Formula: B422 1 Material Safety Data Sheet HMIS® HEALTH FLAMMABILITY 1 1 REACTIVITY PERSONAL PROTECTION 0 None Identity: SCRUBS IN-A-BUCKET® Formula: B422 Part numbers: 42201, 42210, 42230, 42256, 42272 Note: Blank spaces are not permitted. If any item is not applicable, or no information is available, the space must be marked to indicate that. SECTION 1: Company Identification Manufacturer's Name ITW Dymon Emergency Telephone Number 1-800-535-5053 Address (Number, Street, City, State, and ZIP Code) 805 East Old 56 Highway International Emergency Telephone Number 1-352-323-3500 Olathe, Kansas 66061 Telephone Number for Information 1-913-397-9889 Signature of Preparer (Optional) Regulatory Dept. SECTION 2: Ingredients/Identity Information Components (Chemical Identity, Other Limits Common Name(s)) CAS No. OSHA PEL ACGIH-TLV Recommended % (Opt.) Water 7732-18-5 None None None 60 - 100% D-Limonene (R-p-mentha-1,8-diene) 5989-27-5 None None 30 ppm (Manu.) 5 - 13% Ethoxylated Alcohols (C12-15 pareth-7) 68131-39-5 None None None 1 - 5% Sodium Lauryl Sulfate 151-21-3 None None None 1 - 5% Fragrance Mixture None None None 1 - 5% In accordance with 29 CFR 1910.1200 this product does not contain any substances defined as hazardous by this standard. Any substance listed as hazardous by the States of California, Florida, Illinois, Michigan, New Jersey, Ohio, Pennsylvania or Texas is described above if known present in regulated concentrations. SECTION 3: Hazards Identification Route(s) of Entry Eyes? Yes Inhalation? No Skin? Yes Ingestion? Yes Acute Health Hazards - Caution. May cause mild eye or skin irritation. Chronic Health Hazards - None known Carcinogenicity: Chemical: None OSHA: No NTP: No IARC: No Signs and Symptoms of Exposure - Redness, tearing or burning in eyes. Redness, burning, drying or cracking of skin. Irritation of the throat or stomach, nausea, vomiting, and diarrhea if swallowed. Medical Conditions Generally Aggravated by Exposure - Pre-existing skin conditions such as dermatitis may be adversely affected by this and other oil and grease effective cleaners. SECTION 4: Emergency and First Aid Procedures: Eyes - Flush with plenty of water for at least 15 minutes lifting eyelids to insure complete removal. See a physician immediately. Ingestion - Not a likely exposure route. If a large quantity of liquid is swallowed, do not induce vomiting, call a physician or poison control center immediately. Inhalation - Unlikely route as liquid is impregnated on a towel, minimizing exposure via this route. If overexposed move into fresh air. If symptoms develop seek medical attention. Skin - None usually required. Material is designed for skin cleansing. If symptoms develop seek medical attention. SECTION 5: Fire Fighting Measures Flash Point (Method Used) None to boiling (PMCC) Solution on Towel Flammable Limits No Data LEL No Data UEL No Data Formula: B422 2 Extinguishing Media – Use carbon dioxide, dry chemical, foam, fog or water spray. Special Fire Fighting Procedures - Keep containers cool and vapors down with water spray. Prevent runoff from entering sewers and public waterways. Wear SCBA in chemical fires. Hazardous Products of Combustion-Carbon dioxide, carbon monoxide, various hydrocarbons, hydrogen sulfide, sulfur dioxide, and soot. Unusual Fire and Explosion Hazards - None known. SECTION 6: Accidental Release Measures Small Spill - Wipe up small releases with a dry absorbent cloth or other absorbent material. Large Spill – Absorb liquid with vermiculite, absorbent cloth, or other absorbent material. Prevent material from entering sewers or drains. Ventilate area and block traffic. Transfer contaminated material into suitable container for proper disposal. SECTION 7: Handling and Storage Handling - Do not allow towel contact with eyes. For external use only. Not for use around the mouth or eyes for an extended period of time. Do not smoke while using. Do not contaminate water, food or feed by use or storage. Follow label directions carefully. Storage – Store in a cool well ventilated area. Keep away from heat sources. Keep out of reach of children. Keep container tightly sealed