SIGMA CHEMICAL COMPANY -- 14-4 ZINC SULFATE SOLUTION 0.3N ======================================================= MSDS Safety Information ======================================================= FSC: 6550 MSDS Date: 03/07/1996 MSDS Num: BZFCH LIIN: 00F048197 Product ID: 14-4 ZINC SULFATE SOLUTION 0.3N MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST Box: 14508 City: SAINT LOUIS MO 63178-5000 Info Phone Number: 314-771-5765/800-325-3010 Emergency Phone Number: 314-771-5765/800-325-3010 Review Ind: Y Published: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Box: 14508 City: ST LOUIS MO 63178 ======================================================= Contractor Summary ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Box: 14508 City: ST LOUIS MO 63178 Phone: 1-314-771-5765 ======================================================= Ingredients ======================================================= Cas: 7446-20-0 RTECS #: ZH5300000 Name: ZINC SULFATE HEPTAHYDRATE ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50(RAT): 2150 MG/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: HARMFUL IF INHALED, INGESTED/SKIN ABSORPTION. VAPOR/MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. SKIN: IRRITATION. KIDNEYS, PANCREAS, LIVER, LUNGS, GI TRACT. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: IRRITATION. First Aid: EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CA SES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS & HEAVY RUBBER GLOVES. ABSORB ON SAND/VERMICULITE & PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA & WASH AREA SITE AFTER MATERIAL PICKUP IS COMPLETE. Waste Disposal Methods: DISSOLVE/MIX THE MATERIAL W/A COMBUSTIBLE SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER IAW/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL DRY PLACE. KEEP TIGHTLY CLOSED. Other Precautions: DON'T GET IN EYES, SKIN/CLOTHING. DON'T BREATHE VAPOR. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures: WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard: NONCOMBUSTIBLE. ======================================================= Control Measures ======================================================= Ventilation: USE MECHANICAL EXHAUST REQUIRED Protective Gloves: RUBBER Eye Protection: CHEMICAL SAFETY GOGGLES Other Protective Equipment: SUITABLE PROTECTIVE CLOTHING, SAFETY SHOWER & EYE BATH. ======================================================= Physical/Chemical Properties ======================================================= Appearance and Odor: LIQUID ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: STRONG OXIDIZING AGENTS Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 14-4 ZINC SULFATE SOLUTION 0.3N Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY PO Box: 14508 City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765/800-325-3010 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: HARMFUL IF INHALED, INGESTED/SKIN ABSORPTION. VAPOR/MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. SKIN: IRRITATION. KIDNEYS, PANCREAS, LIVER, LUNGS, GI TRACT. IRRITATION. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.