SIGMA CHEMICAL COMPANY -- A4553 S-ADENOSYL-L-METHIONINE-METHYL-3H ======================================================= MSDS Safety Information ======================================================= FSC: 6550 MSDS Date: 08/31/1994 MSDS Num: BWTPG LIIN: 00F038249 Product ID: A4553 S-ADENOSYL-L-METHIONINE-METHYL-3H MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST Box: 14508 City: SAINT LOUIS MO 63178-5000 Info Phone Number: 314-771-5765/800-325-5052 Emergency Phone Number: 314-771-5765/800-325-5052 Review Ind: Y Published: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST Box: 14508 City: ST LOUIS MO 63178 ======================================================= Contractor Summary ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST Box: 14508 City: ST LOUIS MO 63178 Phone: 314-771-5765 ======================================================= Ingredients ======================================================= Cas: 111093-45-9 Name: S-ADENOSYL-L-METHIONINE-METHYL-3H (94-4) ----------------------------- Cas: 64-17-5 RTECS #: KQ6300000 Name: ETHANOL (ETHYL ALCOHOL), TECSOL, ALCOHOL % Wt: 10 Other REC Limits: 1900 MG/CUM OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: MAY BE HARMFUL BY INHALATION, INGESTION, SKIN ABSORPTION. MAY CAUSE IRRITATION. CONTAINS A RADIOACTIVE ISOTOPE WHICH MAY PRODUCE CANCER & GENETIC MUTATION. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: IRRITATION. First Aid: INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS & HEAVY RUBBER GLOVES. HANDLE AS A RADIOACTIVE SPILL. ABSORB ON SAND/VERMICULITE & PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISPOSE OF MATERIAL AS RADIOACTIVE WASTE IAW/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: FOR INTERNAL USE ONLY. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY, CO2, DRY CHEMICAL POWDER, APPROPRIATE FOAM. Fire Fighting Procedures: WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard: COMBUSTIBLE ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: MECHANICAL EXHAUST REQUIRED Protective Gloves: CHEMICAL RESISTANT Eye Protection: SAFETY GOGGLES Other Protective Equipment: PROTECTIVE CLOTHING. Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. ======================================================= Physical/Chemical Properties ======================================================= Appearance and Odor: LIQUID ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: A4553 S-ADENOSYL-L-METHIONINE-METHYL-3H Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY Street: 3050 SPRUCE ST PO Box: 14508 City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765/800-325-5052 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: MAY BE HARMFUL BY INHALATION, INGESTION, SKIN ABSORPTION. MAY CAUSE IRRITATION. CONTAINS A RADIOACTIVE ISOTOPE WHICH MAY PRODUCE CANCER & GENETIC MUTATION. IRRITATION. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.