when not in use. SECTION 8: Exposure Controls / Personal Protection Eye Protection – None necessary. Do not allow towel to directly contact eyes. Skin Protection – None necessary. Product is designed for direct skin use. Respiratory Protections – Not usually necessary. Use with adequate ventilation. Use NIOSH/MSHA approved respirator if PELs or TLVs are exceeded. Engineering Controls – Ventilation not usually necessary but should be provided in the event of overexposure. SECTION 9: Physical and Chemical Properties Appearance and Odor: Opaque white liquid with a fresh citrus scent saturated onto towels. PH 9.8 + 0.5 Specific Gravity (70oF) 0.986 Boiling Point: 212oF Melting Point: No Data Evaporation Rate (Butyl Acetate = 1) No Data Vapor Pressure (mm-Hg @ 70oF) No Data Vapor Density (AIR = 1) > 1 Solubility in Water Dispersible Volatile Organic Compounds (VOCs) 78.97 grams per liter or 8.0% by weight VOCs SECTION 10: Stability and Reactivity Hazardous Polymerization – This product will not undergo hazardous polymerization. Hazardous Decomposition or Byproducts – Carbon dioxide, carbon monoxide, hydrogen sulfide, sulfur dioxide, and soot. Chemical Stability - Stable Incompatibility (Materials to Avoid) - Strong oxidizers and acids. SECTION 11: Toxicological Information D’Limonene: Acute Dermal LD50 >5g/kg, rabbit Acute Oral LD50 >5g/kg, rat Ethoxylated Alcohols: Acute Dermal LD50 2g/kg, rabbit Acute Oral LD50 2.5-5g/kg, rat SECTION 12: Ecological Information Formula: B422 3 Ethoxylated Alcohols: 96 hr fathead minnow static acute LC50: 0.5 mg/L 48 hr Daphnia pulex static acute EC50: 0.76 mg/L SECTION 13: Disposal Consideration Disposal Method - Dispose of in accordance with all applicable local, state, and federal regulations. RCRA Waste Information – If this product becomes a waste, it would not be a hazardous waste as defined by RCRA (40 CFR 261). However the waste should be properly characterized to evaluate whether its composition has been modified prior to disposal. SECTION 14: Transport Information DOT Information – 49 CFR 172.101 Proper Shipping Description: Not Regulated Hazard Class: None Identification Number: None Packing Group: None Water Transportation: Proper Shipping Description: Not Regulated Hazard Class: None Identification Number: None Packing Group: None Air Transportation: Proper Shipping Description: Not Regulated Hazard Class: None Identification Number: None Packing Group: None Marine Pollutants: None SECTION 15: Regulatory Information US Federal Regulations: TSCA (Toxic Substances Control Act) Status All ingredients are on the TSCA inventory or are not required to be listed on the TSCA inventory. CERCLA RQ – 40 CFR 302.4 (a) None Listed SARA 313 Components – 40 CFR 372.65 None State and Local Regulations: California Proposition 65 None NSF Registration Category Code – E4 Section 16: Additional Information Formula: B422 4 Date Prepared: Rev. 3 – 11/21/06 – NSF Category Code added. Rev. 2 – 09/05/06 Rev. 1 – 08/19/05 WARNING! The use of this product is beyond the control of the manufacturer; therefore, no guarantee, expressed or implied, is made as to the effects of such or the results to be obtained if not used in accordance with directions or established safe practice. The user must assume all responsibility, including injury or damage, resulting from its misuse as such, or in combination with other materials. The manufacturer warrants only that this product meets the manufacturer's specifications for such product. THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AS TO DESCRIPTION, QUALITY, MERCHANTABILITY. FITNESS FOR ANY PARTICULAR PURPOSE, PRODUCTIVENESS, OR ANY OTHER MATTER, OF THIS PRODUCT. THE MANUFACTURER SHALL BE IN NO WAY RESPONSIBLE FOR THE IMPROPER USE OF THIS PRODUCT. The sole and exclusive remedy against the manufacturer for breach of warranty shall be reimbursement of the purchase price of the product in the event that a defective condition of the product shall be found to exist. NO OTHER REMEDY (INCLUDING BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY TO PERSON OR PROPERTY OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE.