Page 1/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 11/28/2005 Reviewed on 11/25/2005 DR * 1 Identification of substance · Product details · Trade name: Insta-Fluor Plus · Article number: 0LD1364 · Application of the substance / the preparation Laboratory chemicals · Manufacturer/Supplier: PerkinElmer Life & Analytical Sciences B.V. Rigaweg 22, 9723 TH Groningen PO Box 5205, 9700 GE Groningen The Netherlands Phone: (31) 50- 544 59 00 Fax: (31) 50- 544 59 50 · Information department: Environment Health and Safety (EHS) * 2 Composition/Data on components · Chemical characterization: · CAS No. Description 95-63-6 1,2,4-trimethylbenzene · Identification number(s) · EINECS Number: 202-436-9 · EU Number: 601-043-00-3 · Chemical characterization · Description: Mixture: consisting of the following components. · Non-Dangerous components 92-71-7 2,5-diphenyloxazole = 2.5% 13280-61-0 1,4-bis(2-methylstyryl)-benzeen = 2.5% · Additional information: For the wording of the listed risk phrases refer to section 16. * 3 Hazards identification · Hazard description: Xn Harmful N Dangerous for the environment · Information pertaining to particular dangers for man and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. R 10 Flammable. R 20 Harmful by inhalation. R 36/37/38 Irritating to eyes, respiratory system and skin. R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment · Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. · NFPA ratings (scale 0 - 4) 2 2 0 Health = 2 Fire = 2 Reactivity = 0 (Contd. on page 2) USA Page 2/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 11/28/2005 Reviewed on 11/25/2005 Trade name: Insta-Fluor Plus (Contd. of page 1) DR · WHMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY 2 2 0 Health = 2 Fire = 2 Reactivity = 0 * 4 First aid measures · General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. · After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor. · After swallowing: If symptoms persist consult doctor. · Information for doctor: · The following symptoms may occur: Headache * 5 Fire fighting measures · Suitable extinguishing agents: Foam Fire-extinguishing powder Carbon dioxide · For safety reasons unsuitable extinguishing agents: Water with full jet · Protective equipment: Mount respiratory protective device. * 6 Accidental release measures · Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. · Measures for environmental protection: Do not allow to enter sewers/ surface or ground water. Inform respective authorities in case of seepage into water course or sewage system. · Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. * 7 Handling and storage · Handling: · Information for safe handling: Ensure good ventilation/exhaustion at the workplace. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. (Contd. on page 3) USA Page 3/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 11/28/2005 Reviewed on 11/25/2005 Trade name: Insta-Fluor Plus (Contd. of page 2) DR · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Protect from heat and direct sunlight. 8 Exposure controls and personal protection · Additional information about design of technical systems: No further data; see item 7. · Components with limit values that require monitoring at the workplace: Not required. · Additional information: The lists that were valid during the creation were used as basis. · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. · Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed goggles * 9 Physical and chemical properties · General Information Form: Fluid Color: Colorless Odor: Aromatic · Change in condition Melting point/Melting range: -44°C (-47°F) (Contd. on page 4) USA Page 4/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 11/28/2005 Reviewed on 11/25/2005 Trade name: Insta-Fluor Plus (Contd. of page 3) DR Boiling point/Boiling range: 170°C (338°F) · Flash point: 47°C (117°F) · Ignition temperature: 500°C (932°F) · Auto igniting: Product is not selfigniting. · Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. · Explosion limits: Lower: 1.1 Vol % Upper: 7.0 Vol % · Density at 20°C (68°F): 0.88 g/cm³ · Solubility in / Miscibility with Water: Not miscible or difficult to mix. Organic solvents: 99-100 % * 10 Stability and reactivity · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Dangerous reactions No dangerous reactions known. · Dangerous products of decomposition: Carbon monoxide and carbon dioxide 11 Toxicological information · Acute toxicity: · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant 12 Ecological information · Ecotoxical effects: · Remark: Toxic for fish · General notes: Water hazard class 2 (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms USA (Contd. on page 5) Page 5/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 11/28/2005 Reviewed on 11/25/2005 Trade name: Insta-Fluor Plus (Contd. of page 4) DR * 13 Disposal considerations · Product: · Recommendation: Must be specially treated adhering to official regulations. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. * 14 Transport information · DOT regulations: · Hazard class: 3 · Identification number: UN1993 · Packing group: III · Proper shipping name (technical name): FLAMMABLE LIQUID, N.O.S. (1,2,4-trimethylbenzene) · Label 3 · Land transport ADR/RID (cross-border): · ADR/RID class: 3 Flammable liquids · Danger code (Kemler): 30 · UN-Number: 1993 · Packaging group: III · Description of goods: 1993 FLAMMABLE LIQUID, N.O.S. (1,2,4-trimethylbenzene) · Maritime transport IMDG: · IMDG Class: 3 · UN Number: 1993 · Label 3 · Packaging group: III · EMS Number: F-E,S-E · Marine pollutant: Yes · Propper shipping name: FLAMMABLE LIQUID, N.O.S. (1,2,4-trimethylbenzene) · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: 3 · UN/ID Number: 1993 · Label 3 · Packaging group: III (Contd. on page 6) USA Page 6/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 11/28/2005 Reviewed on 11/25/2005 Trade name: Insta-Fluor Plus (Contd. of page 5) DR · Propper shipping name: FLAMMABLE LIQUID, N.O.S. (1,2,4-trimethylbenzene) * 15 Regulations · Sara · Section 355 (extremely hazardous substances): Substance is not listed. · Section 313 (Specific toxic chemical listings): 95-63-6 1,2,4-trimethylbenzene · TSCA (Toxic Substances Control Act): Substance is listed. · Proposition 65 · Chemicals known to cause cancer: Substance is not listed. · Cancerogenity categories · EPA (Environmental Protection Agency) Substance is not listed. · IARC (International Agency for Research on Cancer) Substance is not listed. · NTP (National Toxicology Program) Substance is not listed. · TLV (Threshold Limit Value established by ACGIH) Substance is not listed. · MAK (German Maximum Workplace Concentration) Substance is not listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) Substance is not listed. · OSHA-Ca (Occupational Safety & Health Administration) Substance is not listed. · Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. · Hazard symbols: Xn Harmful N Dangerous for the environment · Risk phrases: 10 Flammable. 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment · Safety phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. (Contd. on page 7) USA Page 7/7 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 11/28/2005 Reviewed on 11/25/2005 Trade name: Insta-Fluor Plus (Contd. of page 6) DR · National regulations: · Technical instructions (air): Class Share in % II 100 · Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. * 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing MSDS: Environment Health and Safety (EHS) · Contact: J. van der Weele · * Data compared to the previous version altered. USA