SIGMA CHEMICAL CO -- PHENYLMETHYLSULFONYL FLUORIDE, P7626 ======================================================= MSDS Safety Information ======================================================= FSC: 6810 MSDS Date: 03/17/1992 MSDS Num: BQRWQ LIIN: 00N037369 Product ID: PHENYLMETHYLSULFONYL FLUORIDE, P7626 MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL CO Box: 14508 City: ST LOUIS MO 63178 Info Phone Number: 800-325-3010;314-771-5750 Emergency Phone Number: 314-771-5765 Published: Y ======================================================= Contractor Summary ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST City: ST LOUIS MO 63178 Phone: 314-771-5765 ======================================================= Ingredients ======================================================= Cas: 329-98-6 RTECS #: XT8040000 Name: ALPHA-TOLUENESULFONYL FLUORIDE; (PHENYLMETHYLSULFONYL FLUORIDE) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: MAY BE FATAL IF INHALED, SWALLOWED, OR ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN. INHALATION MAY BE FATAL AS RES ULT OF SPASM, INFLAMMATION AND EDEMA OFLARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA. (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING. HIGHLY TOXIC CHOLINESTERASE INHIBITOR. EXPOSURE CAN CA USE NEUROTOXIC EFFECTS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: IMMED FLUSH WITH COPIOUS AMTS OF WATER FOR AT LEAST 15 MINUTES. ASSURE ADEQ FLUSHING OF EYES BY SEPARATING EYELIDS WITH FINGERS. SKIN: IMMED FLUSH WITH COPIOUS AMTS OF WATER FOR AT LEAST 15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. INGEST: WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. CALL PHYS. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS AND HEAVY RUBBER GLOVES. COVER WITH DRY LIME OR SODA ASH, PICK UP, KEEP IN CLOSED CONTAINER AND HOLD FOR WASTE DISPOSAL. VENTILATE AREA AND W ASH SPILL SITE AFTER MATERIAL PICKUP ISCOMPLETE. Neutralizing Agent: COVER WITH DRY LIME OR SODA ASH. Waste Disposal Methods: DISSOLVE OR MIX MATERIAL WITH COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS (FP N). Handling And Storage Precautions: KEEP TIGHTLY CLOSED. MOISTURE SENSITIVE. STORE IN A COOL DRY PLACE. Other Precautions: HIGHLY TOX. CORR. CHOLINESTERASE INHIBITOR. CAUSES BURNS. DO NOT BRTH DUST.DO NOT GET IN EYES, ON SKIN, ON CLTHG.AVOID PRLNGD/RPTD EXPOS.TOX BY INHAL,IN CONT W/SKIN & IF SWALLOWED. CONT W/WATER LIBERA TES HIGHLY FLAM GASES. IF YOU (SUPDAT) ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: DO NOT USE WATER. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: EMITS TOX FUMES UNDER FIRE CONDITIONS. WATER HYDROLYZES MATL LIBERATING ACIDIC GAS WHICH IN CONT W/METAL SURFS CAN GENERATE FLAMMABLE &/OR EXPLO HYDROGEN GAS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves: CHEMICAL-RESISTANT GLOVES. Eye Protection: CHEM WORK GOG W/FULL LGTH FCESHLD (FP N) Other Protective Equipment: OTHER PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE BATH. Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health: OTHER PRECAUTIONS: FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW LABEL WHERE POSSIBLE). ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: >198F,>92C Appearance and Odor: WHITE CRYSTALLINE POWDER. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: MOISTURE. Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG BASES. Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, SULFUR OXIDES, HYDROGEN FLUORIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Responsible Party Cage: 21076 Trans ID NO: 41604 Product ID: PHENYLMETHYLSULFONYL FLUORIDE, P7626 MSDS Prepared Date: 03/17/1992 Review Date: 09/09/1998 MFN: 1 Multiple KIT Number: 0 Review IND: Y Additional Data: * * THIS ITEM DELETED BECAUSE OF ERRONEOUS DATA * * ======================================================= Detail DOT Information ======================================================= DOT PSN Code: LVL DOT Proper Shipping Name: POISONOUS SOLIDS, N.O.S. Hazard Class: 6.1 UN ID Num: UN2811 DOT Packaging Group: II Label: POISON Packaging Exception: NONE Non Bulk Pack: 211 Bulk Pack: 242 Max Qty Pass: 25 KG Max Qty Cargo: 100 KG Vessel Stow Req: B ======================================================= Detail IMO Information ======================================================= IMO PSN Code: LYT IMO Proper Shipping Name: POISONOUS SOLIDS, N.O.S. IMDG Page Number: 6236 UN Number: 2811 UN Hazard Class: 6.1 IMO Packaging Group: I/II/III Subsidiary Risk Label: - EMS Number: 6.1-04 MED First Aid Guide NUM: ** ======================================================= Detail IATA Information ======================================================= IATA PSN Code: UKE IATA UN ID Num: 2811 IATA Proper Shipping Name: POISONOUS SOLID, N.O.S. IATA PSN Modifier: * IATA UN Class: 6.1 IATA Label: POISON UN Packing Group: II Packing Note Passenger: 613 Max Quant Pass: 25KG Max Quant Cargo: 100KG Packaging Note Cargo: 615 Exceptions: A5 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: UKE AFI Proper Shipping Name: POISONOUS SOLIDS, N.O.S. AFI Hazard Class: 6.1 AFI UN ID NUM: UN2811 AFI Packing Group: II AFI Label: POISON Back Pack Reference: A10.6 ======================================================= HAZCOM Label ======================================================= Product ID: PHENYLMETHYLSULFONYL FLUORIDE, P7626 Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY Street: 3050 SPRUCE ST City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 314-771-5765 Label Required IND: Y Date Of Label Review: 12/09/1992 Status Code: C Label Date: 12/09/1992 Origination Code: G Chronic Hazard IND: Y Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Severe Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: MAY BE FATAL IF INHALED, SWALLOWED, OR ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN. INHALATION MAY BE FATAL AS RESULT OF SPASM, INFLAMMATION AND EDEMA OF LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA. SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNE SS OF BREATH, HEADACHE, NAUSEA AND VOMITING. HIGHLY TOXIC CHOLINESTERASE INHIBITOR. EXPOSURE CAN CAUSE NEUROTOXIC EFFECTS. DO NOT BRTH DUST. DO NOT GET IN EYES, ON SKIN OR CLOTHING. WASH THOROUGHLY AF TER HANDLING. CHRONIC: CAN CAUSE TISSUE DAMAGE. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.