LEXMARK INTERNATIONAL INC -- OPTRA N LASER PRINT CARTRIDGE, 1382140 ======================================================= MSDS Safety Information ======================================================= FSC: 6850 MSDS Date: 08/05/1996 MSDS Num: CHWJX LIIN: 00N089644 Product ID: OPTRA N LASER PRINT CARTRIDGE, 1382140 MFN: 01 Responsible Party Cage: 0SD37 Name: LEXMARK INTERNATIONAL INC Address: 740 NEW CIRCLE RD NW City: LEXINGTON KY 40511-1876 Info Phone Number: 606-232-3000 Emergency Phone Number: 606-232-3333 Published: Y ======================================================= Contractor Summary ======================================================= Cage: 0SD37 Name: LEXMARK INTL INC FEDERAL SALES DIV Address: 2275 RESEARCH BLVD SUITE 360 City: ROCKVILLE MD 20850-1876 Phone: 800-552-3422 ======================================================= Ingredients ======================================================= Cas: 25767-47-9 Name: ACRYLIC ACID BUTYL ESTER POLYMER WITH STYRENE; (STYRENE ACRYLATE COPOLYMER) % Wt: 45-55 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 1317-61-9 Name: IRON OXIDE % Wt: 45-55 OSHA PEL: 10 MG/M3 ACGIH TLV: 5 MG/M3 ------------------------------ Name: SUPDAT: INGEST: SHORT TERM EXPOS: TEST DATA FROM SIMILAR TONER MATLS INDICATES LOW ORAL TOXICITY. EXPOSURE NOT ----------------------------- Name: ING 3: NOT PROBABLE W/INTENDED USE. LONG TERM EXPOS: NO INFORMATION AVIAL. EXPOSURE NOT PROBABLE W/INTENDED USE. ----------------------------- Name: SPILL PROC: DISPOSAL. AVOID INHALATION OF DUST. ----------------------------- Name: WASTE DISP METH: DISPOSAL SHOULD BE SUBJECT TO LOCAL, STATE OR FEDERAL LAWS. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: SIGNS & SYMPS OF EXPOSURE: TONER ON SKIN OR MUCOUS MEMBRANES (MOUTH, EYES & RESP SYSTEM) MAY CAUSE DISCOMFORT. INHAL: SHORT-TERM EXPOS: MINIMAL RESP TRACT IRRIT MAY OCCUR AS W/EXPOS TO LG AMTS OF ANY NON-TOXIC DUST. EXPOS NOT PROBABLE W/INTENDED USE. LONG TERM EXPOS: NO ADVERSE EFTS KNOWN. EXPOS(EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: NOT PROBABLE W/INTENDED USE. SKIN CONT: SHORT TERM EXPOS: TEST DATA FROM SIMILAR TONER MATLS INDICATES THIS TONER IS NOT SKIN IRRITANT ACCORD TO OSHA 29CFR 1910.1200. EXPOS NOT PROBABLE W/IN TENDED USE. LONG TERM EXPOS: RARE INDIVIDUALS MAY NOTE SKIN RASH W/RPTD CONT. EXPOS NOT PROBABLE W/INTENDED USE.(SUPDAT) Medical Cond Aggravated By Exposure: NONE KNOWN AT INTENDED LEVELS OF USE. First Aid: INHAL: REMOVE FROM AREA OF EXPOSURE. SEEK MED ATTN IF DFCLTY IN BRTHG IS EXPERIENCED. SKIN CONT: WASH AREA W/SOAP & WATER. EYE CONT: FLUSH IMMED W/LG AMT OF RUNNING WATER FOR AT LST 15 MINS. SEEK MED ATTN IF IRRIT PERSIST. INGEST: IF CONSCIOUS, PERSON SHOULD IMMED DRINK LG QTYS OF WATER TO DILUTE THIS PROD. SEEK MED ATTN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: OCCUP SPILL: IF DUST CLOUD IS POSS DUE TO SPILL, REMOVE ALL SOURCES OF IGNIT SUCH AS OPEN SPARKS, FLAMES/STATIC DISCHARGE TO PVNT IGNIT OF DUST. MINIMIZE DUST GENERATION DURING CLEAN UP. SWEEP UP SPIL L W/NON-METALLIC BROOM & DUST PAN. CNTNFOR Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: IF DISCARDED IN ITS PURCHASED FORM, PROD WOULD NOT BE HAZ WASTE EITHER BY LISTING/BY CHARACT. HOWEVER, UNDER RCRA, IT IS RESPONSIBILITY OF PROD USER TO DETERM @ TIME OF DISP WHETHER MATL HAS BEEN CONT AMD & SHOULD BE CLASSIFIED AS HAZ WASTE. Handling And Storage Precautions: AVOID EXCESSIVE HEAT DURING STORAGE. KEEP AWAY FROM CONTACT WITH OXIDIZING MATERIALS. Other Precautions: KEEP OUT OF REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER, DRY CHEMICAL, OR FOAM. Fire Fighting Procedures: NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). FIRE MAY PRDCE HAZ DECOMP PRODS SUCH AS CARBON DIOXIDE, CARBON MONOXIDE, & UNIDENTIFIED ORGANICS. Unusual Fire/Explosion Hazard: LIKE MANY FINELY DIVIDED MATERIALS, TONER DUST, IN HIGH CONCENTRATIONS CAN FORM AN EXPLOSIVE MIXTURE IN AIR WHICH, IF IGNITED, COULD RESULT IN DUST EXPLOSION. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE REQUIRED FOR INTENDED USE IN PRINTER. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: MECHANICAL ROOM VENTILATION. Protective Gloves: IMPERVIOUS GLOVES (FP N). Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: EFTS OF OVEREXP: EYE CONT: SHORT TERM EXPOS: TONER MAY ACT AS MECH IRRITANT. TEST DATA FROM SIMILAR TONER MATLS INDICATES THIS TONER IS NOT EYE IRRITANT ACCORD TO OSHA 29CFR 1910.1200. EXPOS NOT PROBA BLE W/INTENDED USE. LONG TERM EXPOS: NOADVERSE CHRONIC EFTS KNOWN. EXPOS NOT PROBABLE W/INTENDED USE. ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: >212F,>100C Spec Gravity: 1.4-1.8(H*2O=1) Solubility in Water: INSOLUBLE Appearance and Odor: BLACK POWDERY MATERIAL, WITH SLIGHT ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE KNOWN. Materials To Avoid: STRONG OXIDIZERS. Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE, AND LOW MOLECULAR WEIGHT ORGANICS. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: OPTRA N LASER PRINT CARTRIDGE, 1382140 Cage: 0SD37 Company Name: LEXMARK INTL INC FEDERAL SALES DIV Street: 2275 RESEARCH BLVD SUITE 360 City: ROCKVILLE MD Zipcode: 20850-1876 Health Emergency Phone: 606-232-3333 Label Required IND: Y Date Of Label Review: 09/02/1998 Status Code: C Label Date: 09/02/1998 Origination Eye Protection IND: YES Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: SIGNS & SYMPS OF EXPOSURE: TONER ON SKIN OR MUCOUS MEMBRANES (MOUTH, EYES & RESPIRATORY SYSTEM) MAY CAUSE DISCOMFORT. INHALATION: SHORT-TERM EXPOSURE: MINIMAL RESPIRATORY TRACT IRRITATION MAY O CCUR AS WITH EXPOSURE TO LARGE AMOUNTS OF ANY NON-TOXIC DUST. SKIN: RASH. EYE: IRRITANT. CHRONIC: NONE LISTED BY MANUFACTURER. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.