======================================================= MSDS Safety Information ======================================================= NAME: 210B GOLDEN OAK ======================================================= - Continued - Material Safety Data Sheet Document Code: Wood/MW Date of Preparation Version: 00 17-JAN-2000 Section 1 - Product and Company Identification PRODUCT NAME & NUMBERS HMIS CODES MINWAX® WOOD FINISH® Health 2* 209 Natural 230 Early American Flammability 2 210B Golden Oak 235 Cherry Reactivity 0 211 Provincial 241 Fruitwood 215 Red Oak 245 Golden Pecan 218 Puritan Pine 260 Pickled Oak 221 Ipswich Pine 2126 Driftwood 223 Colonial Maple 2716 Dark Walnut 224 Special Walnut 2718 Ebony 225 Red Mahogany 2750 Jacobean PRODUCT CLASS Alkyd Stain MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. MINWAX Company (216) 566-2917 10 Mountainview Road INFORMATION TELEPHONE NO. Upper Saddle River, NJ 07458 (800) 523-9299 Section 2 – Composition/Information on Ingredients Products were reformulated on 01/01/00. Check manufacturer’s date on lid of can. Products Mfg. After 01/01/00: --------------- % WT. CAS No. Ingredient Name ---------------------------------------------------------------------------- 50-56 64742-88-7 Mineral Spirits. ACGIH TLV TWA 100 PPM OSHA PEL TWA 100 PPM 4-5 64741-65-7 Mineral Spirits (Odorless). ACGIH TLV TWA 100 PPM OSHA PEL TWA 100 PPM 6-9 64742-52-5 Heavy Naphthenic Petroleum Oil. ACGIH TLV TWA 5 Mg/M3 as Mist OSHA PEL TWA 5 Mg/M3 as Mist 6-9 64742-53-6 Highly refined Naphthenic Oil. ACGIH TLV TWA 5 Mg/M3 as Mist OSHA PEL TWA 5 Mg/M3 as Mist 0-2 14807-96-6 Talc ACGIH TLV TWA 2 Mg/M3 as Resp. Dust OSHA PEL TWA 2 Mg/M3 as Resp. Dust 0-4 13463-67-7 Titanium Dioxide. ACGIH TLV TWA 10 Mg/M3 as Dust OSHA PEL TWA 10 Mg/M3 as Total Dust OSHA PEL TWA 5 Mg/M3 as Respirable Fraction 0-0.8 1333-86-4 Carbon Black. ACGIH TLV TWA 3.5 Mg/M3 OSHA PEL TWA 3.5 Mg/M3 Rockler SKUs: 31136, 33504, 35093, 36415, 38516, 38603, 57091, 57109, 57125, 57133, 57141, 57158, 57166, 57174, 57182, 57190, 57208, 57224, 57232, 57240, 57257, 57273, 57281, 57307, 57315, 57323, 57331, 57349, 57356, 57364, 57372, 57380, 57398, 57414 RTD20000235AA MINWAX® Wood Finish – Wood/MW Page 2 - Continued - Products Mfg. Before 01/01/00: ---------------- % WT. CAS No. Ingredient Name ---------------------------------------------------------------------------- 71-87 64742-88-7 Mineral Spirits. ACGIH TLV TWA 100 PPM OSHA PEL TWA 100 PPM 0-2 64741-65-7 Mineral Spirits (Odorless). ACGIH TLV TWA 100 PPM OSHA PEL TWA 100 PPM 0-0.2 136-52-7 Cobalt 2-Ethylhexanoate. ACGIH TLV Not Established OSHA PEL Not Established 0-7 14807-96-6 Talc ACGIH TLV TWA 2 Mg/M3 as Resp. Dust OSHA PEL TWA 2 Mg/M3 as Resp. Dust 0-6 13463-67-7 Titanium Dioxide. ACGIH TLV TWA 10 Mg/M3 as Dust OSHA PEL TWA 10 Mg/M3 as Total Dust OSHA PEL TWA 5 Mg/M3 as Respirable Fraction 0-1 1333-86-4 Carbon Black. ACGIH TLV TWA 3.5 Mg/M3 OSHA PEL TWA 3.5 Mg/M3 Section 3 – Hazards Identification ROUTES OF EXPOSURE Exposure may be by INHALATION and/or SKIN or EYE contact, depending on conditions of use. To minimize exposure, follow recommendations for proper use, ventilation, and personal protective equipment. EFFECTS OF OVEREXPOSURE Irritation of eyes, skin and respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11. Section 4 – First Aid Measures If INHALED: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWED: Get medical attention. Section 5 – Fire Fighting Measures FLASH POINT LEL UEL 101-110 °F PMCC 1.0 7.0 FLAMMABILITY CLASSIFICATION Combustible, Flash above 99 and below 200 °F MINWAX® Wood Finish – Wood/MW Page 3 - Continued - EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 – Accidental Release Measures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate and remove with inert absorbent. Section 7 – Handling and Storage DOL STORAGE CATEGORY 2 PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are COMBUSTIBLE. Keep away from heat and open flame. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. To minimize the possibility of spontaneous combustion: control the accumulation of overspray; soak wiping rags and waste immediately after use in a water-filled, closed metal container; air dry filters outside, far from any combustible material and separated by bricks or other non-combustible spacers; dispose of all contaminated materials and waste properly. Consult OSHA 29 CFR 1910.107(b)(5) and NFPA 33, Chapter 8 (8-9) for the proper procedures. Section 8 – Exposure Controls/Personal Protection PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact with skin and eyes. Wash hands after using. These coatings may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg./m3 (total dust), 3 mg./m3 (respirable fraction), OSHA PEL 15 mg./m3 (total dust), 5 mg./m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. MINWAX® Wood Finish – Wood/MW Page 4 - Continued - PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Section 9 – Physical and Chemical Properties PRODUCT WEIGHT 6.6-7.2 lb./gal. EVAPORATION RATE Slower than Ether SPECIFIC GRAVITY 0.79-0.87 VAPOR DENSITY Heavier than Air BOILING POINT 300-412 °F MELTING POINT N.A. VOLATILE VOLUME 62-92 % SOLUBILITY IN WATER N.A. VOC – Mfg. After 01/01/00 4.0-4.3 lbs./gal. (less exempt solvents) VOC – Mfg. Before 01/01/00 5.0-5.9 lbs./gal. (less exempt solvents) Section 10 – Stability and Reactivity STABILITY - Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur Section 11 – Toxicological Information CHRONIC HEALTH HAZARDS Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity. Cobalt and cobalt compounds are classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is inadequate evidence in humans for its carcinogenicity. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems. Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. MINWAX® Wood Finish – Wood/MW Page 5 - Continued - TOXICOLOGY DATA CAS No. Ingredient Name ---------------------------------------------------------------------------- 64742-88-7 Mineral Spirits. LC50 RAT 4HR >700 PPM LD50 RAT 4700 MG/KG 64741-65-7 Mineral Spirits (Odorless). LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-52-5 Heavy Naphthenic Petroleum Oil. LC50 RAT 4HR Not Available LD50 RAT Not Available 64742-53-6 Highly refined Naphthenic Oil. LC50 RAT 4HR Not Available LD50 RAT >5000 MG/KG 136-52-7 Cobalt 2-Ethylhexanoate. LC50 RAT 4HR Not Available LD50 RAT Not Available 14807-96-6 Talc LC50 RAT 4HR Not Available LD50 RAT Not Available 13463-67-7 Titanium Dioxide. LC50 RAT 4HR Not Available LD50 RAT >7500 MG/KG 1333-86-4 Carbon Black. LC50 RAT 4HR Not Available LD50 RAT >15400 MG/KG Section 12 – Ecological Information ECOTOXICOLOGICAL INFORMATION No Data Available. Section 13 – Disposal Considerations WASTE DISPOSAL METHOD Waste from these products may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State, and Local regulations regarding pollution. Section 14 – Transport Information DOT PROPER SHIPPING DESCRIPTION: Paint and Related Materials, NOIBN IATA/IMDG SHIPPING DESCRIPTION: Paint, 3, UN1263, PG III, Ltd Qty Section 15 – Regulatory Information SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT % Element Cobalt Compound. 0-0.2 0-0.04 CALIFORNIA PROPOSITION 65 (Before and After 01/01/00) After 01/01/00 - WARNING: These products, except for 209, contain a chemical known to the State of California to cause cancer. Before 01/01/00 - WARNING: 215, 221, 223, 224, 225, 230, 235, 241, 245, 260, 2126, 2716 and 2750 contain a chemical known to the State of California to cause cancer. 2718 contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. MINWAX® Wood Finish – Wood/MW Page 6 TSCA CERTIFICATION All chemicals in these products are listed, or are exempt from listing, on the TSCA Inventory. Section 16 – Other Information CANADIAN DISTRIBUTOR: Consumer Brands Canada Inc. 200 Confederation Parkway Vaughn, ON L4K 4T8 NOTE: These products have been classified in accordance with the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. The above information pertains to these products as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to these products may substantially alter the composition and hazards of the products. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.