Material Safety Data Sheet GelCodeŽ Reducer Base Reagent 0942 1851150 1880950 Pierce Chemical Company P.O. Box 117 Rockford, IL 61105 USA 815.968.0747 CALL CHEMTREC: 800.424.9300 OUTSIDE US: 202.483.7616 Pierce Chemical Company P.O. Box 117 Rockford, IL 61105 USA 815.968.0747 4/30/2002 5/24/2002 Common Name Supplier Manufacturer Code MSDS# Validation Date Print Date In Case of Emergency Section 1. Chemical Product and Company Identification Responsible Name Pierce Administration Section 2. Composition and Information on Hazardous (OSHA) Ingredients 1) Strong base 20-35 CEIL: 2 (ppb) from ACGIH (TLV) [United States] [1994] Inhalation STEL: 2 CEIL: 2 (mg/m3) from NIOSH [United States] [1994] Inhalation TWA: 2 CEIL: 2 (mg/m3) from OSHA (PEL) [United States] [1989] Inhalation CAS # % by Weight Exposure Limits Name Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion. Emergency Overview Medical Conditions Aggravated by Overexposure: Section 3. Hazards Identification Routes of Entry Potential Acute Health Effects Carcinogenic Effects Data Do not get in eyes, on skin or on clothing. Avoid contact with eyes, skin and clothing. Do not ingest. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. No specific information is available in our database regarding the other toxic effects of this material for humans.Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. CARCINOGENIC EFFECTS: Classified None. by NIOSH [Strong base]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Review the most current and approved institutional guideline, protocol, standard operating procedure(s) and MSDS(s) for the proper handling of institutional materials/equipment associated with the use of this Pierce product. DANGER! CAUSES SEVERE RESPIRATORY TRACT, EYE AND SKIN BURNS. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, MUCOUS MEMBRANES, RESPIRATORY TRACT, SKIN, EYES, EYE, LENS OR CORNEA. MAY BE HARMFUL IF INHALED OR SWALLOWED. Continued on Next Page GelCodeŽ Reducer Base Reagent Page: 2/5 Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. See Toxicological Information (section 11) EU Regulations R22- Harmful if swallowed. R35- Causes severe burns. R40- Possible risks of irreversible effects. S1/2- Keep locked up and out of the reach of children. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37- Wear suitable protective clothing and gloves. S39- Wear eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S46- If swallowed, seek medical advice immediately and show this container or label. Corrosive SKIN: Wash contaminated skin with soap and water. EYES: Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek medical attention. Inhalation: Move exposed person to fresh air. If irritation persists, get medical attention. Ingestion: Do not induce vomiting. If affected person is conscious, give plenty of water to drink. Seek medical attention. Section 4. First Aid Measures Non-flammable. Not applicable. Not applicable. Not applicable. Section 5. Fire Fighting Measures Flammability of the Product Flash Points Fire Hazards in Presence of Various Substances Fire Fighting Media and Instructions Not applicable. Protective Clothing (Fire) Continued on Next Page GelCodeŽ Reducer Base Reagent Page: 3/5 Large Spill and Leak Corrosive liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Section 6. Accidental Release Measures Small Spill and Leak Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If necessary: Neutralize the residue with a dilute solution of acetic acid. Keep container tightly closed. Keep container in a cool, well-ventilated area. Avoid contact with eyes, skin, and clothing. Do not ingest. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Section 7. Handling and Storage Handling Storage Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Engineering Controls Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Face shield. Full suit. Gloves. Boots. Personal Protection Eyes Body Respiratory Hands Feet Protective Clothing (Pictograms) Consult local authorities for acceptable exposure limits. Section 8. Exposure Controls/Personal Protection The lowest known value is 100°C (212°F) (Milli-Q Water). Liquid. Basic. May start to solidify at -0.1°C (31.8°F) based on data for: Milli-Q Water. Weighted average: 1.19 (Water = 1) The highest known value is 0.62 (Air = 1) (Milli-Q Water). The highest known value is 2.3 kPa (@ 20°C) (Milli-Q Water). See solubility in water. Easily soluble in cold water, hot water. Not applicable. Not available. Not available. Not available. Boiling/Condensation Point Melting/Freezing Point 0.36 (Milli-Q Water) compared to Butyl acetate. Physical State and Appearance Molecular Weight pH (1% Soln/Water) Specific Gravity Vapor Pressure Vapor Density Evaporation Rate Dispersion Properties Solubility Odor Taste Color Section 9. Physical and Chemical Properties Continued on Next Page GelCodeŽ Reducer Base Reagent Page: 4/5 The product is stable. Slightly reactive to reactive with metals, acids. Section 10. Stability and Reactivity Stability and Reactivity Incompatibility with Various Substances Hazardous Decomposition Products Not available. Extremely hazardous in case of eye contact (corrosive), of inhalation (lung corrosive). Very hazardous in case of eye contact (corrosive), of inhalation (lung corrosive). Slightly hazardous in case of ingestion, of inhalation (lung sensitizer). CARCINOGENIC EFFECTS: Classified None. by NIOSH [Strong base]. Section 11. Toxicological Information Chronic Effects on Humans Other Toxic Effects on Humans The products of degradation are less toxic than the product itself. Section 12. Ecological Information Toxicity of the Products of Biodegradation Waste must be disposed of in accordance with federal, state and local environmental control regulations. Not available. Waste Information Waste Stream Section 13. Disposal Considerations Consult your local or regional authorities. Section 14. Transport Information Contact Pierce for all transport information. U.S. Federal Regulations CLASS: Target organ effects. CLASS: Corrosive material HCS Classification Section 15. Regulatory Information TSCA 8(b) inventory: Sodium Hydroxide 50% Solution Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: Strong base Clean air act (CAA) 112 accidental release prevention: No products were found. Clean air act (CAA) 112 regulated flammable substances: No products were found. Clean air act (CAA) 112 regulated toxic substances: No products were found. CEPA DSL: Milli-Q Water; Strong base WHMIS (Canada) WHMIS CLASS E: Corrosive liquid. International Regulations Not available. EINECS SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: Strong base SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Strong base: immediate health hazard SARA 313 toxic chemical notification and release reporting: No products were found. Continued on Next Page GelCodeŽ Reducer Base Reagent Page: 5/5 Pennsylvania RTK: Strong base: (environmental hazard, generic environmental hazard) Massachusetts RTK: Strong base New Jersey: Strong base California prop. 65: No products were found. State Regulations Australia (NICNAS): Milli-Q Water; Strong base Korea (TCCL): Milli-Q Water; Strong base Philippines (RA6969): Milli-Q Water; Strong base R20/22- Harmful by inhalation and if swallowed. R35- Causes severe burns. R40- Possible risks of irreversible effects. DSCL (EEC) International Lists Section 16. Other Information Validated by Pierce Administration on 4/30/2002. Verified by Pierce Administration. Printed 5/24/2002. Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Hazardous Material Information System (U.S.A.) 2 0 1 1 0 2 * National Fire Protection Association (U.S.A.) Health Specific Hazard Reactivity Fire Hazard Health Fire Hazard Reactivity Personal Protection