POLY SCIENTIFIC R&D CORP -- LIGHT GREEN S.F. YELLOWISH 2% AQUEOUS, S231 ======================================================= MSDS Safety Information ======================================================= FSC: 6550 MSDS Date: 10/01/1991 MSDS Num: CGDGK LIIN: 00N082588 Product ID: LIGHT GREEN S.F. YELLOWISH 2% AQUEOUS, S231 MFN: 01 Responsible Party Cage: 67458 Name: POLY SCIENTIFIC R&D CORP Address: 70 CLEVELAND AVE City: BAY SHORE NY 11706 Info Phone Number: 516-586-0400 Emergency Phone Number: 800-424-9300 (CHEMTREC) Published: Y ======================================================= Contractor Summary ======================================================= Cage: 67458 Name: POLY SCIENTIFIC R&D CORP. Address: 70 CLEVELAND AVE City: BAY SHORE NY 11706 Phone: 516-586-0400 ======================================================= Ingredients ======================================================= Cas: 5141-20-8 RTECS #: BQ4900000 Name: AMMONIUM, ETHYL(4-(P-ETHYL(M-SULFOBENZYL) AMINO)-ALPHA-(P-SULFOPHENL)BENZYLIDENE)-2,5- CYCLOHEXADIEN-1- OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Name: ING 1: YLIDENE)(M-SULFOBENZYL)-, HYDROXIDE, INNER SALT, DISODIUM SALT; (LIGHT GREEN). LD50: (ORAL, RAT) 2 G/KG. OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- Cas: 64-19-7 RTECS #: AF1225000 Name: ACETIC ACID; (GLACIAL ACETIC ACID) (CERCLA). LD50: (ORAL, RAT) 10 MG/KG. OSHA PEL: 10 PPM ACGIH TLV: 10 PPM; 15 STEL EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE INGREDIENTS Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: MAY CAUSE VOMITING; CYANOSIS; DIARRHEA AND ABDOMINAL PAIN IF INGESTED. EXPOSURE TO 50 PPM OF GLACIAL ACETIC ACID IS INTOLERABLE TO MOST INDIVIDUALS. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. First Aid: INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF AVAILABLE. EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH COPIOUS AMOUNTS OF SOAP AND WATER. INGESTION: GIVE LARGE A MOUNTS OF MILK OR WATER TO CONSCIOUS VICTIM. DO NOT INDUCE VOMITING! GET MEDICAL ATTENTION IMMEDIATELY! ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: PICK UP SPILL WITH ABSORBENT VERMICULITE AND CONTAINERIZE FOR PROPER DISPOSAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: WASTE DISPOSAL METHODS IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY, WELL VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL FOAM. Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROTECTIVE EQUIPMENT (FP N). NO ACUTE HAZARD. AVOID BREATHING VAPORS. WATER DILUTED ACID CAN REACT W/METALS TO FORM HYDROGEN GAS. Unusual Fire/Explosion Hazard: VAPOR AIR MIXTURES ARE EXPLOSIVE WITHIN FLAMMABLE LIMITS. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS. Ventilation: LOCAL EXHAUST: YES. MECHANICAL (GENERAL): HOOD. Protective Gloves: IMPERVIOUS GLOVES (FP N). Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). APRON. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= Solubility in Water: YES Appearance and Odor: GREEN COLORED SOLUTION. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: AVOID HEATING TO DECOMPOSITION. Materials To Avoid: ACIDS, BASES, OXIDIZERS, METALS, CHROMIC ACID, NITRIC ACID, SODIUM HYDROXIDE, POTASSIUM HYDROXIDE. Hazardous Decomposition Products: CARBON MONOXIDE AND NITROUS OXIDES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: LIGHT GREEN S.F. YELLOWISH 2% AQUEOUS, S231 Cage: 67458 Company Name: POLY SCIENTIFIC R&D CORP. Street: 70 CLEVELAND AVE City: BAY SHORE NY Zipcode: 11706 Health Emergency Phone: 800-424-9300 (CHEMTREC) Label Required IND: Y Date Of Label Review: 01/28/1998 Status Code: C Label Date: 01/28/1998 Origination Code: G Eye Protection IND: YES Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: MAY CAUSE VOMITING; CYANOSIS; DIARRHEA AND ABDOMINAL PAIN IF INGESTED. EXPOSURE TO 50 PPM OF GLACIAL ACETIC ACID IS INTOLERABLE TO MOST INDIVIDUALS. CHRONIC: NONE LISTED BY MANUFACTURER. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.