SIGMA CHEMICAL CO -- NONIDET P-40, N3516 ======================================================= MSDS Safety Information ======================================================= FSC: 6810 MSDS Date: 01/01/1999 MSDS Num: CJXMY LIIN: 00N093263 Product ID: NONIDET P-40, N3516 MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL CO Box: 14508 City: ST LOUIS MO 63178 Info Phone Number: 314-771-5765 Emergency Phone Number: 314-771-5765 Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST City: ST LOUIS MO 63178 Phone: 314-771-5765 ======================================================= Ingredients ======================================================= Cas: 9036-19-5 RTECS #: MD0907600 Name: NONIDET P 40 Percent by Wt: 100. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50: (ORAL,RAT) 4190 MG/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE EFFECTS: MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. CAUSES SEVERE EYE IRRITATION. CAUSES SKIN IRRITATION. THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. First Aid: IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. IN CASE OF SKIN CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHI NG AND SHOES. CALL A PHYSICIAN. IF INHALED, REMOVE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT, CALL A PHYSICIAN. IN CASE OF CONTACT WITH EYES, FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MIN UTES. ASSURE ADEQUATE FLUSHING BY SEPARATING THE EYELIDS WITH FINGERS. CALL A PHYSICIAN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR NIOSH APPRVD RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SI TE AFTER MATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED RESPIRATOR. Ventilation: MECHANICAL EXHAUST REQUIRED. Protective Gloves: COMPATIBLE CHEMICAL-RESISTANT GLOVES. Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.06 Solubility in Water: SOLUBLE (WITH HAZE) Appearance and Odor: LIQUID. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Hazardous Decomposition Products: TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= Toxicological Information: SEE HEALTH HAZARDS. RTECS #: MD0907600. GLYCOLS, POLYETHENE, MONO((1,1,3,3-TETRAMETHYLBUTYL)PHENYL) ESTER. IRRITATION DATA: EYE RBT 1% SEV JAPMA8 38,428,1949. TOXICITY DATA: ORL-RAT LD50:4190 MG/KG FC TOD7 22,665,1984. IPR-RAT LD50:770 MG/KG FCTOD7 22,665,1984. ORL-MUS LD50:3500 MG/KG JAPMA8 38,428,1949. IVN-MUS LD50:70 MG/KG JAPMA8 38,428,1949. ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL S UBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. ======================================================= Ecological Information ======================================================= Ecological: DATA NOT YET AVAILABLE. ======================================================= MSDS Transport Information ======================================================= Transport Information: CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. ======================================================= Regulatory Information ======================================================= Federal Regulatory Information: EUROPEAN INFO. CAUTION: SUBSTANCE NOT YET FULL TESTED. IRRITANT R 36/38 IRRITATING TO EYES AND SKIN. R 41 RISK OF SERIOUS DAMAGE TO EYES. S 26 IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLEN TY OF WATER AND SEEK MEDICAL ADVICE. S 36 WEAR SUITABLE PROT CLTHG. REVIEWS, STANDARDS, AND REGULATIONS. OEL=MAK. NOHS 1974: HZD 814235; NIS 250; TNF 42544; NOS 129; TNE 388256. NOES 1983: HZD X5849; NIS 227; TNF 35278; NOS 160; TNE 687698; TFE 226942. EPA TSCA SECTION 8 (B) CHEMICAL INVENTORY. EPA TSCA SECTION 8 (D) UNPUBLISHED HEALTH/SAFETY STUDIES. EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998. ======================================================= Other Information ======================================================= Other Information: LABEL PRECAUTIONARY STATEMENTS. IRRITANT. IRRITATING TO EYES AND SKIN. RISK OF SERIOUS DAMAGE TO EYES. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. WEA R SUITABLE PROTECTIVE CLOTHING. ======================================================= HAZCOM Label ======================================================= Product ID: NONIDET P-40, N3516 Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY Street: 3050 SPRUCE ST City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765 Label Required IND: Y Date Of Label Review: 12/29/1999 Status Code: A Origination Code: F Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Severe Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: IRRITANT. ACUTE EFFECTS: MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. CAUSES SEVERE EYE IRRITATION. RISK OF SERIOUS DAMAGE TO EYES. CAUSES SKIN IRRITATION. CHRONIC: NONE LISTED BY MAN UFACTURER. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.