LCI (LUCIER CHEMICAL INDUSTRIE -- SODIUM FLUOROSILICATE ======================================================= MSDS Safety Information ======================================================= FSC: 6810 NIIN: 00-088-7252 MSDS Date: 03/01/1999 MSDS Num: BNBQF Product ID: SODIUM FLUOROSILICATE MFN: 01 Responsible Party Cage: 0K1E4 Name: LCI (LUCIER CHEMICAL INDUSTRIES) LTD Box: 49000 City: JACKSONVILLE BEACH FL 32240-9000 Info Phone Number: 904-241-1200 Emergency Phone Number: 904-241-1200 Preparer's Name: GUSTAVO R. NAVAR Chemtrec IND/Phone: (800)424-9300 Published: Y ======================================================= Contractor Summary ======================================================= Cage: 75656 Name: LOS ANGELES CHEMICAL CO Address: 4545 ARDINE ST Box: 1987 City: SOUTH GATE CA 90280 Phone: 213-562-9500 Cage: 0K1E4 Name: LUCIER CHEMICAL INDUSTRY DBA LCI LTD Address: 415 PABLO AVE N Box: 49000 City: JACKSONVILLE BEACH FL 32240-9000 Phone: 904-241-1200 ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: SODIUM SILICOFLUORIDE,TECHNICAL Specification Number: AWWA STD B 702-89 Type/Grade/Class: NONE Unit of Issue: DR Quantitative Expression: 00000000050LB UI Container Qty: 1 Type of Container: 1A2 ======================================================= Ingredients ======================================================= Cas: 16893-85-9 RTECS #: VV8410000 Name: SODIUM SILICOFLUORIDE/FLUOROSILICATE % Wt: 99 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Name: WATER INSOLUBLES/INSOLUBLE MATERIALS % Wt: 0.5 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ----------------------------- Name: NAF.HF % Wt: 0.50 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50 (RAT) IS 125 MG/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: MAY CAUSE IRRITATION OF EYES, SKIN AND REPIRATORY TRACT. INGESTION MAY CAUSE KIDNEY DAMAGE, SEVERE DIGESTIVE SYSTEM DISTRESS AND TOXIC EFFECTS. CHRONIC: MAY CAUSE SCLEROSIS. MAY CAUSE MAY ENZYM E SYSTEM EFFECTS. Explanation Of Carcinogenicity: NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. (PER MFG MSDS) Signs And Symptions Of Overexposure: INHALATION: COUGHING, WHEEZING, CHEST PAIN, SHORTNESS OF BREATH. EYES: REDNESS, PAIN, DISCOMFORT, ITCHING, TEARING. SKIN: RASH, DISCOMFORT, ITCHING. INGESTION: ABDOMINAL PAIN, DIARRHEA, NAUSEA, VOMITI NG, THIRST, DISTURBED COLOR VISION, MUSCULAR WEAKNESS, CONVULSIONS, LOSS OF CONSCIOUSNESS. Medical Cond Aggravated By Exposure: PRE-EXISTING RESPIRATORY DISORDERS SUCH AS ASTHMA AND EMPHYSEMA. First Aid: INHALATION: REMOVE PERSON TO FRESH AIR. IF NEEDED, RESUSCITATE. EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: REMOVE CONTAMINATED CLOTHES AND WASH AREA WITH SOAP AND WATER. INGESTIO N: DO NOT INDUCE VOMITING! IF CONSCIOUS, GIVE SEVERAL GLASSES OF MILK OR WATER. GET IMMEDIATE MEDICAL ATTENTION. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: EVAACUATE AREA & ISOLATE HAZARD AREA. CAREFULLY SHOVEL MATERIAL & PLACE IN CLEAN DRY CONTAINER & COVER. REMOVE CONTAINER FROM SPILL SITE & DISPOSE. CHEMTREC MAY BE CONTACTED FOR 24-HOUR ASSISTANCE Neutralizing Agent: MFR GAVE NO INFORMATION OF MSDS. Waste Disposal Methods: DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE AWAY FROM IACIDS. USE ONLY W/ADEQUATE VENTILATION, DUST MASK OR SCBA. ALWAYS WEAR PROTECTIVE CLOTHING. Other Precautions: AVOID CONTACT W/EYES, SKIN & CLOTHING. KEEP BAG OR CONTAINER CLOSED WHEN NOT IN USE. AVOID BREATHING DUST OR MIST. DO NOT GET ON SKIN, CLOTHING OR IN EYES. WASH OFF W/WATER. DO NOT TAKE INTERNALLY. DO NOT BREATHE DUST. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: N/A. Lower Limits: N/A. Upper Limits: N/A. Extinguishing Media: CHEMICAL IS NOT FLAMMABLE. FOAM, DRY CHEMICALS OR CARBON DIOXIDE MAY BE USED WHERE IT IS STORED. Fire Fighting Procedures: WHEN THIS PRODUCT IS HEATED TO DECOMPOSITION (>500C) IT WILL GENERATE HIGHLY TOXIC GASES SUCH AS HYDROGEN FLUORIDE. Unusual Fire/Explosion Hazard: EXTREME TEMPERATURES WILL CAUSE DECOMPOSITION & FORMATION OF NITROGEN OXIDES & FLUORINE. FIRE FIGHTERS SHOULD SEAR FULL PROTECTIVE CLOTHING & SCBA. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR A NIOSH APPROVED RESPIRATOR. SELF-CONTAINED BREATHING APPARATUS MAY BE REQUIRED WHEN CHEMICAL IS HEATED TO DECOMPOSITION. Ventilation: ADEQUATE VENTILATION TO MAINTAIN FLUORIDE CONCENTRATIONS BELOW APPLICABLE STANDARDS. Protective Gloves: IMPERVIOUS GLOVES Eye Protection: SPLASH PROOF GOGGLES Other Protective Equipment: PROTECTIVE IMPERVIOUS CLOTHING TO PREVENT CONTACT W/SKIN. Work Hygienic Practices: MFR GAVE NO INFORMATION OF MSDS. Supplemental Safety and Health: MSDS WAS MISSING PAGE 2 WHICH COVERED HEALTH RISKS AND FIRST AID. INFORMATION FROM PREVIOUS MSDS WAS LEFT IN THOSE FIELDS. ======================================================= Physical/Chemical Properties ======================================================= HCC: T4 NRC/State LIC No: NOT RELEVANT B.P. Text: DECOMPOSES M.P/F.P Text: DECOMPOSES Decomp Temp: =500.C, 932.F Vapor Pres: N/A. Vapor Density: N/A. Spec Gravity: 2.679 Viscosity: UNKNOWN Evaporation Rate & Reference: N/A. Solubility in Water: 0.44% Appearance and Odor: WHITE ODORLESS GRANULAR CRYSTALLINE MATERIAL - PH 1% SOLN = 3.1 Corrosion Rate: UNKNOWNN ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: CONTACT WITH STRONG ACIDS & ALKALIES WILL CAUSE FORMATION OF HYDROGEN FLUORIDE GAS. Materials To Avoid: STRONG ACIDS, ALKALIES Hazardous Decomposition Products: MAY FORM HYDROGEN FLUORIDE, FLUORINE AND NITROGEN OXIDES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Responsible Party Cage: 0K1E4 Trans ID NO: 47125 Product ID: SODIUM FLUOROSILICATE MSDS Prepared Date: 05/01/1994 Review Date: 02/28/2001 MFN: 1 Net Unit Weight: 50 POUNDS Multiple KIT Number: 0 Review IND: Y Unit Of Issue: DR Container QTY: 1 Type Of Container: 1A2 Additional Data: MFR SUPPLIED THE PROPER SHIPPING NAME. ======================================================= Detail DOT Information ======================================================= DOT PSN Code: NFM DOT Proper Shipping Name: SODIUM FLUOROSILICATE Hazard Class: 6.1 UN ID Num: UN2674 DOT Packaging Group: III Label: KEEP AWAY FROM FOOD Packaging Exception: 153 Non Bulk Pack: 213 Bulk Pack: 240 Max Qty Pass: 100 KG Max Qty Cargo: 200 KG Vessel Stow Req: A Water/Ship/Other Req: 26 ======================================================= Detail IMO Information ======================================================= IMO PSN Code: NRZ IMO Proper Shipping Name: SODIUM FLUOROSILICATE IMDG Page Number: 6250 UN Number: 2674 UN Hazard Class: 6.1 IMO Packaging Group: III Subsidiary Risk Label: - EMS Number: 6.1-04 MED First Aid Guide NUM: 750 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: WQL IATA UN ID Num: 2674 IATA Proper Shipping Name: SODIUM FLUOROSILICATE IATA UN Class: 6.1 IATA Label: TOXIC UN Packing Group: III Packing Note Passenger: 619 Max Quant Pass: 100KG Max Quant Cargo: 200KG Packaging Note Cargo: 619 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: WQL AFI Proper Shipping Name: SODIUM FLUOROSILICATE AFI Hazard Class: 6.1 AFI UN ID NUM: UN2674 AFI Packing Group: III Special Provisions: P5 Back Pack Reference: A10.6 ======================================================= HAZCOM Label ======================================================= Product ID: SODIUM FLUOROSILICATE Cage: 0K1E4 Company Name: LUCIER CHEMICAL INDUSTRY DBA LCI LTD Street: 415 PABLO AVE N PO Box: 49000 City: JACKSONVILLE BEACH FL Zipcode: 32240-9000 Health Emergency Phone: 904-241-1200 Label Required IND: Y Date Of Label Review: 05/03/1997 Status Code: C MFG Label NO: NONE Label Date: 05/03/1997 Year Procured: 1997 Origination Code: F Eye Protection IND: YES Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS. ACUTE- FLUORIDE DUST MAY CAUSE IRRITATION TO EYES & RESPIRATORY TRACT. SWALLOWING MAY CAUSE ABDOMINAL PAIN/BURNING. CHRONIC- SKIN RASH, PULMONARY FIBR OSIS. STORE AWAY FROM INCOMPATIBLES. SWEEP UP & PLACE IN A SUITABLE CONTAINER FOR DISPOSAL. FIRST AID- GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES: FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP &WATER. ORAL:IF CONSCIOUS, DRINK SEVERAL GLASSES OF MILK (CALCIUM) OR LARGE AMOUNT OF WATER. GET MEDICAL ATTENTION IMMEDIA TELY. DO NOT INDUCE VOMITING. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.