E.E. Zimmerman Company/Elroy Turpentine Company Prepared: 7/05
P.O. Box 111254
Pittsburgh, PA 15238
(412) 963-0949
EMERGENCY CONTACT: FOR CHEMICAL EMERGENCY - SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT,
CALL CHEMTREC AT 1-(800)-424-9300, DAY OR NIGHT.
INDEX HMIS NFPA
4 - Severe Health *2 Health Not Determined
3 - Serious Flammability 3 Flammability Not Determined
2 - Moderate Reactivity 1 Reactivity Not Determined
1 - Slight
0 - Insignificant * denotes a chronic hazard
Section 2. COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT(S) CAS Number % (by volume)
XYLENE 1330-20-7 82.0
METHYL ISOBUTYL KETONE 108-10-1 15.0
METHYL ALCOHOL 67-56-1 3.0
ETHYLBENZENE 100-41-4 15.0 - 16.0
Section 3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS:
EYE:
Can cause severe eye irritation. Symptoms include stinging, tearing, redness, and swelling
of eyes. Can injure eye tissue. Additional symptoms of eye exposure may include: blurred vision.
SKIN:
Can cause skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include
redness, burning, and drying and cracking of skin, burns and other skin damage. Additional symptoms of
skin contact may include: skin blistering.
SWALLOWING:
Swallowing small amounts of this material during normal handling is not likely to cause harmful
effects. Swallowing large amounts may be harmful. This material can get into the lungs during
swallowing or vomiting. This results in lung inflammation and other lung injury.
INHALATION:
Breathing of vapor or mist is possible. Breathing small amounts of this material during normal
handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms
usually occur at air concentrations higher than the recommended exposure limits (See Section 8).
SYMPTOMS OF EXPOSURE:
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the
material through the skin may include: redness of the face and neck, stomach or intestinal upset (nausea,
vomiting, diarrhea), irritation (nose, throat, airways), central nervous system excitation (giddiness,
liveliness, light-headed feeling) followed by central nervous system depression (dizziness, drowsiness,
weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects,
respiratory depression (slowing of the breathing rate), shortness of breath, loss of coordination, confusion,
irregular heartbeat, coma, and death.
TARGET ORGAN EFFECTS:
Exposure to this material (or a component) has been found to cause kidney damage in male rats. The
mechanism by which this toxicity occurs is specific to the male rat and the kidney effects are not expected
MATERIAL SAFETY DATA SHEET
E-Z PAINT DEGLOSSER
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to occur in humans. Overexposure to this material (or its components) has been suggested as a cause
of the following effects in laboratory animals: liver abnormalities, nervous system damage, eye damage,
kidney damage, lung damage, brain damage, effects on hearing. Overexposure to this material (or
its components) has been suggested as a cause of the following effects in humans: eye damage.
DEVELOPMENTAL INFORMATION:
This material (or a component) has been shown to cause birth defects in laboratory animal studies. The
relevance of these findings to humans is uncertain.
CANCER INFORMATION:
Ethylbenzene has been shown to cause cancer in laboratory animals. The relevance of this finding to
humans is uncertain. IARC (International Agency for Research on Cancer) has classified ethylbenzene
as a possible human carcinogen.
OTHER HEALTH EFFECTS:
No Data
PRIMARY ROUTE(S) OF ENTRY:
Inhalation, skin absorption, skin contact, ingestion.
Section 4. FIRST AID MEASURES
EYES:
If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes
gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.
SKIN:
Remove contaminated clothing. Flush exposed area with large amounts of water. If skin is damaged,
seek immediate medical attention. If skin is not damaged and symptoms persist, seek medical attention.
Launder clothing before reuse.
SWALLOWING:
Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place
individual on the left side with the head down. Contact a physician, medical facility, or poison control center
for advice about whether to induce vomiting. If possible, do not leave individual unattended.
INHALATION:
If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate
medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration.
If breathing is difficult, administer oxygen.
NOTE TO PHYSICIANS:
Inhalation of high concentrations of this material, as could occur in enclosed spaces or during deliberate
abuse, may be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac
arrhythmias in persons exposed to this material. This product contains methanol which can cause
intoxication and central nervous system depression. Methanol is metabolized to formic acid and
formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness.
