HONEYWELL -- GENETRON 22 ======================================================= MSDS Safety Information ======================================================= FSC: 6830 NIIN: 00-106-1659 MSDS Date: 01/01/2000 MSDS Num: CKWBX Product ID: GENETRON 22 MFN: 01 Responsible Party Cage: UO139 Name: HONEYWELL Address: 101 COLUMBIA ROAD Box: 1053 City: MORRISTOWN NJ 07962-1053 Info Phone Number: 800-707-4555 Emergency Phone Number: 973-455-2000 Resp. Party Other MSDS No.: MSDS #: GTRN-0026 Chemtrec IND/Phone: (800)424-9300 Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: UO139 Name: HONEYWELL Address: 101 COLUMBIA ROAD Box: 1053 City: MORRISTOWN NJ 07962-1053 Phone: 800-707-4555 ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: MONOCHLORODIFLUOROMETHANE,TECHNICAL Specification Number: BB-F-1421 Type/Grade/Class: 22 TYPE Unit of Issue: CY Quantitative Expression: 00000000050LB UI Container Qty: 0 Type of Container: CYLINDER,DISP ======================================================= Ingredients ======================================================= Cas: 75-45-6 RTECS #: PA6390000 Name: CHLORODIFLUOROMETHANE % Wt: 100 Other REC Limits: NONE SPECIFIED OSHA PEL: 1000 PPM ACGIH TLV: 1000PPM; 9192 Ozone Depleting Chemical: 2 ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NOT PROVIDED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: SKIN: IRRITATION WOULD RESULT FROM A DEFATTING ACTION ON TISSUE. LIQUID CONTACT COULD CAUSE FROST-BITE. EYE: LIQUID CONTACT CAN CUASE SEVERE IRRITATION & FROSTBITE. MIST MAY IRRITATE. INHALATION: GENT RON 22 IS LOW IN ACUTE TOXICITY IN AMINALS. WHEN OXYGEN LEVELS IN AIR ARE REDUCED BY 12 TO 14 % BY DISPLACEMENT, SYMPTOMS OF ASPHYXIATION, LOSS OF COORDINATION, INCREASED PULSE RATE & DEEPER RESPIRATI ON WILL OCCUR. AT HIGH LEVELS, CARDIAC ARRHYTHMIA MAY OCCUR. INGESTION: INGESTION IS UNLIKELY. SHOULD IT OCCUR, MAY CAUSE DISCOMFORT IN THE GASTROINTESTINAL TRACT, & EFFECTS SIMILAR TO INHALATION & SK IN WOULD BE EXPECTED. Explanation Of Carcinogenicity: PRODUCT CONTAINS NO MATERIALS CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA. Signs And Symptions Of Overexposure: INHALATION: WHEN OXYGEN LEVELS ARE REDUCED TO 12-14%, LOSS OF COORDINATION, INCREASED PULSE RATE, AND DEEPER RESPIRATION. SKIN/EYES: FROSTBITE, INDICATED BY PALLOR OR REDNESS, LOSS OF SENSATION AND SW ELLING. INGESTION: GI DISCOMFORT. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: SKIN: PROMPTLY FLUSH SKIN WITH WATER UNTIL ALL CHEMICAL IS REMOVED. IF THERE IS EVIDNCE OF FROSTBITE, BATHE (DO NOT RUB) WITH LUKEWARM (NOT HOT) WATER. IF WATER IS NOT AVAILABLE, COVER WITH A CLEAN, S OFT CLOTH OR SIMILAR COVERING. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS (IN CASE OF FROSTBITE, WATER SHOULD BE LUKEWARM, NOT HOT) LIFTING EYELIDS OCCASSIONALLY TO FACLITATE IRRIGATION. GET MEDICAL ATTENTION OF SYMPTOMS PERSIST. INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIR ATION/ OXYGEN AS REQUIRED. