENETRIAMINE, 99%, D9385-6 ======================================================= MSDS Safety Information ======================================================= FSC: 6810 MSDS Date: 12/11/1996 MSDS Num: CFLMT LIIN: 00N014342 Product ID: DIETHYLENETRIAMINE, 99%, D9385-6 MFN: 02 Responsible Party Cage: 60928 Name: ALDRICH CHEMICAL CO INC Box: 355 City: MILWAUKEE WI 53201 Info Phone Number: 414-273-3850 Emergency Phone Number: 414-273-3850 Published: Y ======================================================= Contractor Summary ======================================================= Cage: 60928 Name: ALDRICH CHEMICAL CO INC Address: 1001 WEST ST PAUL AVE Box: 355 City: MILWAUKEE WI 53233 Phone: 414-273-3850 ======================================================= Ingredients ======================================================= Cas: 111-40-0 RTECS #: IE1225000 Name: DIETHYLENETRIAMINE % Wt: 99 OSHA PEL: 1 PPM ACGIH TLV: 1 PPM, S ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50 (ORAL RAT): 1080 MG/KG. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: MAY BE FATAL IF INHALED, SWALLOWED/ABSORBED THRU SKIN. EXTREMELY DESTRUCTIVE TO TISS OF MUC MEMB & UPPER RESP TRACT, EYES & SKIN. INHAL MAY BE FATAL AS RSLT OF SPASM, INFLAMM & EDEMA OF LARYNX & BRONCHI. CHEM PNEUMIT & PULM EDEMA. SYMPS OF EXPOS MAY INCL BURNING SENSATION, COUGHING, WHEEZING, (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: LARYNGITIS, SHORTNESS OF BREATH, HDCH, NAUS & VOMIT. MAY CAUSE ALLERGIC RESP & SKIN RXNS. TARGET ORGANS: LIVER, KIDNEYS. TO THE BEST OF MFR KNOWLEDGE, THE CHEM, PHYSICAL, & TOX PROPERTIES HA VE NOT BEEN THORO INVESTIGATED. TARGET ORGAN DATA: BEHAVIORAL (CONVLS/EFT ON SEIZURE THRESHOLD); GI (PERITONITIS). Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: SKIN/EYES: IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MIN, WHILE REMOVING CONTAM CLTHG & SHOES. ASSURE ADEQ FLUSHING OF EYES BY SEPARATING EYELIDS W/FINGERS. INHAL: REMOVE TO FRESH AIR. IF NO T BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. INGEST: WASH OUT MOUTH W/WATER PROVIDED PERS IS CONSCIOUS. CALL MD IMMED. WASH CONTAM CLTHG BEFORE REUSE. DISCARD CONTAM SHOES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: EVACUATE AREA. WEAR NIOSH APPROVED SCBA, RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATER IAL PICKUP IS COMPLETE. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS (FP N). Handling And Storage Precautions: STORE UNDER NITROGEN. DO NOT BREATHE VAPOR. Other Precautions: DIETHYLENETRIAMINE (DETA) HAS BEEN REPORTED TO FORM COMPLEXES WITH SILVER, COBALT OR CHROMIUM WHICH CAN BE EXPLOSIVE. IT HAS BEEN REPORTED TO CAUSE SPONTANEOUS IGNITION OF CELLULOSE NITRATE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 202F,94C Lower Limits: 2% Upper Limits: 6.7% Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. WATER SPRAY. Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR. Ventilation: USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves: CHEMICAL RESISTANT GLOVES. Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N). Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >390F,>199C M.P/F.P Text: -31F,-35C Vapor Pres: 0.08 @ 20C Vapor Density: 3.6 Spec Gravity: 0.955 Appearance and Odor: COLORLESS LIQUID ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG ACIDS, COPPER, COPPER ALLOYS. ABSORBS CARBON DIOXIDE FROM AIR. Hazardous Decomposition Products: TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: DIETHYLENETRIAMINE, 99%, D9385-6 Cage: 60928 Company Name: ALDRICH CHEMICAL CO INC Street: 1001 WEST ST PAUL AVE PO Box: 355 City: MILWAUKEE WI Zipcode: 53233 Health Emergency Phone: 414-273-3850 Label Required IND: Y Date Of Label Review: 10/13/1997 Status Code: C Label Date: 10/13/1997 Origination Code: G Chronic Hazard IND: Y Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Severe Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE: MAY BE FATAL IF INHALED, SWALLOWED OR ABSORBED THROUGH SKIN. EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN. INHALATION MAY BE FATAL. SYMPTOMS OF EXPOSURE: BURNING SENSATION, COUGHING,WHEEZING, LARYNGITIS, SHORT BREATH, HEADACHE, NAUSEA, VOMITING. CHRONIC: ALLERGIC RESPIRATORY AND SKIN REACTIONS. TARGET ORGANS: LIVER AND KIDNEYS. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.