SIGMA CHEMICAL CO -- 3-AMINOPROPYLTRIETHOXYSILANE, A3648 ======================================================= MSDS Safety Information ======================================================= FSC: 6810 MSDS Date: 07/22/1993 MSDS Num: BWYTW LIIN: 00N057737 Product ID: 3-AMINOPROPYLTRIETHOXYSILANE, A3648 MFN: 01 Responsible Party Cage: 21076 Name: SIGMA CHEMICAL CO Address: 3050 SPRUCE ST City: ST PAUL MO 63103 Info Phone Number: 314-771-5765 Emergency Phone Number: 800-325-3010 Published: Y ======================================================= Contractor Summary ======================================================= Cage: 21076 Name: SIGMA CHEMICAL COMPANY Address: 3050 SPRUCE ST Box: 14508 City: ST LOUIS MO 63178 Phone: 314-771-5765 ======================================================= Ingredients ======================================================= Cas: 919-30-2 RTECS #: TX2100000 Name: 1-PROPANAMINE,3-(TRIETHOXYSILYL)-;(3-AMINOPROPYLTRIETHOXYSILANE) OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50: (ORAL,RAT) 1780 MG/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: MATL IS EXTREMELY DESTRUCTIVE TO TISS OF MUC MEMBS & UPPER RESP TRACT, EYES & SKIN. INHAL MAY BE FATAL AS RSLT OF SPASM, INFLAMM & EDEMA OF LARYNX & BRONCHI, CHEM PNEUM & PULM EDEMA. SYMPS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HDCH, NAUS & VOMIT(EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL & TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. HARMFUL IF INHALED OR SWALLOWED. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYE/SKIN: FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMD CLTHG & SHOES. ASSURE ADEQUATE FLUSHING OF EYES BY SEPARATING EYELIDS W/FINGERS. INHAL: REMOVE TO FRESH AIR. IF N OT BREATHING GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE O*2. INGEST: WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONS. CALL MD. WASH CONTAMD CLTHG BEFORE REUSE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR NIOSH/MSHA APPRVD SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. ABSORB ON SAND/VERMICULITE & PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENT AREA & WASH SPILL SITE AFTER MATL PICKUP IS COMPLETE. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISSOLVE OR MIX THE MATERIAL W/COMBUSTIBLE SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER. OBSERVE ALL LOCAL, STATE & FEDERAL REGULATIONS (FP N). Handling And Storage Precautions: KEEP TIGHTLY CLSD. MOISTURE SENSITIVE. STORE IN COOL DRY PLACE. DO NOT BRTH VAP. DO NOT GET IN EYES, ON SKIN, ON CLTHG. AVOID PLNGD/RPTD EXPOS. Other Precautions: CORROSIVE. MAY BE READILY ABSORBED THROUGH SKIN. CAUSES BURNS. HARMFUL BY INHAL & INGEST. WATER & ACIDS REACT W/MATL TO LIBERATE ETHANOL. HEAT OF RXN MAY IGNIT VAPORS OF THE ALCOHOL. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 220F,104C Lower Limits: 0.8% Upper Limits: 4.5% Extinguishing Media: DO NOT USE WATER. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT(FP N). Unusual Fire/Explosion Hazard: UNDER FIRE CNDTNS, MATL MAY DECOMPOSE TO FORM FLAMMABLE &/EXPLOSIVE MIXTURES IN AIR. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves: CHEMICAL RESISTANT GLOVES. Eye Protection: ANSI APPRVD FCSHLD(8-INCH MINIMUM)(FP N) Other Protective Equipment: EYEWASH FOUNTAIN & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 423F,217C Vapor Pres: <10 @ 100C Vapor Density: 7.7 Spec Gravity: 0.942 Appearance and Odor: COLORLESS LIQUID. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: MAY DECOMPOSE ON EXPOSURE TO MOIST AIR OR WATER. Materials To Avoid: STRONG OXIDIZING AGENTS. ACIDS. Hazardous Decomposition Products: THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, AND NITROGEN OXIDES. SILICON OXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 3-AMINOPROPYLTRIETHOXYSILANE, A3648 Cage: 21076 Company Name: SIGMA CHEMICAL COMPANY Street: 3050 SPRUCE ST PO Box: 14508 City: ST LOUIS MO Zipcode: 63178 Health Emergency Phone: 800-325-3010 Label Required IND: Y Date Of Label Review: 03/14/1995 Status Code: C Label Date: 03/14/1995 Origination Code: G Chronic Hazard IND: Y Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Health Hazard: Moderate Contact Hazard: Severe Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE: MATL IS EXTREMELY DESTRUCTIVE TO TISS OF MUC MEMBS & UPPER RESP TRACT, EYES & SKIN. INHAL MAY BE FATAL AS RSLT OF SPASM, INFLAMM & EDEMA OF LARYNX & BRONCHI, CHEM PNEUM & PULM EDEM A. SYMPS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HDCH, NAUS & VOMIT. TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL AND TOXICOLOGICAL PROP ERTIES HAVE NOT BEEN THOROUGHLY INVERSTIGATED. HARMFUL IF INHALED OR SWALLOWED.CHRONIC: NONE SPECIFIED BY MANUFACTURER. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.