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: EVACUATE UNPROTECTED PERSONNEL. PROTECTED PERSONNEL SHOULD REMOVE ANY IGNITION SOURCES & SHUT OFF LEAK, IF WITHOUT RISK, & PROVIDE VENTILATION. UNPROTECTED PERSONNEL SHOULD NOT RETURN UNTIL AIR HAS BE EN TESTED & DETERMINED SAFE, INCLUDING LOW-LYING AREAS. (ALWAYS WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT). SPILLS & RELEASES MAY HAVE TO BE REPORTED TO FEDERAL &/OR LOCAL AUTHORITIES. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSAL MUST COMPLY WITH FEDERAL, STATE & LOCAL DISPOSAL OR DISCHARGE LAWS. GENETRON 22 IS SUBJECT TO U.S. EPA CLEAN AIR ACT REGULATIONS SECTION 608 IN 40 CFR PART 82 REGARDING REFRIGERANT RECYCLING. THE INFORMATION OFFERED HERE IS FOR THE PRODUCT AS SHIPPED. Handling And Storage Precautions: AVOID BREATHING VAPORS & LIQUID CONTACT WITH EYES, SKIN OR CLOTHING. DO NOT PUNCTURE OR DROP CYLINDERS, EXPOSE THEM TO OPEN FLAME OR EXCESSIVE HEAT. USE AUTHORIZED CONTAINERS ONLY. FOLLOW STANDARD SAF ETY PRECAUTIONS FOR HANDLING & USE OF COMPRESSED GAS CYLINDERS. Other Precautions: GENETRON 22 SHOULD NOT BE MIXED WITH AIR ABOVE ATMOSPHERIC PRESSURE FOR LEAK TESTING OR OTHER PURPOSES. USE &/OR ALTERATIONS TO THE PRODUCT SUCH AS MIXING WITH OTHER MATERIALS MAY ALTER THE RCRA CLASS IFICATION & THE PROPER DISPOSAL METHOD. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: GAS, NOT APPLICA Lower Limits: NONE Upper Limits: NONE Extinguishing Media: ANY STANDARD AGENT--CHOOSE THE ONE MOST SUITABLE FOR TYPE OF SURROUNDING FIRE. (MATERIAL ITSELF IS NOT FLAMMABLE). Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR SELF CONTAINED, NIOSH-APPROVED BREATHING APPARATUS FOR PROTECTION AGAINST POSSIBLE TOXIC DECOMPRESSION PRODUCTS. PROPER EYE & SKIN PROTECTION SHOULD BE PROVIDED. USE WATER SPR AY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard: GENETRON 22 IS NOT FLAMMABLE AT AMBIENT TEMPERATURES & ATMOSPHERIC PRESSURE. HOWEVER, THIS MATERIAL WILL BECOME COMBUSTIBLE WHEN MIXED WITH AIR UNDER PRESSURE & EXPOSED TO STRONG IGNITION SOURCES. CON TACT WITH CERTAIN REACTIVE METALS MAY RESULT IN FORMATION OF EXPLOSIVE OR EXOTHERMIC REACTIONS UNDER SPECIFIC CONDITIONS ======================================================= Control Measures ======================================================= Respiratory Protection: NONE GENERALLY REQUIRED FOR ADEQUATELY VENTILATED WORK SITUATIONS. FOR ACCIDENTAL RELEASE OR NON-VENTILATED SITUATIONS, OR RELEASE INTO CONFINED SPACE (CONCENTRATION ABOVE THE PEL OF 1,000 PPM), USE A SELF-CONTAINED NIOSH-APPROVED BREATHING APARATUS OR SUPPLIED AIR RESPIRATOR. FOR ESCAPE: USE THE FORMER OR NIOSH-APPROVED GAS MASK WITH ORGANIC VAPOR CANISTER Ventilation: PROVIDE LOCAL VENTILATION AT FILLING ZONES AND AREAS WHERE LEAKAGE IS PROBABLE. MECHANICAL (GENERAL) VENTILATION MAY BE ADEQUATE FOR OTHER OPERATING & STORAGE Protective Gloves: PVA, NEOPRENE OR BUTYL RUBBER Eye Protection: SAFETY GLASSES, CHEMICAL SAFETY GOGGLES Other Protective Equipment: IMPERVIOUS BOOTS AND CLOTHING. EYEWASH STATIONS AND QUICK-DRENCH SHOWER FACILITIES. Work Hygienic Practices: ANY CONTAMINATED CLOTHING SHOULD BE PROMPLY REMOVED AND WASHED BEFORE REUSE Supplemental Safety and Health: NOTE TO PHYSICIANS: DO NOT USE EPINEPHRINE (ADRENALINE). ======================================================= Physical/Chemical Properties ======================================================= HCC: G3 Boiling Point: =-40.6C, -41.4F Melt/Freeze Pt: =-160.C, -256.F Decomp Text: NONE PROVIDED BY MFR. Vapor Pres: 136.1 PSIA@ 70 DEG F Vapor Density: 3.0(AIR=1) Spec Gravity: 1.21@21.1C (WATER=1) PH: NEUTRAL Viscosity: NONE PROVIDED BY MFR. Evaporation Rate & Reference: >1 (CCL4=1) Solubility in Water: 0.3 WT%@25C AND 1 ATMOSPH Appearance and Odor: CLEAR, COLORLESS LIQUID/(GAS @AMBIENT TEMP), FAINT ETHEREAL ODOR Percent Volatiles by Volume: 100 Corrosion Rate: NONE PROVIDED BY MFR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES NESIUM, & ZINC Stability Condition To Avoid: DO NOT MIX WITH OXYGEN OR AIR ABOVE ATMOSPHERIC PRESSURE. ANY SOURCE OF HIGH TEMPERATURES, SUCH AS LIGHTED CIGARETTES, FLAMES, HOT SPOTS, OR WELDING. Materials To Avoid: UNDER SPECIFIC CONDITIONS; E.G. VERY HIGH TEMPERATURES &/OR APPROPRIATE PRESSURE)-FRESHLY ABRADED ALUMINUM SURFACES (MAY CAUSE STRONG EXOTHERMIC REACTION). CHEMICALLY ACTIVE METALS: POTASSIUM, CALCIUM, POWDERED ALUMINUM, ME Hazardous Decomposition Products: HALOGENS, HALOGEN ACIDS, & POSSIBLY CARBONYL HALIDES Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= Toxicological Information: LC50 4 HR RAT = />300,000 PPM. CARDIAC SENSITIZATION THRESHOLD (DOG) = 50,000 PPM. DELAYED OR SUBCHRONIC EFFECTS: INHALATION (RAT) NOEL= 50,000 PPM. NOT TERATOGENIC. NOT MUTAGENIC IN IN-VITRO OR IN-VIVO TESTS. LIFETIME EXPOSURE OF MALE RATS WAS ASSOCIATED WITH A SMALL INCREASE IN SALIVARY GLAND FIBROSARCOMAS. ======================================================= Ecological Information ======================================================= Ecological: DEGRADABILITY (BOD): GENETRON 22 IS A GAS AT ROOM TEMPERATURE, THEREFORE, IT IS UNLIKELY TO REMAIN IN WATER. OCTANOL WATER PARTITION COEFFECIENT: UNKNOWN. ======================================================= MSDS Transport Information ======================================================= Transport Information: US DOT PSN: CHLORODIFLUOROMETHANE (R-22), 2.2, UN1018. ======================================================= Regulatory Information ======================================================= Sara Title III Information: CERCLA RQ OR TPQ: NONE. SEC 311 HAZARD CLASS: IMMEDIATE AND PRESSURE. SARA SEC 313 TOXIC CHEMCIALS: CHLORODIFLUOROMETHANE (HCFC-22). GENETRON 22 IS SUBJECT TO US EPA CLEAN AIR ACT REGULATIONS AT 40 CF R PART 82. WARNING! DO NOT VENT TO THE ATMOSPHERE. TO COMPLY WITH US CLEAN AIR ACT, ANY RESIDUAL MUST BE COVERED. CONTAINS CHLORODIFLUOROMETHANE, HCFC SUBSTANCE WHICH HARMS PUBLIC HEALTH & ENVIRONMENT BY DESTROYING OZONE IN THE UPPER ATMOSPHERE. DESTRUCTION OF OZONE LAYER CAN LEAD TO INCREASED ULTRAVIOLET RADIATION WHICH, WITH EXPOSURE TO SUNLIGHT, CAN LEAD TO INCREASE IN SKIN CANCER & EYE CATARAC TS. Federal Regulatory Information: TSCA INVENTORY STATUS: LISTED ON THE TSCA INVENTORY. ======================================================= Other Information ======================================================= Other Information: W CLASSIFICATION (CANADA): THIS PRODUCT HAS BEEN EVALUATED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. FOREIGN INVENTORY STATUS : CANADA: LISTED ON DSL. EU - EINECS # 2008719. CLASSIFICATION: HEALTH=1; FLAMMABLITY = 1; REACTIVITY = 0. NFPA CLASSIFICATION: HEALTH=2; FLAMMABILITY =1; REACTIVITY = 0. ======================================================= Transportation Information ======================================================= Responsible Party Cage: UO139 Trans ID NO: 155381 Product ID: GENETRON 22 MSDS Prepared Date: 01/01/2000 Review Date: 11/17/2000 MFN: 1 Net Unit Weight: 50 LB/CYL Multiple KIT Number: 0 Unit Of Issue: CY Container QTY: 0 Type Of Container: CYLINDER,DISP ======================================================= Detail DOT Information ======================================================= DOT PSN Code: DHC DOT Proper Shipping Name: CHLORODIFLUOROMETHANE, OR REFRIGERANT GAS R22 Hazard Class: 2.2 UN ID Num: UN1018 Label: NONFLAMMABLE GAS Special Provision: B51 Non Bulk Pack: 304 Bulk Pack: 314,315 Max Qty Pass: 75 KG Max Qty Cargo: 150 KG Vessel Stow Req: A ======================================================= Detail IMO Information ======================================================= IMO PSN Code: EDB IMO Proper Shipping Name: CHLORODIFLUOROMETHANE IMDG Page Number: 2118 UN Number: 1018 UN Hazard Class: 2(2.2) IMO Packaging Group: - Subsidiary Risk Label: - EMS Number: 2-09 MED First Aid Guide NUM: 350 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: GHQ IATA UN ID Num: 1018 IATA Proper Shipping Name: CHLORODIFLUOROMETHANE IATA PSN Modifier: (R22) IATA UN Class: 2.2 IATA Label: NON-FLAMMABLE GAS Packing Note Passenger: 200 Max Quant Pass: 75KG Max Quant Cargo: 150KG Packaging Note Cargo: 200 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: GHQ AFI Proper Shipping Name: CHLORODIFLUOROMETHANE AFI Hazard Class: 2.2 AFI UN ID NUM: UN1018 Special Provisions: P5 Back Pack Reference: A6.3, A6.5 ======================================================= HAZCOM Label ======================================================= Product ID: GENETRON 22 Cage: UO139 Assigned IND: Y Company Name: HONEYWELL Street: 101 COLUMBIA ROAD PO Box: 1053 City: MORRISTOWN NJ Zipcode: 07962-1053 Health Emergency Phone: 973-455-2000 Label Required IND: Y Date Of Label Review: 11/17/2000 Status Code: A Origination Code: F Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: SKIN: IRRITATION, FROST-BITE. EYE: LIQUIDMIST CAN CUASE SEVERE IRRITATION & FROSTBITE. INHALATION: LOW IN ACUTE TOXICITY IN AMINALS. WILL CAUSE ASPHYXIATION WHEN OXYGEN LEVELS IN AIR ARE REDUCED BY 1 2 TO 14 %. AT HIGH LEVELS, CARDIAC ARRHYTHMIA MAY OCCUR. INGESTION: UNLIKELY. FIRST AID: EYE: IMMEDIATELY FLUSH WITH LUKE WARM WATER FOR 15 MINUTES. CALL PHYSICIAN. SKIN: FLUSH WITH LUKE WARM WATER . INHALATION: MOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. INGESTION: DO NOT INDUCE VOMITING UNLESS INTRUCTED BYA PHYSICIAN. GET MEDICAL HELP. DO NOT GIVE EPINEPHRINE (ADRENALINE) ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.