======================================================= MSDS Safety Information ======================================================= NAME: 303 DRI-STRIP FLOOR CLEANER ======================================================= MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2000, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M Brand 303 DRI-STRIP ID NUMBER/U.P.C.: 61-5000-0312-6 00-48011-08108-3 61-5000-6130-6 00-48011-14000-1 FZ-0100-0476-5 - - - ISSUED: November 17, 2000 SUPERSEDES: October 13, 1998 DOCUMENT: 10-2817-4 ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT ----------------------------------------------------------------------------- WATER................................... 7732-18-5 60 - 90 2-BUTOXYETHANOL......................... 111-76-2 7 - 13 ISOBUTANE............................... 75-28-5 5 - 10 ETHANOLAMINE............................ 141-43-5 < 1 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372: 2-BUTOXYETHANOL ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT:................. ca. 212 F VAPOR PRESSURE:................ N/D VAPOR DENSITY:................. N/D EVAPORATION RATE:.............. N/D SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY:.............. 0.99 Water=1 PERCENT VOLATILE:.............. > 99 % pH:............................ ca. 11 VISCOSITY:..................... < 100 centipoise MELTING POINT:................. N/D ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand 303 DRI-STRIP November 17, 2000 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA (continued) ----------------------------------------------------------------------------- APPEARANCE AND ODOR: Aerosol, liquid, clear, mild odor ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT:................... 196 F TOC (Above for liquid; propellant < 0 F) FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers exposed to heat from fire may build pressure and explode. NFPA HAZARD CODES: HEALTH: 1 FIRE: 2 REACTIVITY: 0 AEROSOL STORAGE: 1 UNUSUAL REACTION HAZARD: none ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Heat. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand 303 DRI-STRIP November 17, 2000 PAGE 3 ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Ventilate area. Extinguish all ignition sources. Contain spill. Evacuate unprotected personnel from hazard area. Cover with absorbent material. Cover spill area with Light Water Brand or other ATC foam. (For further information on ATC foam usage, contact 3M Fire Protection Systems.) Collect using non-sparking tools. Clean up residue. Place in an approved metal container. Seal the container. Place leaking containers in a wellventilated area, preferrably in an exhaust hood, if available, or outdoors. RECOMMENDED DISPOSAL: Incinerate in a permitted hazardous waste incinerator. Do not puncture or burn cans in a household incinerator. Facility must be capable of handling aerosol cans. Dispose of empty cans in a sanitary landfill. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: ca. 190 gms/liter South Coast Air Quality Mgmt Dist Method Rule 443.1, calculated. Volatile Organic Compounds: 20 % by wt. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = D001 (Ignitable) All chemicals used in the manufacture of this material are listed on the following chemical inventories: TSCA EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: No ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate medical attention. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand 303 DRI-STRIP November 17, 2000 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID (continued) ----------------------------------------------------------------------------- SKIN CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention. INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: Avoid eye contact with vapor, spray, or mist. Wear unvented goggles during operations in which exposure is likely. SKIN PROTECTION: Avoid prolonged or repeated skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber. RECOMMENDED VENTILATION: Do not use in a confined area or areas with little or no air movement. Use in a well-ventilated area. Use with adequate dilution ventilation. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or spray. Avoid breathing of airborne material. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: half-mask organic vapor respirator. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating. RECOMMENDED STORAGE: Store away from areas where product may come into contact with food or pharmaceuticals. Store at temperatures below 120 degrees F (49 degrees C). Keep out of the reach of children. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand 303 DRI-STRIP November 17, 2000 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- FIRE AND EXPLOSION AVOIDANCE: Aerosol container contains flammable gas under pressure. Keep away from heat, sparks, open flame, and other sources of ignition. Do not pierce or burn container, even after use. OTHER PRECAUTIONARY INFORMATION: Not intended for consumer sale or use. HMIS HAZARD RATINGS: HEALTH: 0 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7.) EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* ----------------------------------------------------------------------------- WATER................................ NONE NONE NONE NONE 2-BUTOXYETHANOL...................... 25 PPM TWA ACGIH Y 2-BUTOXYETHANOL...................... 25 PPM TWA OSHAV Y OSHA VACATED PEL 2-BUTOXYETHANOL...................... 50 PPM TWA OSHA Y ISOBUTANE............................ NONE NONE NONE NONE ETHANOLAMINE......................... 3 PPM TWA ACGIH ETHANOLAMINE......................... 6 PPM STEL ACGIH ETHANOLAMINE......................... 3 PPM TWA OSHA ETHANOLAMINE......................... 6 PPM STEL OSHA ETHANOLAMINE......................... 6 MG/M3 TWA OSHA * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - OSHA: Occupational Safety and Health Administration - OSHAV: Occupational Safety and Health Administration Vacated PEL. Vacated Permissible Exposure Limits (PEL) are enforced as the OSHA PEL in some states. Check with your local regulatory authority. - NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Mild Eye Irritation: signs/symptoms can include redness, swelling, pain, and tearing. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand 303 DRI-STRIP November 17, 2000 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- SKIN CONTACT: Mild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, and itching. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. IF SWALLOWED: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. Ingestion may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors and convulsions. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- INGREDIENTS SECTION CHANGED SINCE October 13, 1998 ISSUE PRECAUTIONARY INFO. SECTION CHANGED SINCE October 13, 1998 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand 303 DRI-STRIP November 17, 2000 PAGE 7 ----------------------------------------------------------------------------- The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.