Sikaflex® 227 (All Colors) Sika HMIS HEALTH *2 FLAMMABILITY 1 REACTIVITY 0 PERSONAL PROTECTION C 1. PRODUCT AND COMPANY IDENTIFICATION Supplier Manufacturer Imperial Supplies LLC Sika Corporation PO BOX 11008 30800 Stephenson Highway Green Bay, WI 54307 Madison Heights, MI 48071 U.S.A. Company Contact: Customer Service Company Contact: EHS Department Telephone Number: 800-558-2808 Telephone Number: 201-933-8800 FAX Number: 800-553-8769 FAX Number: 201-933-9379 Web Site: www.imperialsupplies.com Web Sit: www.sikaindustry.com Supplier Emergency Contacts & Phone No. Mfg. Emergency Contacts & Phone No. CHEMTEL: 800-255-3924 CHEMTREC: 800-424-9300 INTERNATIONAL; 703-527-3887 Issue Date: 06/18/2004 Product Name: Sikaflex® 227 (All Colors) CAS Number: Not Established Chemical Family: Polyurethane Sealant MSDS Number: 3230 Product Code: 0227542 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient CAS Percent of Name Number Total Weight -------------------------------------------------------------------------------- POLYISOCYANATE PREPOLYMER Trade Secret XYLENE (MIXED ISOMERS) 1330-20-7 < 4 3. HAZARDS IDENTIFICATION Eye Hazards Causes eye irritation. Skin Hazards May cause skin irritation. Prolonged and/or repeated skin contact may cause an allergic reaction/sensitization. Ingestion Hazards May be harmful if swallowed. Inhalation Hazards May cause nose, throat, and lung irritation. May cause respiratory tract irritation. Reports have associated repeated and prolonged exposure to some of the chemicals in this product with permanent brain, liver, kidney, and Central Nervous System damage.Headaches and dizziness may result. Chronic exposure to Xylene may damage a developing fetus and damage bone marrow causing a low blood count. 4. FIRST AID MEASURES Eye In case of contact, hold eyelids apart immediately flush eyes with plenty of tepid water for at least 15 minutes. Get medical attention immediately if irritation develops and persists. Skin In case of contact, immediately flush skin with soap and plenty of tepid water for at least 15 minutes. Get medical attention immediately if irritation (redness, rash, blistering) develops and persists. Ingestion If swallowed, do not induce vomiting unless directed to do so by medical personnel. If victim is fully conscious, give one or two cups of water or milk to drink. Seek medical attention immediately. Inhalation Remove to fresh air. If not breathing, give artificial respiration. 5. FIRE FIGHTING MEASURES Flash Point: 143ºF Flash Point Method: Solid per ASTM D4359 Autoignition Point: N/AV ºF Lower Explosive Limit: N/AV Upper Explosive Limit: N/AV Fire And Explosion Hazards During a fire, irritating and/or toxic gases and aerosols from the decomposition/combustion products may be present. Extinguishing Media In case of fire, use water spray (fog) foam, dry chemical, or CO2. Fire Fighting Instructions In the event of a fire, firefighters should wear full protective clothing and NIOSH-approved self-contained breathing apparatus with a full facepiece operated in the pressure demand or other positive pressure mode. 6. ACCIDENTAL RELEASE MEASURES Avoid release to the environment. Use appropriate Personal Protective Equipment (PPE). Contain spill and collect with absorbent material and transfer into suitable containers. Do not flush to sewer or allow to enter waterways. Ventilate enclosed area. 7. HANDLING AND STORAGE Handling And Storage Precautions Keep out of reach of children. Not for internal consumption. Handling Precautions Condition to 65-85F before using. If closed container is exposed to heat, pressure can build up. If moisture enters container, pressure may build up due to reaction. Storage Precautions Store at 40 - 95F. Store in cool dry area in tightly closed containers, away from sparks and open flames. Work/Hygienic Practices Wash thoroughly with soap and water after handling. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Use of a system of local and/or general exhaust is recommended to keep employee below applicable exposure limits. Refer to the current edition of "industrial Ventilation: A Manual of Recommended Practice" published by the American Conference of Governmental Industrial Hygienist for information on the design, installation, use, and maintenance of exhaust systems. Eye/Face Protection Safety glasses with side shields or goggles. Skin Protection Chemical-resistant gloves. Lab coat or other work clothing. Launder before reuse. Respiratory Protection A respirator protection program that meets 29 CFR 1910.134 requirement must be followed whenever workplace conditions warrant a respirator's use. In area where the Permissible Exposure Limits are exceeded, use a properly fitted NIOSH-approved respirator. Other/General Protection Wash thoroughly after handling. Ingredient(s) - Exposure Limits POLYISOCYANATE PREPOLYMER ACGIH TLV: NOT ESTABLISHED OSHA PEL: NOT ESTABLISHED IARC: NO NTP: NO XYLENE (MIXED ISOMERS) OSHA PEL - TWA: 100 PPM OSHA PEL - STEL: 150 PPM ACGIH TLV - TWA: 100 PPM ACGIH TLV - STEL; 150 PPM CONTAINS 15% ETHYL BENZENE 100-41-4 ETHYL BENZENE OSHA PEL/STEL 100 PPM / 125 PPM 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Paste (solid) in all colors. Odor Aromatic Odor Chemical Type: Mixture Physical State: Solid Melting Point: N/AV ºF Boiling Point: N/AV ºF Specific Gravity: 1.27 Percent VOCs: 3.85 Packing Density: 10.6 pounds/gallon Vapor Pressure: N/AV Vapor Density: > AIR Solubility: N/AV Evaporation Rate: Slower than ether VOC Content: 48.9 grams / liter 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Conditions To Avoid (Stability) Open Flame, Heat Incompatible Materials Water, Alcohols and Amines Hazardous Decomposition Products CO, CO2, NOx, Smoke, Fumes 11. TOXICOLOGICAL INFORMATION No Data Available… 12. ECOLOGICAL INFORMATION No Data Available… 13. DISPOSAL CONSIDERATIONS Dispose in accordance with applicable federal, state and local government regulations. Waste generators must determine whether a discarded material is classified as a hazardous waste. USEPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. 14. TRANSPORT INFORMATION Proper Shipping Name Not regulated by the USDOT. 15. REGULATORY INFORMATION U.S. Regulatory Information All ingredients of this product are listed or are excluded from listing under the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. SARA Hazard Classes Acute Health Hazard Chronic Health Hazard SARA Title III - Section 313 Supplier Notification This product contains the following toxic chemicals that are subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372. XYLENE (MIXED ISOMERS) (1330-20-7) <4 % This information must be included on all MSDSs that are copied and distributed for this material. Ingredient(s) - U.S. Regulatory Information XYLENE (MIXED ISOMERS) SARA Title III - Section 313 Form "R"/TRI Reportable Chemical 16. OTHER INFORMATION HMIS Rating Health: *2 Fire: 1 Reactivity: 0 PPE: C Revision/Preparer Information MSDS Preparer: EHS Department MSDS Preparer Phone Number: 201-933-8800 This MSDS Supercedes A Previous MSDS Dated: 06/14/2004 Disclaimer The data in this Material Safety Data Sheet relates only to the specific material herein and does not relate to use in combination with any other material or in any process. The information set for the herein is based on technical data that Sika believes to be reliable as of the date hereof. Since conditions of use are outside our control, we make no warranties, express or implied and assume no liability in connection with any use of this information. Nothing herein is to be taken as a license to operate under or a recommendation to infringe any patents. Sika Corporation