SIGMA CHEMICAL CO -- OCTYL-SEPHAROSE CL-4B, O6001 ======================================================= MSDS Safety Information ======================================================= FSC: 6550 MSDS Date: 01/01/1999 MSDS Num: CJTGC LIIN: 00N092571 Product ID: OCTYL-SEPHAROSE CL-4B, O6001 MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL CO Box: 14508 City: ST LOUIS MO 63178 Info Phone Number: 314-771-5765 Emergency Phone Number: 314-771-5765 Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST City: ST LOUIS MO 63178 Phone: 314-771-5765 ======================================================= Ingredients ======================================================= Cas: 69106-60-1 Name: OCTYL-SEPHAROSE CL-4B Percent by Wt: 100. ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. MAY CAUSE IRRITATION. THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. First Aid: INGESTION: IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. SKIN: IN CASE OF SKIN CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. REMOVE CO NTAMINATED CLOTHING AND SHOES. CALL A PHYSICIAN. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT, CALL A PHYSICIAN. EYES: IN CASE OF CONTACT WITH EYES, FLUSH WITH COPIOUS A MOUNTS OF WATER FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING THE EYELIDS WITH FINGERS. CALL A PHYSICIAN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: CC Flash Point: =35.C, 95.F Extinguishing Media: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N) TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard: FLAMMABLE LIQUID. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR. Ventilation: MECHANICAL EXHAUST. Protective Gloves: CHEMICAL-RESISTANT GLOVES. Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPROVED EYE WASH AND DELUGE SHOWER (FP N). OTHER PROTECTIVE CLOTHING. ======================================================= Physical/Chemical Properties ======================================================= Appearance and Odor: SUSPENSION. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. Hazardous Decomposition Products: NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= Toxicological Information: SEE HEALTH HAZARDS. ======================================================= Ecological Information ======================================================= Ecological: DATA NOT YET AVAILABLE. ======================================================= MSDS Transport Information ======================================================= Transport Information: CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. ======================================================= Regulatory Information ======================================================= Federal Regulatory Information: EUROPEAN INFORMATION - CAUTION: SUBSTANCE NOT YET FULLY TESTED. R 10 FLAMMABLE. S 16 KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. ======================================================= Other Information ======================================================= Other Information: LABEL PRECAUTIONARY STATEMENTS: FLAMMABLE. KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. ======================================================= HAZCOM Label ======================================================= Product ID: OCTYL-SEPHAROSE CL-4B, O6001 Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY Street: 3050 SPRUCE ST City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765 Label Required IND: Y Date Of Label Review: 10/19/1999 Status Code: A Origination Code: F Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMMABLE LIQUID. MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. MAY CAUSE IRRITATION. CHRONIC: NONE LISTED BY MANUFACTURER. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.