SIGMA CHEMICAL CO -- FLAVIN ADENINE DINUCLEOTIDE SODIUM, F6625 ======================================================= MSDS Safety Information ======================================================= FSC: 6550 MSDS Date: 04/01/1999 MSDS Num: CJTMJ LIIN: 00N092593 Product ID: FLAVIN ADENINE DINUCLEOTIDE SODIUM, F6625 MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL CO Box: 14508 City: ST LOUIS MO 63178 Info Phone Number: 314-771-5765 Emergency Phone Number: 314-771-5765 Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST City: ST LOUIS MO 63178 Phone: 314-771-5765 ======================================================= Ingredients ======================================================= Cas: 146-14-5 RTECS #: AU7470000 Name: FLAVIN ADENINE DINUCLEOTIDE DISODIUM Percent by Wt: 100. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE TOXICICOLOGICAL INFORMATION Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE EFFECTS: MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. MAY CAUSE IRRITATION. THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. ALSO, SEE TOXICOLOGICAL INFORMATION . Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. First Aid: INGESTION: IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. SKIN: IN CASE OF SKIN CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. REMOVE CO NTAMINATED CLOTHING AND SHOES. CALL A PHYSICIAN. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT, CALL A PHYSICIAN. EYES: IN CASE OF CONTACT WITH EYES, FLUSH WITH COPIOUS A MOUNTS OF WATER FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING THE EYELIDS WITH FINGERS. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR PROTECTIVE EQUIPMENT. SWEEP UP, PLACE IN A BAG AND HOLD FOR DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMCAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N) TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR. Ventilation: MECHANICAL EXHAUST. Protective Gloves: CHEMICAL-RESISTANT GLOVES. Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N). Other Protective Equipment: EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). ======================================================= Physical/Chemical Properties ======================================================= Appearance and Odor: SOLID. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Hazardous Decomposition Products: TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= Toxicological Information: RTECS #: AU7470000 ADENOSINE 5'-(TRIHYDROGEN PYROPHOSPHATE), 5'-5'-ESTER WITH RIBOFLAVINE. TOXICITY DATA: ORL-MUS LD50: >7 G/KG NIIRDN -,1124,1995. IVN-MUS LD50: 589 MG/KG NIIRDN -,1124,1995. ONLY SEL ECTED REGISTRY OF TOXIC EFFECTS OF CHEMCIAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. ======================================================= Ecological Information ======================================================= Ecological: DATA NOT YET AVAILABLE. ======================================================= MSDS Transport Information ======================================================= Transport Information: CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. ======================================================= Regulatory Information ======================================================= Federal Regulatory Information: REVIEWS, STANDARDS AND REGULATIONS: OEL=MAK. NOES 1983: HZD X3863; NIS 1; TNF 3; NOS 1; TNE 29; TFE 22. EPA TSCA SECTION 8(B) CHEMICAL INVENTORY. ======================================================= Other Information ======================================================= Other Information: INGREDIENT INFORMATION: MF: C*27H*31N*9NA*2O*15P*2. EC NO: 205-663-1. HAZARDS IDENTIFICATION: DATA NOT AVAILABLE. ======================================================= HAZCOM Label ======================================================= Product ID: FLAVIN ADENINE DINUCLEOTIDE SODIUM, F6625 Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY Street: 3050 SPRUCE ST City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765 Label Required IND: Y Date Of Label Review: 11/23/1999 Status Code: A Origination Code: F Eye Protection IND: YES Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE EFFECTS: MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. MAY CAUSE IRRITATION. CHRONIC: NONE LISTED BY MANUFACTURER. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.