Since metabolism is required for these toxic symptoms, their onset may be delayed from 6 to 30 hours
following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent
methanol metabolism. Ethanol administration is indicated in symptomatic patients or at blood methanol
concentrations above 20 ug/dl. Methanol is effectively removed by hemodialysis. Fomepizole
(4-methylpyrazole) is an effective antagonist of alcohol dehydrogenase, and as such, may be used as an
antidote in the treatment of ethylene glycol, diethylene glycol and methanol poisoning. This material is an
aspiration hazard. Potential danger from aspiration must be weighed against possible oral toxicity (See
Section 3 - Swallowing) when deciding whether to induce vomiting. Preexisting disorders of the following
organs (or organ systems) may be aggravated by exposure to this material: skin, lung (for example,
asthma-like conditions), liver, kidney, central nervous system, nervous system, auditory system, and eye.
Individuals with preexisting heart disorders may be more susceptible to arrhythmias (irregular heartbeats)
if exposed to high concentrations of this material.
Section 5. FIRE FIGHTING MEASURES
FLASH POINT:
50.0 - 60.0 F (10.0 - 15.5 C) TCC
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EXPLOSIVE LIMIT:
(for component) Lower 1.0%
AUTOIGNITION TEMPERATURE:
No Data
HAZARDOUS PRODUCTS OF COMBUSTION:
May form: carbon dioxide and carbon monoxide, various hydrocarbons.
FIRE AND EXPLOSION HAZARDS:
Material is volatile and readily gives off vapors which may travel along the ground or be moved by
ventilation and ignited by pilot lights, flames, sparks, heaters, smoking, electric motors, static discharge or
other ignition sources at locations distant from material handling point. Never use welding or cutting torch
on or near drum (even empty) because product (even just residue) can ignite explosively.
EXTINGUISHING MEDIA:
Regular foam (such as AFFF), carbon dioxide, dry chemical.
FIRE FIGHTING INSTRUCTIONS:
Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA).
Section 6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL:
Absorb liquid on vermiculite, floor absorbent or other absorbent material.
LARGE SPILL:
Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing
protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at
source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading.
If run-off occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean
containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other
materials to containers for disposal. Prevent run-off to sewers, streams or other bodies of water.
If run-off occurs, notify proper authorities as required, that a spill has occurred.
Section 7. HANDLING AND STORAGE
HANDLING:
Containers of this material may be hazardous when emptied. Since emptied containers retain product
residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
Static ignition azard can result from handling and use. Electrically bond and ground all containers,
personnel and equipment before transfer or use of material. Special precautions may be necessary to
dissipate static electricity for non-conductive containers. Use proper bonding and grounding during
product transfer as described in National Fire Protection Association document NFPA 77.
WARNING. Sudden release of hot organic chemical vapors or mists from process equipment operating at
elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions
without the presence of obvious ignition sources. Published "autoignition" or "ignition" temperature
values cannot be treated as safe operating temperatures in chemical processes without analysis of the
actual process conditions. Any use of this product in elevated temperature processes should be thoroughly
evaluated to establish and maintain safe operating conditions.
Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION:
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations
also permit other type safety glasses. Consult your safety representative.
SKIN PROTECTION:
Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin
contact, wear impervious clothing and boots.
RESPIRATORY PROTECTIONS:
If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a
NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control.
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OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified
conditions (see your industrial hygienist). Engineering or administrative controls should be implemented
to reduce exposure.
ENGINEERING CONTROLS:
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below
TLV(s).
EXPOSURE GUIDELINES:
COMPONENT
XYLENE (1330-20-7)
OSHA PEL 100.000 ppm - TWA
OSHA VPEL 100.000 ppm - TWA
OSHA VPEL 150.000 ppm - STEL
ACGIH TLV 100.000 ppm - TWA
ACGIH TLV 150.000 ppm - STEL
METHYL ISOBUTYL KETONE (108-10-1)
OSHA PEL 100.000 ppm - TWA
OSHA VPEL 50.000 ppm - TWA
OSHA VPEL 75.000 ppm - STEL
ACGIH TLV 50.000 ppm - TWA
ACGIH TLV 75.000 ppm - STEL
METHYL ALCOHOL (67-56-1)
OSHA PEL 200.000 ppm - TWA
OSHA VPEL 200.000 ppm - TWA (Skin)
OSHA VPEL 250.000 ppm - STEL (Skin)
ACGIH TLV 200.000 ppm - TWA (Skin)
ACGIH TLV 250.000 ppm - STEL (Skin)
ETHYLBENZENE (100-41-4)
OSHA PEL 100.000 ppm - TWA
OSHA VPEL 100.000 ppm - TWA
OSHA VPEL 125.000 ppm - STEL
ACGIH TLV 100.000 ppm - TWA
ACGIH TLV 125.000 ppm - STEL
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT: (for component) 147.0 F (63.8 C) @ 760 mmHg
VAPOR PRESSURE: (for component) 97.680 mmHg @ 68.00 F
SPECIFIC VAPOR DENSITY: >1.000 @ AIR=1
SPECIFIC GRAVITY: .837 - .871 @ 68.00 F
LIQUID DENSITY: 7.110 lbs/gal @ 68.00 F
.854 kg/l @ 20.00 C
PERCENT VOLATILES: 100%
EVAPORATION RATE: Slower than ethyl ether
APPEARANCE: No Data
STATE: Liquid
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PHYSICAL FORM: Homogeneous solution
COLOR: No Data
ODOR: No Data
pH: Not Applicable
Section 10. STABILITY AND REACTIVITY
HAZARDOUS POLYMERIZATION:
Product will not undergo hazardous polymerization.
