ALDRICH CHEMICAL SUB OF SIGMA- -- 24082-6 METHYL SALICYLATE ======================================================= MSDS Safety Information ======================================================= FSC: 6550 MSDS Date: 01/19/1995 MSDS Num: BWWTH LIIN: 00F039326 Product ID: 24082-6 METHYL SALICYLATE MFN: 01 Responsible Party Cage: 60928 Name: ALDRICH CHEMICAL CO SUB OF SIGMA-ALDRICH Address: 1001 W ST PAUL AVE Box: 355 City: MILWAUKEE WI 53201-5000 Info Phone Number: 414-273-3850 Emergency Phone Number: 414-273-3850 Review Ind: Y Published: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 60928 Name: ALDRICH CHEMICAL CO INC Address: 1001 WEST ST PAUL AVE Box: 355 City: MILWAUKEE WI 53233 ======================================================= Contractor Summary ======================================================= Cage: 60928 Name: ALDRICH CHEMICAL CO INC Address: 1001 WEST ST PAUL AVE Box: 355 City: MILWAUKEE WI 53233 Phone: 414-273-3850 ======================================================= Ingredients ======================================================= Cas: 119-36-8 RTECS #: VO4725000 Name: METHYL SALICYLATE % Wt: 99 ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50 (RAT): 887 MG/KG Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHALATION: TOXIC, IRRITATION TO RESPIRATORY SYSTEM. SKIN/EYES: IRRITATION. HARMFUL IF SWALLOWED, INHALED, ABSORBED. VAPOR/MIST IS IRRITATION TO MUCOUS MEMBRANES. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: IRRITATION First Aid: EYES: WASH IMMEDIATELY W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: WASH OUT MOUTH W/WAT ER PROVIDED PERSON IS CONSCIOUS. OBTAINMEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COVER W/DRY LIME/SODA ASH, PICK UP, KEEP IN A CLOSED CONTAINER & HOLD FOR WASTE DISPOSAL. VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DISSOLVE/MIX THE MATERIAL W/COMBUSTIBLE SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER. Handling And Storage Precautions: KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. Other Precautions: DON'T BREATHE VAPORS. DON'T GET IN EYES, SKIN & CLOTHING. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY, CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM Fire Fighting Procedures: WEAR SELF CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING (RUBBER BOOTS, HEAVY RUBBER GLOVES). ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR Ventilation: USE ONLY IN A CHEMICAL FUME HOOD Protective Gloves: RUBBER Eye Protection: CHEMICAL SAFETY GOGGLES Other Protective Equipment: SAFETY SHOWER & EYE BATH Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 431.6F M.P/F.P Text: 17.6-19.4F Vapor Pres: 1 Vapor Density: 5.26 Spec Gravity: 1.174 Appearance and Odor: COLORLESS LIQUID ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG BASES. Hazardous Decomposition Products: TOXIC FUMES, CO, CO2 Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 24082-6 METHYL SALICYLATE Cage: 60928 Company Name: ALDRICH CHEMICAL CO INC Street: 1001 WEST ST PAUL AVE PO Box: 355 City: MILWAUKEE WI Zipcode: 53233 Health Emergency Phone: 414-273-3850 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: INHALATION: TOXIC, IRRITATION TO RESPIRATORY SYSTEM. SKIN/EYES: IRRITATION. HARMFUL IF SWALLOWED, INHALED, ABSORBED. VAPOR/MIST IS IRRITATION TO MUCOUS MEMBRANES. IRRITATION ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.