E E ZIMMERMAN CO -- E-Z DENATURED SOLVENT ALCOHOL ======================================================= MSDS Safety Information ======================================================= FSC: 8010 MSDS Date: 01/01/1997 MSDS Num: CHLXV LIIN: 00N088333 Product ID: E-Z DENATURED SOLVENT ALCOHOL MFN: 01 Responsible Party Cage: ZMMER Name: E E ZIMMERMAN CO Box: 11254 City: PITTSBURGH PA 15238 Info Phone Number: 412-963-0949 Emergency Phone Number: 412-963-0949 Published: Y ======================================================= Contractor Summary ======================================================= Cage: ZMMER Name: E E ZIMMERMAN CO Address: UNKNOWN Box: 111254 City: PITTSBURGH PA 15238 Phone: 412-963-0949 ======================================================= Ingredients ======================================================= Cas: 67-56-1 RTECS #: PC1400000 Name: METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA) % Wt: 57 OSHA PEL: S, 200 PPM ACGIH TLV: S, 200 PPM/250 STEL EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 64-17-5 RTECS #: KQ6300000 Name: ETHYL ALCOHOL (ETHANOL) % Wt: 38-42 OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM ------------------------------ Cas: 7732-18-5 RTECS #: ZC0110000 Name: WATER % Wt: 1-4.5 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Name: EFTS OF OVEREXP: (NAUS, VOMIT, DIARR), IRRIT(NOSE, THROAT, RESP TRACT), COUGH, CNS DEPRESS(DIZZ, DROW, WEAK, ----------------------------- Name: ING 4: FATG, NAUS, HDCH, UNCON), LEG CRAMPS, INVOLUNTARY EYE MOVEMENT, ABDOM & LOW BACK PAIN, RESP DEPRESS, ----------------------------- Name: ING 5: BLURRED VISION, SHORTNESS OF BREATH, IMPAIRED COORD, CONFUSN, IRREGULAR HEARTBEAT, CYANOSIS (CHARACT BY ----------------------------- Name: ING 6: BLUISH DISCOLORATION OF SKIN & NAILS), ANESTH, VISUAL IMPAIRMENT(INCL BLNDNESS), RESP FAIL, COMA, & DEATH. ----------------------------- Name: ING 7: TARGET ORGAN EFTS: PROD CNTNS ETHANOL. ALCOHOLIC BEVERAGE CONSUMPTION HAS BEEN ASSOC W/BRAIN DMG, HEART ----------------------------- Name: ING 8: DMG, & PANCREATITIS IN HUMANS. RELEVANCE OF THESE FINDING TO ETHANOL EXPOS IN INDUST ENVIRONMENTS IS ----------------------------- Name: ING 9: UNCERTAIN. EXPOS TO LETHAL CONCS OF METHANOL HAS BEEN SHOWN TO CAUSE DMG TO ORGANS INCL LIVER, KIDNEYS, ----------------------------- Name: ING 10: PANCREAS, HEART, LUNGS & BRAIN. ALTHOUGH THIS RARELY OCCURS, SURVIVORS OF SEV INTOXICATION MAY SUFFER ----------------------------- Name: ING 11: FROM PERM NEUROLOGICAL DMG. OVEREXP TO MATL (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS CAUSE OF FOLLOWING ----------------------------- Name: ING 12: EFTS IN LAB ANIMALS, & MAY AGGRAVATE PRE-EXISTING DISORDERS OF THESE ORGANS IN HUMANS: TESTIS DMG, ----------------------------- Name: ING 13: PANCREATIC DMG, LIVER DMG, CNS DMG, BRAIN DMG. OVEREXP TO MATL(OR ITS COMPONENTS) HAS BEEN SUGGESTED AS ----------------------------- Name: ING 14: CAUSE