HAZARDOUS DECOMPOSITION:
May form: carbon dioxide and carbon monoxide, various hydrocarbons.
CHEMICAL STABILITY:
Stable
INCOMPATIBILITY:
Avoid contact with: strong oxidizing agents.
Section 11. TOXICOLOGICAL INFORMATION
No Data
Section 12. ECOLOGICAL INFORMATION
No Data
Section 13. DISPOSAL CONSIDERATION
WASTE MANAGEMENT INFORMATION:
Dispose of in accordance with all applicable local, state and federal regulations.
Section 14. TRANSPORT INFORMATION
DOT INFORMATION - 49 CFR 172.101
DOT DESCRIPTION & [CONTAINER MODE]:
PAINT RELATED MATERIAL, 3, UN1263, II [Gallon]
DOT DESCRIPTION & [CONTAINER MODE]:
CONSUMER COMMODITY, ORM-D [Quart]
RQ (Reportable Quantity) - 49 CFR 172.101
Product Quantity (lbs) Component
120 XYLENES (O-, M-, P- ISOMERS)
6325 ETHYLBENZENE
35707 METHYL ISOBUTYL KETONE
OTHER TRANSPORTATION INFORMATION
The DOT Transport Information may vary with the container and mode of shipment.
Section 15. REGULATORY INFORMATION
US FEDERAL REGULATIONS:
TSCA (Toxic Substances Control Act) Status
TSCA (UNITED STATES) The intentional ingredients of this product are listed.
CERCLA RQ - 40 CFR 302.4 (a)
COMPONENT RQ (lbs)
XYLENES (O-, M-, P- ISOMERS) 100
METHYL ISOBUTYL KETONE 5000
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METHYL ALCOHOL 5000
ETHYLBENZENE 1000
SARA 302 Components - 40 CFR 355 Appendix A
None
Section 311/312 Hazard Class - 40 CFR 370.2
Immediate (X) Delayed (X) Fire (X) Reactive ( )
Sudden Release of Pressure ( )
SARA 313 Components - 40 CFR 372.65
Section 313 Component(s) CAS Number %
XYLENE (MIXED ISOMERS) 1330-20-7 82.00
METHYL ISOBUTYL KETONE 108-10-1 15.00
METHANOL 67-56-1 3.00
ETHYLBENZENE 100-41-4 16.40
OSHA Process Safety Management - 29 CFR 1910
None listed
EPA Accidental Release Prevention - 40 CFR 68
None listed
INTERNATIONAL REGULATIONS:
INVENTORY STATUS:
Not Determined
STATE AND LOCAL REGULATIONS:
CALIFORNIA PROPOSITION 65:
The following statement is made in order to comply with the California Safe Drinking Water
and Toxic Enforcement Act of 1986: This product contains the following substance(s) known to
the state of California to cause cancer.
BENZENE
The following statement is made in order to comply with the California Safe Drinking
Water and Toxic Enforcement Act of 1986: This product contains the following substance(s)
known to the state of California to cause reproductive harm.
BENZENE
TOLUENE
NEW JERSEY RTK LABEL INFORMATION:
XYLENES 1330-20-7
METHYL ISOBUTYL KETONE 108-10-1
METHYL ALCOHOL 67-56-1
ETHYL BENZENE 100-41-4
PENNSYLVANIA RTK LABEL INFORMATION:
BENZENE, DIMETHYL- 1330-20-7
2-PENTANONE, 4-METHYL- 108-10-1
METHANOL 67-56-1
BENZENE, ETHYL- 100-41-4
E.E. Zimmerman Company/Elroy Turpentine Company believes that the statements, technical information and recommendations contained
herein are reliable, but they are given without warranty or guarantee of any kind, express or implied, and we assume no responsibility
for any loss, damage, or expense, direct or consequential, arising out of their use
ASPA 2202693 000 00B
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