ALDRICH CHEMICAL SUB OF SIGMA- -- N840-7 NITRILOTRIACETIC ACID ======================================================= MSDS Safety Information ======================================================= FSC: 6810 MSDS Date: 07/31/1995 MSDS Num: BYLFQ LIIN: 00F045135 Product ID: N840-7 NITRILOTRIACETIC ACID MFN: 01 Responsible Party Cage: 60928 Name: ALDRICH CHEMICAL CO SUB OF SIGMA-ALDRICH Address: 1001 W ST PAUL AVE Box: 355 City: MILWAUKEE WI 53233-5000 Info Phone Number: 414-273-3850 Emergency Phone Number: 414-273-3850 Review Ind: Y Published: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 60928 Name: ALDRICH CHEMICAL CO INC Address: 1001 WEST ST PAUL AVE Box: 355 City: MILWAUKEE WI 53233 ======================================================= Contractor Summary ======================================================= Cage: 60928 Name: ALDRICH CHEMICAL CO INC Address: 1001 WEST ST PAUL AVE Box: 355 City: MILWAUKEE WI 53233 Phone: 414-273-3850 ======================================================= Ingredients ======================================================= Cas: 139-13-9 RTECS #: AJ0175000 Name: NITRILOTRIACETIC ACID, NTA, TRIGLYCINE (SUSPECTED CARCINOGEN BY IARC & NTP, IARC GROUP 2B) *95-3* % Wt: 99 ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50 (RAT): 1100 MG/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: HARMFUL IF SWALLOWED, INHALED/ABSORBED. MAY CAUSE IRRITATION. TOXIC. MAY CAUSE CANCER. Explanation Of Carcinogenicity: SEE INGREDIENTS Signs And Symptions Of Overexposure: IRRITATION. First Aid: EYES/SKIN: FLUSH IMMEDIATELY W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. WEAR DISPOSABLE COVERALLS & DISCARD THEM AFTER USE. SWEEP UP, PLACE IN A BAG & HOLD FOR WASTE DISPOSAL. VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISSOLVE/MIX THE MATERIAL W/A COMBUSTIBLE SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: HARMFUL SOLID. KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. Other Precautions: DON'T BREATHE DUST. AVOID ALL CONTACT. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY, CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM. Fire Fighting Procedures: WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves: CHEMICAL RESISTANT Eye Protection: SAFETY GOGGLES Other Protective Equipment: PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH. Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: 474.8F Appearance and Odor: WHITE TO OFF-WHITE POWDER ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG BASES. Hazardous Decomposition Products: TOXIC FUMES OF CO, CO2, NITROGEN OXIDES. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: N840-7 NITRILOTRIACETIC ACID Cage: 60928 Company Name: ALDRICH CHEMICAL CO INC Street: 1001 WEST ST PAUL AVE PO Box: 355 City: MILWAUKEE WI Zipcode: 53233 Health Emergency Phone: 414-273-3850 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: HARMFUL IF SWALLOWED, INHALED/ABSORBED. MAY CAUSE IRRITATION. TOXIC. MAY CAUSE CANCER. IRRITATION. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.