OF FOLLOWING EFTS IN HUMANS, & MAY AGGRAVATE PRE-EXISTING DISORDERS OF THES ORGANS: VISUAL ----------------------------- Name: ING 15: IMPAIRMENT, LIVER DMG. DEVELOPMENTAL INFO: WHILE THERE IS SUFFICIENT EVID METHANOL CAUSES BIRTH DEFECTS ----------------------------- Name: ING 16: IN EXPERIMENTAL ANIMALS, RELEVANCE OF THESE FINDING TO HUMANS IS UNCERTAIN BECAUSE OF DIFFERENCES IN ----------------------------- Name: ING 17: METABOLISM & TOX OF METHANOL BETWEEN HUMANS & NON-PRIMATES. FOR MORE SPECIFIC INFORMATION CONT NECH (FP N). ----------------------------- Name: FIRST AID PROC: IF INDIVIDUAL IS CONSCIOUS & ALERT, INDUCE VOMIT BY GIVING SYRUP OF IPECAC/BY GENTLY PLACING 2 ----------------------------- Name: ING 19: FINGERS @ BACK OF THROAT. IF POSS, DO NOT LEAVE INDIVIDUAL UNATTENDED. INHAL: IMMED MOVE INTO FRESH AIR. ----------------------------- Name: ING 20: SEEK IMMED MED ATTN; KEEP PERSON WARM & QUIET. IF PERSON IS NOT BRTHG, BEGIN ARTF RESP. IF BRTHG IS ----------------------------- Name: ING 21: DFCLT, ADMIN OXYG. NOTE TO PHYS:PROD CNTNS METHANOL WHICH CAN CAUSE INTOXICATION & CNS DEPRESS. METHANOL ----------------------------- Name: ING 22: IS METABOLIZED TO FORMIC ACID AND FORMALDEHYDE. FOR MORE SPECIFIC INFORMATION CONT NEHC (FP N). ----------------------------- Name: SPILL PROC: COMPLETED. STOP SPILL @ SOURCE. PVNT FROM ENTERING DRAINS, SEWERS, STREAMS/OTHER BODIES OF WATER. ----------------------------- Name: ING 24: PVNT FROM SPREADING. IF RUNOFF OCCURS, NOTIFY AUTH AS REQD. FOR MORE INFO CONT NEHC (FP N). ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: EYE: CAUSES IRRIT. SYMPS MAY INCL STINGING, TEARING, REDNESS & SWELL. SKIN: MAY CAUSE MILD IRRIT. PRLNGD/RPTD EXPOS MAY DRY SKIN. SYMPS MAY INCL REDNESS, BURNING, DRYING & CRACKING, & SKIN BURN S. SKIN ABSORP IS POSS, & MAY CONTRIBUTE TO SYMPS OF TOX FROM OTHER ROUTES OF EXPOS. INGEST: SINGLE (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: DOSE ORAL TOX IS MOD. INGEST MAY BE HARMFUL. INHAL: EXPOS TO VAP/MIST IS POSS. SHORT-TERM INHAL TOX IS LOW. BRTHG SM AMTS DURING NORM HNDLG IS NOT LIKELY TO CAUSE HARMFUL EFTS. BRTHG LG AMTS MAY BE HARMFUL. SYMPS ARE MORE TYPICALLY SEEN @ AIR CONCS EXCEEDING REC EXPOS LIMITS. SYMPS OF EXPOS: GI IRRIT Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: IMMED MOVE AWAY FROM EXPOS & INTO FRESH AIR. FLUSH GENTLY W/WATER FOR @ LST 15 MINS WHILE HOLDING EYELIDS APART. SEEK IMMED MED MED ATTN. SKIN: REMOVE CONTAMD CLTHG. WASH EXPOS AREA W/SOAP & WAT ER. IF SYMPS PERSIST, SEEK MED ATTN. LAUNDER CLTHG BEFORE REUSE. INGEST: SEEK MED ATTN. IF INDIVIDUAL IS DROWSY/UNCON, DO NOT GIVE ANYTHING BY MOUTH; PLACE INDIVIDUAL ON LEFT SIDE W/HEAD DOWN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SM SPILL: ABSORB LIQ ON VERMICULITE, FLOOR ABSORB/OTHER ABSORB MATL. LG SPILL: ELIM ALL IGNIT SOURCES(FLARES, FLAMES INCL PILOT LIGHT, ELEC SPKS). PERSONS NOT WEARING PROT EQUIP SHOULD BE EXCLUDED FRO M AREA OF SPILL UNTIL CLEANUP HAS BEEN Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: ALL 5 GAL PAILS & LGR METAL CNTNRS INCL TANK CARS & TANK TRUCKS SHOULD BE GROUNDED &/OR BONDED WHEN MATERIAL IS TRANSFERRED. Other Precautions: CNTNRS OF MATL MAY BE HAZ WHEN EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES(VAP, LIQ, &/OR SOLID), ALL HAZ PREC GIVEN IN DATA SHEET MUST BE OBSERVED. FOR MORE SPECIFIC INFORMATION CONTACT NEHC ( FP N). ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: >20F,>-7C Lower Limits: 1.4% Extinguishing Media: ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/MAY BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, OTHER FLAMES, SPKS, HEATERS, SMKNG, ELEC MOTORS, STATIC (SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT IS EXCEEDED(SEE EXPOS GUIDELINES), NIOSH APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER ENVIRONMENT CONTROL. FOR MORE SPECIFIC INFORMATION CON T NEHC (FP N). Ventilation: PROVIDE SUFFICIENT MECH(GEN AND/OR LOC EXHAUST) VENT TO MAINTAIN EXPOS BELOW TLV(S). Protective Gloves: RESISTANT GLOVES. Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). TO PVNT RPTD/PRLNGD SKIN CONT, WEAR IMPERVIOUS CLOTHING AND BOOTS. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: VP: 97.680 @ 68F. EXPLO HAZ: DISCHARGE/OTHER IGNIT SOURCES @ LOCATIONS DIST FROM MATL HNDLG POINT. NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. HAZ PRODS OF COMBUST: MAYFORM: CARBON DIOXIDE & CARBON MONOXIDE, VARIOUS HYDROCARBONS. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 147F,64C Vapor Pres: SUPDAT Vapor Density: 1.000 Spec Gravity: 0.301 @ 77F Evaporation Rate & Reference: SLOWER THAN ETHYL ETHER Solubility in Water: NOT KNOWN Appearance and Odor: LIQUID. NO ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: AVOID CONTACT WITH: STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: MAY FORM: CARBON DIOXIDE AND CARBON MONOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: E-Z DENATURED SOLVENT ALCOHOL Cage: ZMMER Company Name: E E ZIMMERMAN CO Street: UNKNOWN PO Box: 111254 City: PITTSBURGH PA Zipcode: 15238 Health Emergency Phone: 412-963-0949 Label Required IND: Y Date Of Label Review: 07/06/1998 Status Code: C Label Date: 07/06/1998 Origination Chronic Hazard IND: Y Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMMABLE. ACUTE: EYE: CAUSES IRRITATION, STINGING, TEARING, REDNESS & SWELLING. SKIN: MAY CAUSE MILD IRRITATION, REDNESS, BURNING, DRYING & CRACKING, & SKIN BURNS. SKIN ABSORP IS POSSIBLE, & MAY CONT RIBUTE TO SYMPTOMS OF TOXICITY FROM OTHER ROUTES OF EXPOSURE. INGEST: MAY BE HARMFUL. MAY CAUSE GI IRRITATION, NAUSEA, VOMITING AND DIARRHEA. BLINDNESS. INHAL: LARGE AMOUNTS MAY IRRITATE NOSE, THROAT AND RESP TRACT. MAY CAUSE CNS DEPRESSION, DIZZINESS, WEAKNESS, NAUSEA, HEADACHE, ANESTHESIA, COMA & DEATH. CHRONIC: OVEREXPOSURE MAY DAMAGE LIVER, KIDNEYS, PANCREAS, HEART, LUNGS AND BRAIN. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.