LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 06 PST(R) #580 Low Halogen/Low Sulfur Pipe Sealnt 58031 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: PST(R) #580 Low Halogen/Low Sulfur Pipe Sealnt Item No.: 58031 Product Type: Anaerobic 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Bisphenol A fumarate resin 39382-25-7 35-40 Polyglycol dimethacrylate 25852-47-5 20-25 Polyglycol laurate 9004-81-3 20-25 Poly(ethylene) 9002-88-4 5-10 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 3-5 TITANIUM DIOXIDE 13463-67-7 3-5 CUMENE HYDROPEROXIDE* 80-15-9 1-3 N,N-Dialkyltoluidines 613-48-9 1-3 SACCHARIN 81-07-2 0.1-1 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 resp Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Eye irritant. Estimated Oral LD50 greater than 5,000 mg/kg. Estimated Dermal LD50 greater than 2,000 mg/kg. Primary Routes of Entry: Not Available Signs and symptoms of Exposure: May cause dermatitis on prolonged contact in sen- sitive individuals. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 06 Product Name: PST(R) #580 Low Halogen/Low Sulfur Pipe Sealnt Item No.: 58031 3. HAZARDS IDENTIFICATION (continued) Existing Conditions Aggravated by Exposure: None known Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Bisphenol A fumarate resin ALG IRR NO NO NO Polyglycol dimethacrylate ALG IRR NO NO NO Polyglycol laurate ALG NO NO NO Poly(ethylene) No Data NO N/A NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO TITANIUM DIOXIDE AC4 IRR NUI NO NO NO CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO N,N-Dialkyltoluidines No Data NO NO NO SACCHARIN No Data YES 2B NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2B Possibly carcinogenic to humans AC4 ACGIH-Unclassifiable as human carc. ALG Allergen CNS Central nervous system COR Corrosive IRR Irritant MUT Mutagen NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Does not apply Skin Contact: Flush with water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors. Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not Applicable LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 06 Product Name: PST(R) #580 Low Halogen/Low Sulfur Pipe Sealnt Item No.: 58031 5. FIRE FIGHTING MEASURES (continued) (% by volume in air)Upper Not Applicable 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up in an inert absorbent. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100°F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Does not apply See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: White paste Odor: Mild Boiling Point: Greater than 300°F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.08 at 80°F Volatile Organic Compound (EPA Method 24) 8.4% Vapor Pressure: Less than 5mm at 80°F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: None Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 06 Product Name: PST(R) #580 Low Halogen/Low Sulfur Pipe Sealnt Item No.: 58031 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: This product contains Saccharin. No prop65 hazard warning is necessary if this product is used as reasonably anticipated. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1 Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 06 Product Name: PST(R) #580 Low Halogen/Low Sulfur Pipe Sealnt Item No.: 58031 16. OTHER INFORMATION (continued) HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0027 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 06 of 06 Product Name: PST(R) #580 Low Halogen/Low Sulfur Pipe Sealnt Item No.: 58031 Supplement May 06, 1992 RE: LOCTITE PST(TM) 580 PIPE SEALANT PRODUCT NAME CHANGE Consistent with Nuclear Procurement Issues Committee (NUPIC) and joint Commercial Grade Item Survey Program (CGI) requirements, the Nuclear Grade designation for Loctite Pipe Sealant #580 will no longer be used. The following identifies this simple change in product name only. INFORMATION Please be advised that Loctite(R) Product Nuclear Grade PST(R) Pipe Sealant has been re-named PST(R) 580 Low Halogen/Low Sulfur Pipe Sealant. The change applies only to the Product Name. The Product itself was not changed. The Product design and Specifications remain unchanged. There has been no change affecting Form, Fit and/or Function of the Product. All previous Commercial Grade Quality Systems remain in effect. The purpose of the change is to clarify the fact that Pipe Sealant 580 is a Commercial Grade Item. The product is not and never was intended to comply with 10 CFR 50 Appendix B, ANSI N.45.2 or any other implementing regulatory guidelines and/or requirements. This product name change has been completed on all new technical literature and new container markings. Please note - present/prior product packages can continue to be used as the product and its intended functions remain the same. Please refer to the Product Technical Data Sheet TDS-580 for any questions or product properties, performance and recommended applications. Please direct any questions regarding the NUPIC/CGI change to the Quality Department, Rocky Hill, Connecticut (ATTN: Dick Cavalieri - (860) 571-5150; or Pete Zazzaro (203) 860-5439). NC580 LT-1372