Material Safety Data Sheet Safeclear II ACC# 89682 Section 1 - Chemical Product and Company Identification MSDS Name: Safeclear II Catalog Numbers: BP2695-1G, BP2695-4, 23044192 Synonyms: None. Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 Section 2 - Composition, Information on Ingredients CAS#Chemical NamePercentEINECS/ELINCS 8052-41-3Stoddard solvent<100 232-489-3 64741-66-8Naphtha (petroleum), light alkylate<100 265-068-8 68551-16-6C9-11-isoalkanes<100 271-365-3 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: colorless liquid. Flash Point: 75 deg F. Warning! Flammable liquid and vapor. Aspiration hazard if swallowed. Can enter lungs and cause damage. May cause eye and skin irritation. May cause respiratory tract irritation. May cause central nervous system depression. Target Organs: Central nervous system. Potential Health Effects Eye: May cause eye irritation and possible burns. Skin: May cause skin irritation. May be absorbed through the skin. Ingestion: Aspiration hazard. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Chronic: Prolonged or repeated exposure may cause nausea, dizziness, and headache. Section 4 - First Aid Measures Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately. Skin: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Possible aspiration hazard. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May be ignited by heat, sparks, and flame. Vapors may form an explosive mixture with air. Containers may explode when heated. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out. Flash Point: 75e deg F ( 23.89 deg C) Autoignition Temperature: Not applicable. Explosion Limits, Lower:0.6 Upper: 7.0 NFPA Rating: (estimated) Health: 1; Flammability: 3; Instability: 0 Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits Chemical NameACGIHNIOSHOSHA - Final PELs Stoddard solvent100 ppm TWA 350 mg/m3 TWA 20000 mg/m3 IDLH 500 ppm TWA; 2900 mg/m3 TWA Naphtha (petroleum), light alkylatenone listed none listed none listed C9-11-isoalkanesnone listed none listed none listed OSHA Vacated PELs: Stoddard solvent: 100 ppm TWA; 525 mg/m3 TWA Naphtha (petroleum), light alkylate: No OSHA Vacated PELs are listed for this chemical. C9-11-isoalkanes: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Liquid Appearance: colorless Odor: hydrocarbon-like pH: Not available. Vapor Pressure: Not available. Vapor Density: >1 Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: 284-335F Freezing/Melting Point:Not available. Decomposition Temperature:Not available. Solubility: Negligible. Specific Gravity/Density:Not available. Molecular Formula:Not available. Molecular Weight:Not available. Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Ignition sources, excess heat. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Oxides of carbon. Hazardous Polymerization: Has not been reported Section 11 - Toxicological Information RTECS#: CAS# 8052-41-3: WJ8925000 CAS# 64741-66-8: QK7970000 CAS# 68551-16-6 unlisted. LD50/LC50: CAS# 8052-41-3: Draize test, rabbit, eye: 500 mg/24H Moderate; CAS# 64741-66-8: CAS# 68551-16-6: Carcinogenicity: CAS# 8052-41-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 64741-66-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 68551-16-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Epidemiology: Epidemiological studies involving petroleum refinery workers indicate persons with routine exposure to petroleum or one of its constituents may be at an increased risk to the development of benign neoplasms, digestive tract cancer, and skin cancer. Teratogenicity: No information found. Reproductive Effects: No information found. Mutagenicity: No information found. Neurotoxicity: No information found. Other Studies: Section 12 - Ecological Information No information available. Section 13 - Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. Section 14 - Transport Information US DOTCanada TDG Shipping Name:PETROLEUM DISTILLATES, N.O.S.PETROLEUM DISTILLATES NOS (NAPTHA, PETROLEUM) Hazard Class:33 UN Number:UN1268UN1268 Packing Group:IIIII Additional Info:FP23.89C Section 15 - Regulatory Information US FEDERAL TSCA CAS# 8052-41-3 is listed on the TSCA inventory. CAS# 64741-66-8 is listed on the TSCA inventory. CAS# 68551-16-6 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs None of the chemicals in this material have an RQ. SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS # 8052-41-3: acute, chronic, flammable. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 8052-41-3 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. CAS# 64741-66-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 68551-16-6 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California Prop 65 California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T Risk Phrases: R 20/22 Harmful by inhalation and if swallowed. R 45 May cause cancer. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 23 Do not inhale gas/fumes/vapour/spray. S 24/25 Avoid contact with skin and eyes. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 51 Use only in well-ventilated areas. S 53 Avoid exposure - obtain special instructions before use. WGK (Water Danger/Protection) CAS# 8052-41-3: No information available. CAS# 64741-66-8: No information available. CAS# 68551-16-6: 1 Canada - DSL/NDSL CAS# 8052-41-3 is listed on Canada's DSL List. CAS# 64741-66-8 is listed on Canada's DSL List. CAS# 68551-16-6 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of B2. Canadian Ingredient Disclosure List CAS# 8052-41-3 is listed on the Canadian Ingredient Disclosure List. Section 16 - Additional Information MSDS Creation Date: 1/09/1998 Revision #7 Date: 3/10/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.