EASTMAN KODAK COMPANY -- 121 3677,FIXER AND REPLENISHER,PROCESS E-6 AN ======================================================= MSDS Safety Information ======================================================= NIIN: EMPTY MSDS Date: 02/17/1999 MSDS Num: CKLMT Product ID: 121 3677,FIXER AND REPLENISHER,PROCESS E-6 AND PROCESS E-6AR MFN: 01 Responsible Party Cage: 19139 Name: EASTMAN KODAK COMPANY Address: 343 STATE STREET City: ROCHESTER NY 14650 Info Phone Number: 716-722-5151/(800) 242-2424 Emergency Phone Number: 716 722 5151 Preparer's Name: NOT PROVIDED Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 19139 Name: EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address: 343 STATE ST City: ROCHESTER NY 14650-1115 Phone: 716-722-5151/(800) 242-2424 ======================================================= Ingredients ======================================================= Cas: 7783-18-8 RTECS #: XN6465000 Name: AMMONIUM THIOSULFATE Percent by Wt: 52. Other REC Limits: NOT PROVIDED OSHA PEL: NOT PROVIDED ACGIH TLV: NOT PROVIDED ------------------------------ Cas: 7732-18-5 RTECS #: ZC0110000 Name: WATER % low Wt: 30. % high Wt: 40. Other REC Limits: NOT PROVIDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 10196-04-0 Name: AMMONIUM SULFITE % low Wt: 1. % high Wt: 5. Other REC Limits: NOT PROVIDED OSHA PEL: NOT PROVIDED ACGIH TLV: NOT PROVIDED EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 7631-90-5 RTECS #: VZ2000000 Name: SODIUM BISULFITE % low Wt: 1. % high Wt: 5. Other REC Limits: NOT PROVIDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: 5 MG/M3 ACGIH STEL: NOT ESTABLISHED EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 7757-83-7 RTECS #: WE2150000 Name: SODIUM SULFITE % low Wt: 1. % high Wt: 5. Other REC Limits: NOT PROVIDED OSHA PEL: NOT PROVIDED ACGIH TLV: NOT PROVIDED ------------------------------ Cas: 60-00-4 RTECS #: AH4025000 Name: ETHYLENEDIAMINETETRAACETIC ACID < Wt: 1. Other REC Limits: NOT PROVIDED OSHA PEL: NOT PROVIDED ACGIH TLV: NOT PROVIDED EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NOT PROVIDED Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHALATION: EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS WHICH IS I RRITATING TO RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKI N REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT IF SWALLOWED. Explanation Of Carcinogenicity: (COMPONENTS PRESENT AT 0.1% OR MORE): INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE. AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NONE. NATIONAL TOXICOLOGY PROGRAM (NT P): NONE. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE. Signs And Symptions Of Overexposure: INHALATION: EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS WHICH IS I RRITATING TO RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKI N REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT IF SWALLOWED. Medical Cond Aggravated By Exposure: SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. First Aid: INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENT ION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON SCIOUS PERSON. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. CONCENTRATE: COLLECT IN A NONCOMBUSTIBLE CONTAINER FOR PROMPT DISPOSAL. Neutralizing Agent: NOT PROVIDED Waste Disposal Methods: DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED. Handling And Storage Precautions: KEEP CONTAINER TIGHTLY CLOSED TO PREVENT THE LOSS OF WATER. DO NOT STORE OR SHIP TOGETHER WITH COMBUSTIBLE MATERIALS. STORE IN ORIGINAL CONTAINER. KEEP AWAY FROM COMBUSTIBLE MATERIAL. Other Precautions: AVOID BREATHING MIST/VAPOR. AVOID CONTACT WITH EYES AND PROLONGED/REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP FROM CONTACT WITH OXIDIZING MATERIALS, HIGHLY OXYGENATED OR HALOGENATED SOLVENTS, ORGANIC COMPOUNDS CONTAINING REDUCIBLE FUNCTIONAL GROUPS OR AQUEOUS AMMONIA. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONE. Extinguishing Media: FLOOD WITH WATER. Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard: CONTAINS A STRONG REDUCING AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND REACTIVITY SECTION. IF RESPI RATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation: GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Protective Gloves: FOR PROLONGED OR REPEATED SKIN CONTACT, IMPERVIOUS GLOVES SHOULD BE WORN. Eye Protection: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES). Other Protective Equipment: EYE BATH, SAFETY SHOWER, WASHING FACILITIES. Work Hygienic Practices: NOT PROVIDED Supplemental Safety and Health: NONE ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 NRC/State LIC No: NOT RELEVANT Boiling Point: >100.C, 212.F Vapor Pres: (68F): 24 MBAR (18 MM HG) Vapor Density: 0.6 Spec Gravity: 1.36 PH: 6.2 Viscosity: NOT PROVIDED Evaporation Rate & Reference: NOT PROVIDED Solubility in Water: COMPLETE Appearance and Odor: PHYSICAL FORM: LIQUID COLOR: COLORLESS ODOR: ODORLESS Percent Volatiles by Volume: 30-40% WT Corrosion Rate: NOT PROVIDED ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NOT PROVIDED Materials To Avoid: COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS, STRONG ACIDS, BASES, SODIUM HYPOCHLORITE (BLEACH), STRONG OXIDIZING AGENTS. CONTACT WITH BASE LIBERATES SODIUM HYPOCHLORITE (BLEACH). Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR, AMMONIA, CHLORAMINE Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= Toxicological Information: EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR D IOXIDE GAS WHICH IS IRRITATING TO RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT IF SWALLOWE D. ======================================================= Ecological Information ======================================================= Ecological: DATA FOR THE MAJOR COMPONENTS OF THIS MATERIAL HAVE BEEN USED TO ESTIMATE THE ENVIRONMENTAL IMPACT OF THIS MATERIAL. IT IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A MODERATE BIOCHEMICAL OXYGEN DEMA ND AND MAY CAUSE OXYGEN DEPLETION IN AQUEOUS SYSTEMS, A LOW POTENTIAL TO AFFECT AQUATIC ORGANISMS, A LOW POTENTIAL TO AFFECT SECONDARY WASTE TREATMENT MICROBIAL METABOLISM, A MODERATE POTENTIAL TO AFF ECT THE GROWTH OF SOME PLANT SEEDLINGS, A LOW POTENTIAL TO BIOCONCENTRATE. WHEN DILUTED WITH A LARGE AMOUNT OF WATER, THIS MATERIAL RELEASED DIRECTLY OR INDIRECTLY INTO THE ENVIRONMENT IS NOT EXPECTED TO HAVE A SIGNIFICANT IMPACT. ======================================================= MSDS Transport Information ======================================================= Transport Information: FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY . ======================================================= Regulatory Information ======================================================= Sara Title III Information: CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: AMMONIUM THIOSULFATE, (AS CHEMIC AL SOURCE OF AQUEOUS AMMONIA). Federal Regulatory Information: NOT PROVIDED State Regulatory Information: MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE. ======================================================= Other Information ======================================================= Other Information: CONTAINS: AMMONIUM SULFITE (010196-04-0); SODIUM BISULFITE (007631-90-5); SODIUM SULFITE (007757-83-7). WARNING! MAY BE HARMFUL IF SWALLOWED CAUSES EYE IRRITATION DRIED PRODUCT RESIDUE CAN ACT AS A RE DUCING AGENT. DRYING ON CLOTHING OR OTHER MATERIALS MAY CAUSE FIRE. ======================================================= Transportation Information ======================================================= Responsible Party Cage: 19139 Trans ID NO: 152966 Product ID: 121 3677,FIXER AND REPLENISHER,PROCESS E-6 AND PROCESS E-6AR MSDS Prepared Date: 02/17/1999 Review Date: 05/14/2000 MFN: 1 Net Unit Weight: NONE KNOWN Multiple KIT Number: 0 ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: 121 3677,FIXER AND REPLENISHER,PROCESS E-6 AND PROCESS E-6AR Cage: 19139 Company Name: EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Street: 343 STATE ST City: ROCHESTER NY Zipcode: 14650-1115 Health Emergency Phone: 716 722 5151 Label Required IND: Y Date Of Label Review: 05/14/2000 Status Code: A MFG Label NO: NOT PROVIDED Label Date: 02/17/1999 Origination Eye Protection IND: YES Skin Protection IND: NO Signal Word: CAUTION Respiratory Protection IND: NO Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: TARGET ORGANS: N/P. WARNING! MAY BE HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION. IRST AID: IF SWALLOWED, SEEK MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IN CASE OF EYE CONT ACT, IMMEDIATELY FLUSH EYES WITH PLENTYOF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED CONTA CT WITH SKIN. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FROM COMBUSTIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED TO PREVENT THE LOSS OF WATER. KEEP FROM CONTACT WITH C LOTHING. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.