NU-CALGON WHOLESALER, INC -- NICKEL-SAFE ICE MACHINE CLEANER ======================================================= MSDS Safety Information ======================================================= FSC: 6850 NIIN: 01-363-4770 MSDS Date: 07/06/1994 MSDS Num: BSDCL Product ID: NICKEL-SAFE ICE MACHINE CLEANER MFN: 01 Responsible Party Cage: NUCAL Name: NU-CALGON WHOLESALER, INC Address: 2451 SCHUETZ ROAD City: MARYLAND HEIGHTS MO 63043 Info Phone Number: 314-994-1010/800-554-5499 Emergency Phone Number: 800-424-9300(CHEMTREC) ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: CLEANING COMPOUND,SOLVENT Specification Number: UNKNOWN Type/Grade/Class: NONE Unit of Issue: BX Quantitative Expression: 00000000024EA UI Container Qty: 1 Type of Container: BOTTLES ======================================================= Ingredients ======================================================= Cas: 7664-38-2 RTECS #: TB6300000 Name: PHOSPHORIC ACID (SARA 313) (CERCLA) % Wt: <30 Other REC Limits: NONE RECOMMENDED OSHA PEL: 1 MG/M3 ACGIH TLV: 1 MG/M3/3 STEL; 9495 EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 77-92-9 RTECS #: GE7350000 Name: CITRIC ACID % Wt: <5 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: UNKNOWN Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYE:SEVERELY IRRIT. MAY CAUSE BURNS. SKIN:CAUSES SEVERE IRRIT. MAY CAUSE BURNS ON PROLONGED CONTACT. INHAL:MISTS IRRIT OT UPPER RESP TRACT. INGEST:SEVERELY IRRIT TO MOUTH, THROAT, STOMACH. Explanation Of Carcinogenicity: MFR LISTED NO INFORMATION ABOUT THE CARCINOGENICITY OF THIS MATERIAL. DOES NOT EXPECT IT TO BE CARCINOGENIC. Signs And Symptions Of Overexposure: SEVERELY IRRIT EYES, SKIN, UPPER RESP TRACT, MOUTH, THROAT, STOMACH. CAUSES BURNS ON EYES & SKIN. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYE:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS. GET MED ATTN. SKIN:FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS. IRRIT PERSISTS GET MED ATTN. INHAL:REMOVE TO FRESHAIR. INGEST:DO NOT INDUCE VOMITING. GIVE 1 OR 2 GLASSES OF WATER TO DILUTE. GET IMMED MED ATTN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SMALL SPILLS MAY BE MOPPED UP & RESIDUES FLUSHED TO DRAIN W/WATER. RINSE MOP BEFORE STORING. NEUTRALIZE WITH DILUTE SOLUTION OF SODA ASH. Neutralizing Agent: DILUTION SOLUTION OF SODA ASH. Waste Disposal Methods: UNUSED MATL IS CORROSIVE WASATE (DOO2). USED MATERIAL MAY BE SEWERED IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. Handling And Storage Precautions: THIS PRODUCT WILL W/STAND AN OCCASIONAL ACCIDENTAL FREEZING W/O LOSS OF PERFORMANCE. THAW & REMIX BEFORE USE. Other Precautions: THIS IS A COMPLETE PROUDCT. DO NOT ADD OR MIX WITH OTHER CHEMICALS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONE Extinguishing Media: PRODUCT IS NOT FLAMM/COMBUSTIBLE.NONE SPECIFIED BY MFG. HOWEVER USE APPROPRIATE MEDIA FOR SURROUNDING FIRE/MATL. Fire Fighting Procedures: NONE KNOWN. ======================================================= Control Measures ======================================================= Respiratory Protection: NOT NORMALLY REQUIRED. Ventilation: GOOD GENERAL VENTILATION. Protective Gloves: RUBBER GLOVES. Eye Protection: SPLASH GOGGLES. Other Protective Equipment: NONE NORMALLY REQUIRED. Work Hygienic Practices: WASH HANDS AFTER HANDLING. Supplemental Safety and Health: PH 1% SOLN=2.0, AS DISTRIBUTED <1. ======================================================= Physical/Chemical Properties ======================================================= HCC: C1 B.P. Text: >200F,>93C M.P/F.P Text: 0F,-18C Spec Gravity: 1.188 @25C PH: SUPPLE Solubility in Water: COMPLETE Appearance and Odor: GREEN LIQUID, MILD CHEMICAL ODOR. Percent Volatiles by Volume: 30 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE KNOWN. Materials To Avoid: STRONG BASES, AMMONIA, CHLROINE BLEACH. Hazardous Decomposition Products: FORCED IGNITION OF DRIED RESIDUES MAY PRODUCE OXIDES OF PHOSPHORUS. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Responsible Party Cage: NUCAL Trans ID NO: 129464 Product ID: NICKEL-SAFE ICE MACHINE CLEANER MSDS Prepared Date: 07/06/1994 Review Date: 08/14/1995 MFN: 1 Tech Entry NOS Shipping Nm: CORROSIVE LIQUID, N.O.S. (PHOSPHORIC ACID <30%, CITRIC ACID <5%). Net Unit Weight: 24 X 2.4LBS Multiple KIT Number: 0 Review IND: Y Unit Of Issue: BX Container QTY: 1 Type Of Container: BOTTLES ======================================================= Detail DOT Information ======================================================= DOT PSN Code: DON Symbols: D,G DOT Proper Shipping Name: COMPOUNDS, CLEANING LIQUID Hazard Class: 8 UN ID Num: NA1760 DOT Packaging Group: II Label: CORROSIVE Special Provision: B2,N37,T14 Packaging Exception: 154 Non Bulk Pack: 202 Bulk Pack: 242 Max Qty Pass: 1 L Max Qty Cargo: 30 L Vessel Stow Req: B Water/Ship/Other Req: 40 ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ESH IMO Proper Shipping Name: CORROSIVE LIQUID, N.O.S. o IMDG Page Number: 8147 UN Number: 1760 UN Hazard Class: 8 IMO Packaging Group: I/II/III Subsidiary Risk Label: - EMS Number: 8-15 MED First Aid Guide NUM: 760 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: HKR IATA UN ID Num: 1760 IATA Proper Shipping Name: CORROSIVE LIQUID, N.O.S. * IATA UN Class: 8 IATA Label: CORROSIVE UN Packing Group: II Packing Note Passenger: 808 Max Quant Pass: 1L Max Quant Cargo: 30L Packaging Note Cargo: 812 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: HKR AFI Symbols: * AFI Proper Shipping Name: CORROSIVE LIQUID, N.O.S. AFI Hazard Class: 8 AFI UN ID NUM: UN1760 AFI Packing Group: II Special Provisions: P4 Back Pack Reference: A12.3 ======================================================= HAZCOM Label ======================================================= Product ID: NICKEL-SAFE ICE MACHINE CLEANER Cage: NUCAL Company Name: NU-CALGON WHOLESALERS INC Street: 2451 SCHUSTZ RD City: MARYLAND HEIGHTS MO Zipcode: 63043 Health Emergency Phone: 800-424-9300(CHEMTREC) Label Required IND: Y Date Of Label Review: 08/14/1995 Status Code: C Label Date: 08/14/1995 Year Procured: 1995 Origination Code: F Eye Protection IND: YES Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: EYE:SEVERELY IRRIT. MAY CAUSE BURNS. SKIN:CAUSES SEVERE IRRIT. MAY CAUSE BURNS ON PROLONGED CONTACT. INHAL:MISTS IRRIT OT UPPER RESP TRACT. INGEST:SEVERELY IRRIT TO MOUTH, THROAT, STOMACH. THIS PRODUC T WILL W/STAND AN OCCASIONAL ACCIDENTALFREEZING W/O LOSS OF PERFORMANCE. THAW & REMIX BEFORE USE. FIRST AID: EYE:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS. GET MED ATTN. SKIN:FLUSH W/PLENTY OF W ATER FOR @LEAST 15MINS. IRRIT PERSISTS GET MED ATTN. INHAL:REMOVE TO FRESHAIR.INGEST:DO NOT INDUCE VOMITING. GIVE 1 OR 2 GLASSES OF WATER TO DILUTE. GET IMMED MED ATTN. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.