SIGMA CHEMICAL CO -- G2025,GLYCEROL INSECT CELL CULTURE TESTED ======================================================= MSDS Safety Information ======================================================= FSC: 6550 NIIN: 01-361-6838 MSDS Date: 01/01/1999 MSDS Num: CKNDY Product ID: G2025,GLYCEROL INSECT CELL CULTURE TESTED MFN: 01 Responsible Party Cage: 20176 Name: SIGMA CHEMICAL CO Box: 14508 City: ST LOUIS MO 63178 Info Phone Number: 314-771-5765 Emergency Phone Number: 314-771-5765 Preparer's Name: NOT PROVIDED Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 20176 Name: SIGMA CHEMICAL CO Box: 14508 City: SAINT LOUIS MO 63178 Phone: 314-771-5765 / 800-325-3010 ======================================================= Item Description Information ======================================================= Item Name: GLYCEROL Unit of Issue: BT Quantitative Expression: 00000000500ML UI Container Qty: 1 ======================================================= Ingredients ======================================================= Cas: 56-81-5 RTECS #: MA8050000 Name: GLYCERIN Other REC Limits: NOT PROVIDED OSHA PEL: 15 MG/M3 ACGIH TLV: 10 MG/M3 ACGIH STEL: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50 (ORAL, RAT) 12600 MG/KG Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE EFFECTS: MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. CAUSES EYE AND SKIN IRRITATION. MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. PROLONGED EXPOSU RE CAN CAUSE: NAUSEA, HEADACHE AND VOMITING. CHRONIC EFFECTS: TARGET ORGANS(S): KIDNEYS. TO THE BEST OF OUR KNOWLEDE, THE CHEMICAL, PHYSICAL AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVES TIGATED. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: CAUSES EYE AND SKIN IRRITATION. MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. PROLONGED EXPOSURE CAN CAUSE: NAUSEA, HEADACHE AND VOMITING. Medical Cond Aggravated By Exposure: NOT PROVIDED First Aid: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHI NG GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. WASH CONTAMINATED CLOTHING BEFORE REUSE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATE RIAL PICK UP IS COMPLETE. Neutralizing Agent: NOT RELEVANT Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. KEEP TIGHTLY CLOSED. Other Precautions: DO NOT BREATHE VAPOR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. WASH THOROUGHLY AFTER HANDLING. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point: =160.C, 320.F Autoignition Temp: =370.C, 698.F Lower Limits: 0.9 Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: MECHANICAL EXHAUST REQUIRED. Protective Gloves: CHEMICAL-RESISTANT GLOVES. Eye Protection: SAFETY GLASSES. Other Protective Equipment: WEAR APPROPRIATE PROTECTIVE CLOTHING. Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health: NONE ======================================================= Physical/Chemical Properties ======================================================= HCC: V5 NRC/State LIC No: NOT RELEVANT Boiling Point: =182.C, 359.6F B.P. Text: 20 MM Melt/Freeze Pt: =20.C, 68.F Decomp Text: NOT REGULATED Vapor Pres: <1 @ 20C/68F Vapor Density: 3.1 Spec Gravity: 1.261 PH: NOT RELEVANT Viscosity: NOT PROVIDED Evaporation Rate & Reference: NOT PROVIDED Solubility in Water: NOT PROVIDED Appearance and Odor: VISCOUS COLORLESS LIQUID Corrosion Rate: NOT PROVIDED ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: PROTECT FROM MOISTURE. Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG BASES. Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NONE ======================================================= Toxicological Information ======================================================= Toxicological Information: ORAL-RAT LD50: 12600 MG/KG. IHL-RAT LC50: >570 MG/M3/1H. IPR-RAT LD50: 4420 MG/KG. SCU-RAT LD50: 100 MG/KG. IVN-RAT LD50: 5566 MG/KG. ======================================================= Ecological Information ======================================================= Ecological: DATA NOT YET AVAILABLE. ======================================================= MSDS Transport Information ======================================================= Transport Information: CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. ======================================================= Regulatory Information ======================================================= Sara Title III Information: NOT PROVIDED Federal Regulatory Information: EPA TSCA SECTION B (B) CHEMICAL INVENTORY. State Regulatory Information: NOT PROVIDED ======================================================= Other Information ======================================================= Other Information: NONE ======================================================= Transportation Information ======================================================= Responsible Party Cage: 20176 Trans ID NO: 153377 Product ID: G2025,GLYCEROL INSECT CELL CULTURE TESTED MSDS Prepared Date: 01/01/1999 Review Date: 06/06/2000 MFN: 1 Net Unit Weight: 1.387 LBS Multiple KIT Number: 0 Unit Of Issue: BT Container QTY: 1 ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: G2025,GLYCEROL INSECT CELL CULTURE TESTED Cage: 20176 Company Name: SIGMA CHEMICAL CO PO Box: 14508 City: SAINT LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765 Label Required IND: Y Date Of Label Review: 06/06/2000 Status Code: A MFG Label NO: NOT PROVIDED Label Date: 01/01/1999 Origination Chronic Hazard IND: Y Eye Protection IND: YES Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: NO Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: TARGET ORGANS: KIDNEYS. IRRITANT. IRRITATING TO EYES AND SKIN. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. WEAR SUITABLE PROTECTIVE CLOTHING. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.