SIGMA CHEMICAL SIGMA DIAGNOSTI -- MALACHITE GREEN SOLUTION ======================================================= MSDS Safety Information ======================================================= FSC: 6550 NIIN: 01-449-4353 MSDS Date: 07/13/1999 MSDS Num: CLDMS Product ID: MALACHITE GREEN SOLUTION MFN: 01 Responsible Party Cage: 0DK69 Name: SIGMA CHEMICAL CO SIGMA DIAGNOSTICS DIV Address: 3050 SPRUCE ST City: ST LOUIS MO 63103-2530 Info Phone Number: 314-771-5765 Emergency Phone Number: 1-314-771-5765 Resp. Party Other MSDS No.: 3632XA Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 0DK69 Name: SIGMA CHEMICAL CO SIGMA DIAGNOSTICS DIV Address: 3050 SPRUCE ST City: ST LOUIS MO 63103-2530 Phone: 314-771-5765 ======================================================= Item Description Information ======================================================= Item Manager: S9M Item Name: MALACHITE GREEN STA Unit of Issue: BT ======================================================= Ingredients ======================================================= Cas: 2437-29-8 RTECS #: BQ1190000 Name: MALACHITE GREEN OXALATE, CERTIFIED; CATALOG NUMBER M9015 Percent by Wt: 1.5 ------------------------------ Cas: 64-19-7 RTECS #: AF1225000 Name: ACETIC ACID, GLACIAL; CATALOG NUMBER A0657 Percent by Wt: .1 OSHA PEL: 25 MG/M3;10 PPM ACGIH TLV: 25 MG/M3;10 PPM ACGIH STEL: 37 MG/M3;15 PPM EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 56-81-5 RTECS #: MA8050000 Name: GLYCEROL SIGMS GRADE; CATALOG NUMBER G9012 Percent by Wt: 17. OSHA PEL: 15 MG/M3 ACGIH TLV: 10 MG/M3 ACGIH STEL: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= Effects of Exposure: IRRITANT. Signs And Symptions Of Overexposure: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. First Aid: IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR PROTECTIVE EQUIPMENT. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURN AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. ======================================================= Fire and Explosion Hazard Information ======================================================= ======================================================= Control Measures ======================================================= Other Protective Equipment: WEAR SUITABLE PROTECTIVE CLOTHING. Supplemental Safety and Health: CATALOG #: HT80-2-8. ======================================================= Physical/Chemical Properties ======================================================= HCC: F6 ======================================================= Reactivity Data ======================================================= ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: HEALTH=3, FLAMMABILITY=2, REACTIVITY=0. ======================================================= Transportation Information ======================================================= Responsible Party Cage: 0DK69 Trans ID NO: 157251 Product ID: MALACHITE GREEN SOLUTION MSDS Prepared Date: 07/13/1999 Review Date: 06/02/2001 MFN: 1 Multiple KIT Number: 0 Review IND: Y Unit Of Issue: BT ======================================================= Detail DOT Information ======================================================= DOT PSN Code: AAW DOT Proper Shipping Name: ACETIC ACID SOLUTION DOT PSN Modifier: WITH MORE THAN 10 PERCENT AND LESS THAN 50 PERCENT ACID BY MASS Hazard Class: 8 UN ID Num: UN2790 DOT Packaging Group: III Label: 8 Special Provision: T8 Packaging Exception: 154 Non Bulk Pack: 203 Bulk Pack: 242 Max Qty Pass: 5 L Max Qty Cargo: 60 L Vessel Stow Req: A ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ACI IMO Proper Shipping Name: ACETIC ACID,SOLUTION IMO PSN Modifier: ,MORE THAN 25% BUT NOT MORE THAN 80% ACID, BY MASS IMDG Page Number: 8100 UN Number: 2790 UN Hazard Class: 8 IMO Packaging Group: II/III Subsidiary Risk Label: - EMS Number: 8-05 MED First Aid Guide NUM: 700 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ABP IATA UN ID Num: 2790 IATA Proper Shipping Name: ACETIC ACID SOLUTION IATA PSN Modifier: MORE THAN 10% BUT LESS THAN 50% ACID BY WEIGHT IATA UN Class: 8 IATA Label: CORROSIVE UN Packing Group: III Packing Note Passenger: 818 Max Quant Pass: 5L Max Quant Cargo: 60L Packaging Note Cargo: 820 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ABS AFI Proper Shipping Name: ACETIC ACID SOLUTION AFI PSN Modifier: ,MORE THAN 10% BUT NOT MORE THAN 80% ACID,BY MASS AFI Hazard Class: 8 AFI UN ID NUM: UN2790 AFI Packing Group: II Special Provisions: P5, A3, A6, A7, A10 Back Pack Reference: A12.3 ======================================================= HAZCOM Label ======================================================= Product ID: MALACHITE GREEN SOLUTION Cage: 0DK69 Company Name: SIGMA CHEMICAL CO SIGMA DIAGNOSTICS DIV Street: 3050 SPRUCE ST City: ST LOUIS MO Zipcode: 63103-2530 Health Emergency Phone: 1-314-771-5765 Label Required IND: Y Date Of Label Review: 06/02/2001 Status Code: A Origination Code: F Signal Word: CAUTION Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: LABEL PRECAUTIOINARY STATEMENTS: IRRITANT. IRRITATING TO EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MDICAL ADVICE. WEAR SUITABLE PROTECTIVE CLOTHING. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.