Revision Date: 05/04/2001 PRODUCT NAME: MATERIAL SAFETY DATA SHEET PRODUCT NUMBER: EC-840 SequaGel Diluent Aqueous solution of urea MANUFACTURER: National Diagnostics, Inc 305 Patton Drive Atlanta, GA 30336 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION CHEMICAL NAMES/ DESCRIPTION: TELEPHONE NUMBER: (800) 526-3867 (404) 699-2121 EMERGENCY NUMBER: CHEMTREC (800) 424-9300 2. COMPOSITION / INFORMATION ON INGREDIENTS Component Urea % Comp CAS # EINECS # 200-315-5 57-13-6 40 - 50 Clear, colorless solution TLV (units) 10 mg/m3, 8-hour TWA SequaGel Diluent 3. HAZARDS IDENTIFICATION APPEARANCE AND ODOR: EMERGENCY OVERVIEW - IMMEDIATE HAZARD CAUSES IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. UREA IS HARMFUL IF SWALLOWED OR INHALED. EMERGENCY OVERVIEW - CHRONIC HAZARD WARNING LONG-TERM EXPOSURE TO HIGH AIRBORNE CONCENTRATIONS CAN LEAD TO PROTEIN METABOLISM DISTURBANCES, MODERATE EMPHYSEMA, AND CHRONIC WEIGHT LOSS. INHALATION POTENTIAL HEALTH EFFECTS Causes irritation to the respiratory tract. INGESTION Causes irritation to the garstrointestinal tract. SKIN Causes irritation to the skin. EYES Causes irritation to the eyes. INHALATION SIGNS AND SYMPTOMS 0F OVEREXPOSURE Symptoms may include coughing, shortness of breath. May be absorbed into the bloodstream with symptoms similar to ingestion. INGESTION Symptoms may include nausea, vomiting, and diarrhea. May also cause headache, confusion and electrolyte depletion. SKIN Symptoms include redness, itching, and pain. EYES Redness, itching and pain. CARCINOGENICITY Page 1 Not listed as a carcinogen by NTP or IARC. MUTAGENICITY No information found. REPRODUCTIVE TOXICITY No information found. TERATOGENIC EFFECTS No information found. ROUTES OF ENTRY Ingestion and inhalation. TARGET ORGAN STATEMENT Supersensitive individuals with skin or eye problems, kidney impairment or asthmatic condition should have physician's approval before exposure to urea dust. 4. FIRST AID MEASURES INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. INGESTION: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician. SKIN: Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. EYES: Immediately flush eyes with plenty of water for at least fifteen minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. FLAMMABLE LIMITS: N.A. AUTOIGNITION TEMPERATURE: N.A. 5. FIRE FIGHTING MEASURES FLASH POINT: N.A. FLASH POINT METHOD: N.A. EXTINGHISHING MEDIA Use media appropriate to the primary cause of fire. PROTECTIVE EQUIPMENT In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. HAZARDOUS COMBUSTION PRODUCTS: Thermal decomposition products may include toxic oxides of nitrogen and carbon. UNUSUAL FIRE AND EXPLOSION HAZARDS N.A. 1 0 Flammability: Reactivity:0 NFPA CODES: Health: 6. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Contain and clean up spill immediately, prevent from entering floor drains. Contain liquids using absorbents. Shovel all spill materials into disposal drum. Scrub spill area with detergent, flush with copious amounts of water. WASTE DISPOSAL METHOD Disposal must be made in accordance with applicable federal, state, and local regulations. SequaGel Diluent Page 2 PERSONAL PRECAUTIONS Wear appropriate protective equipment as specified in section 8. 7. HANDLING AND STORAGE HANDLING Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling. STORAGE Keep in a tightly closed container, stored in a cooled, dry, ventilated area. STORAGE TEMPERATURE: Room Temperature DISPOSAL Observe all national, state, and local regulations regarding disposal. 9. PHYSICAL PROPERTIES 220 F Boiling Point N.A. Melting Point Water Vapor Pressure mm Hg Vapor Density N.A. Air = 1 50 % Volatile by Volume 10. STABILITY AND REACTIVITY STABILITY Stable under ordinary conditions of use and storage. If moisture is present, boric acid can be corrosive to iron. CONDITIONS TO AVOID Heat, incompatibles. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION AIRBORNE EXPOSURE LIMITS: Component: Urea 10 mg/m3, 8-hour TWA ACGIH Threshold Limit Value (TLV): not available OSHA Permissible Exposure Limit (PEL): ENGINEERING CONTROLS A system of local and/or general exhaust is recommended to keep employee exposures below the Airborn Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source. RESPIRATORY PROTECTION For conditions of use where exposure to the dust or mist is apparent, a full-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, airsupplied respirator. EYE PROTECTION Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. SKIN PROTECTION Wear protective gloves and clean body covering clothing. OTHER CONTROL MEASURES N.A. Evaporation Rate Solubility in Water pH Specific Gravity (H20 = 1) Page 3 1.0 Soluble Neutral 1.13 SequaGel Diluent HAZARDOUS DECOMPOSITION PRODUCTS Urea decomposes upon heating and can form products including ammonia, oxides of nitrogen, cyanuric acid, cyanic acid, biuret, and carbon dioxide. HAZARDOUS POLYMERIZATION Will not occur INCOMPATIBLES Urea reacts with calcium hypochlorite or sodium hypochlorite to form the explosive nitrogen trichloride. It is incompatible with sodium nitrite, gallium perchlorate, strong oxidizing agents (permanganate, dichromate, nitrate, chlorine), phosphorus penta 18824 not available NTP Carcinogen Anticipated IARC Category Known 11. TOXICOLOGICAL INFORMATION Oral Rat LD50 (mg/kg): Dermal Rabbit LD50 (mg/kg): PRODUCT LD50 VALUES SequaGel Diluent SequaGel Diluent COMPONENT CANCER LIST STATUS Component Urea None No No 12. ECOLOGICAL INFORMATION When urea is released to soil, this material will hydrolyze into ammonium in a matter of days to several weeks. When released into the soil, this material may leach into groundwater. When released into water, this material may biodegrade to a moderate extent. When released into water, this material is not expected to evaporate significantly. This material has an experimentally determined bioconcentration factor (BCF) of less than 100. This material is not expected to significantly bioaccumulate. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. When released into the air, this material is expected to have a half-life of less than 1 day. 13. DISPOSAL CONSIDERATIONS Observe all national, state, and local regulations regarding disposal. 14. TRANSPORT INFORMATION Domestic (D.O.T.) Not Regulated Proper Shipping Name: Hazard Class: N.A. UN Number: N.A. Packing Group: N.A. International (I.A.T.A. / I.M.O.) Not Regulated Proper Shipping Name: Hazard Class: N.A. UN Number: N.A. N.A. Packing Group: Chronic Acute Pressure Reactivity Fire 15. REGULATORY INFORMATION UNITED STATES TSCA Regulatory: All intentional ingredients are listed on the TSCA Inventory. SARA 311/312 Hazard Categories Component Urea Yes Yes No No No SequaGel Diluent Page 4 EUROPE EEC Regulatory: All intentional ingredients are listed on the European EINECS Inventory. 16. OTHER INFORMATION 1 0 Flammability: Reactivity:0 NFPA CODES: Health: MANUFACTURER DISCLAIMER: The information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users. Page 5 SequaGel Diluent