SIGMA CHEMICAL CO -- GN BROTH, HAJNA (GRAM NEGATIVE BROTH), G9288 ======================================================= MSDS Safety Information ======================================================= FSC: 6550 MSDS Date: 07/01/1999 MSDS Num: CJTLN LIIN: 00N092583 Product ID: GN BROTH, HAJNA (GRAM NEGATIVE BROTH), G9288 MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL CO Box: 14508 City: ST LOUIS MO 63178 Info Phone Number: 314-771-5765 Emergency Phone Number: 314-771-5765 Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST City: ST LOUIS MO 63178 Phone: 314-771-5765 ======================================================= Ingredients ======================================================= Cas: 50-99-7 RTECS #: LZ6600000 Name: GLUCOSE ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: MAY CAUSE SKIN IRRITATION. MAY CAUSE EYE IRRITATION. MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. First Aid: INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL MD. INHALATION: REMOVE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT, CALL MD. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS AMOU NTS OF WATER. EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING EYELIDS WITH FINGERS. CALL MD. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SI TE AFTER MATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. Handling And Storage Precautions: AVOID INHALATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. KEEP TIGHTLY CLOSED. STORE IN A COOL, DRY PLACE. DO NOT HEAT ABOVE 50C. MAY DECOMPOSE ON EXPOSURE TO LIGHT. Other Precautions: CAUTION: SUBSTANCE NOT YET FULLY TESTED. HARMFUL. DO NOT BREATHE DUST. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED RESPIRATOR. Ventilation: MECHANICAL EXHAUST REQUIRED. Protective Gloves: COMPATIBLE CHEMICAL-RESISTANT GLOVES. Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). WEAR SUITABLE PROTECTIVE CLOTHING. Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. ======================================================= Physical/Chemical Properties ======================================================= Appearance and Odor: SOLID. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: DO NOT HEAT ABOVE 50C. MAY DECOMPOSE ON EXPOSURE TO LIGHT. Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES, SULFUR OXIDES, AMMONIA, HYDROGEN CHLORIDE GAS, PHOSPHOROUS OXIDES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= Toxicological Information: TO THE BEST OF MFR'S KNOWLEDGE, THE CHEMICAL, PHYSICAL AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. MAY BE HARMFUL IF INHALED. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. HARMFUL IF SWALLOWED. ======================================================= Ecological Information ======================================================= Ecological: DATA NOT YET AVAILABLE. ======================================================= MSDS Transport Information ======================================================= Transport Information: CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. ======================================================= Regulatory Information ======================================================= Federal Regulatory Information: EUROPEAN INFORMATION: CAUTION: SUBSTANCE NOT YET FULLY TESTED. HARMFUL. R 22 - HARMFUL IF SWALLOWED; R 37 - IRRITATING TO RESPIRATORY SYSTEM; S 22 - DO NOT BREATHE DUST; S 36 - WEAR SUITABLE PROTECTI VE CLOTHING. ======================================================= Other Information ======================================================= Other Information: LABEL PRECAUTIONARY STATEMENTS: HARMFUL. HARMFUL IF SWALLOWED. IRRITATING TO RESPIRATORY SYSTEM. DO NOT BREATHE DUST. WEAR SUITABLE PROTECTIVE CLOTHING. ======================================================= HAZCOM Label ======================================================= Product ID: GN BROTH, HAJNA (GRAM NEGATIVE BROTH), G9288 Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY Street: 3050 SPRUCE ST City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765 Label Required IND: Y Date Of Label Review: 11/22/1999 Status Code: A Origination Code: F Eye Protection IND: YES Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE: MAY CAUSE SKIN IRRITATION. MAY CAUSE EYE IRRITATION. MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. CHR ONIC: NONE LISTED BY MANUFACTURER. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.