SIGMA CHEMICAL CO -- PARAROSANILINE CHLORIDE, P3750 ======================================================= MSDS Safety Information ======================================================= FSC: 6810 MSDS Date: 11/01/1995 MSDS Num: CGZHP LIIN: 00N079479 Product ID: PARAROSANILINE CHLORIDE, P3750 MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL CO Box: 14508 City: ST LOUIS MO 63178 Info Phone Number: 314-325-3010 Emergency Phone Number: 314-771-5765 Published: Y ======================================================= Contractor Summary ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST City: ST LOUIS MO 63178 Phone: 314-771-5765 ======================================================= Ingredients ======================================================= Cas: 569-61-9 RTECS #: CX9850100 Name: BENZENEAMINE, 4-((4-AMINOPHENYL) (4-IMINO-2,5- CYCLOHEXADIEN-1-YLIDENE)METHYL), MONOHYDROCHLORIDE; (BASIC FUCHSIN) OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Name: SUPDAT:PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: ACUTE: HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THRU SKIN. CAUSES EYE & SKIN IRRITATION. MATL IS IRRITATING TO MUCOUS MEMBRANES & UPPER RESP TRACT. CHRONIC: MAY ALTER GENETIC MATERIAL. TARGET ORGAN( S): THYROID, PITUITARY. THIRTEEN WEEK STUDIES IN RATS IDENTIFIED THYROID & PITUITARY GLAND AS TARGET (EFTS OF OVEREXP) Explanation Of Carcinogenicity: BASIC FUCHSIN:IARC MONO ON EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 57, PG 215; 1993:GROUP 2B. NTP 7TH ANNUAL (SUPDAT) Signs And Symptions Of Overexposure: HLTH HAZ: SITES. RATS OF BOTH SEXES SHOWED SUBCUTANEOUS FIBROMAS, THYROID GLAND FOLLICULAR CELL ADENOMAS & CARCINOMAS, & ZYMBAL GLAND CARCINOMAS. MALE RATS SHOWED SHOWED SQUAMOUS CELL CARCINOMAS, TRIC HOEPITHELIOMAS & SEBACEOUS ADENOMAS OF SKIN. HEPATOCELLULAR CARCINOMAS APPEARED IN MALE RATS & BOTH SEXES OF (SUPDAT) Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES/SKIN:IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR @ LST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. INHAL:REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BR EATHING IS DIFFICULT, GIVE OXYGEN. INGEST:WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. DISCARD CONTAMINATED CLOTHING AND SHOES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: EVAC AREA. WEAR NIOSH APPRVD SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. WEAR DISPOSABLE COVERALLS & DISCARD THEM AFTER USE. SWEEP UP, PLACE IN A BAG & HOLD FOR WASTE DISPOSAL. VENTILATE AREA & WASH SPI LL SITE AFTER MATL PICKUP IS COMPLETE. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL WITH COMBUSTIBLE SOLVENT & BURN IN CHEMICAL INCINERATOR EQUIPPED WITH AFTERBURNER & SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. Handling And Storage Precautions: DO NOT BREATHE DUST. AVOID ALL CONTACT. AVOID PRLNGD/RPTD EXPOSURE. IRRITANT. MUTAGEN. HARMFUL SOLID. KEEP TIGHTLY CLOSED. STORE IN COOL DRY PLACE. Other Precautions: TOXIC. KEEP CONTAINER TIGHTLY CLOSED IN A COOL WELL VENTILATED PLACE. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR. Ventilation: USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves: CHEMICAL-RESISTANT GLOVES. Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health: EXPLAN OF CARCIN:RPT ON CARCINS, 1994:KNOWN TO BE CARCIN. EFTS OF OVEREXP:MICE. ADRENAL GLAND PHEOCHROMOCYTOMAS/MALIGNANT PHEOCHROMOCYTOMAS & HEMATOPOIETIC SYS TUMORS OCCURRED IN FEMALE MICE. INCR INC IDENCES OF MAMMARY GLAND TUMORS OCCURRED IN FEMALE RATS. TO BEST OF MFR'S KNOWLEDGE, CHEM, PHYSICAL, & TOX ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: >514F,>268C Evaporation Rate & Reference: NOT KNOWN Solubility in Water: NOT KNOWN Appearance and Odor: DARK-GREEN CRYSTALLINE POWDER. ======================================================= Reactivity Data ======================================================= Stability Indicator: NO Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: TOXIC FUMES OF:CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE GAS, NITROGEN OXIDES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: PARAROSANILINE CHLORIDE, P3750 Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY Street: 3050 SPRUCE ST City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765 Label Required IND: Y Date Of Label Review: 09/18/1997 Status Code: C Label Date: 09/18/1997 Origination Chronic Hazard IND: Y Eye Protection IND: YES Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THRU SKIN. CAUSES EYE & SKIN IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. CHRONIC: CANCER HAZARD. CONTAINS BASIC FUCHSIN, WHICH IS LISTED AS A HUMAN CARCINOGEN (FP N). MAY ALTER GENETIC MATERIAL. TARGET ORGAN(S): THYROID, PITUITARY. THIRTEEN WEEK STUDIES IN RATS IDENTIFIED THYROID & PITUITARY GLAND AS TARGET SIT ES. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.