KEYSTONE WASH 'N WALK NO-RINSE FLOOR CLEANER
910785-01
Ecolab Co.
5105 Tomken Road
Mississauga ON L4W 2X5
1-800-352-5326
EMERGENCY HEALTH INFORMATION: 1-800-328-0026
Outside United States and Canada CALL 1-651-222-5352 (in USA)
05-February-2007
Material Safety Data Sheet
Trade name
Supplier
Code
Date of issue
Section 1. Chemical product and company identification
KEYSTONE WASH 'N WALK NO-RINSE FLOOR CLEANER
: : : :
Product use : Floor Cleaner
Section 2. Composition, information on ingredients
boric acid (h3bo3), compd. with 2-aminoethanol 26038-87-9 7 - 13
propylene glycol 57-55-6 3 - 7
glycerin 56-81-5 3 - 7
benzenesulfonic acid, 4-dodecyl-, compd. with 2-aminoethanol (1:1) 58089-99-9 3 - 7
alcohols, c12-16, ethoxylated 68551-12-2 3 - 7
xylenesulfonic acid, sodium salt 1300-72-7 1 - 5
amines, coco alkyldimethyl, n-oxides 61788-90-7 0.5 - 1.5
boric acid 10043-35-3 0.1 - 1
lipase, triacylglycerol 9001-62-1 0.1 - 1
Perfume ingredient. (melon) Mixture <1.0
Name CAS number % by weight
Emergency overview
Section 3. Hazards identification
Physical state Liquid. [Liquid.]
CAUTION!
MAY CAUSE ALLERGIC RESPIRATORY REACTION.
MAY CAUSE EYE IRRITATION.
Repeated or prolonged contact with irritants may cause dermatitis.
Avoid contact with eyes. Do not breathe vapour or mist. Keep container closed.
Use only with adequate ventilation. Wash thoroughly after handling.
: :
Routes of entry : Skin contact, Eye contact, Inhalation, Ingestion
Potential acute health effects
Slightly irritating to the respiratory system. May cause sensitisation by inhalation.
Moderately irritating to eyes.
No known significant effects or critical hazards.
Slightly irritating to the skin.
Eyes
Skin
Inhalation
Ingestion
: : : :
See toxicological information (section 11)
Do not induce vomiting. Never give anything by mouth to an unconscious person. If irritation
persists, get medical attention.
In case of contact, immediately flush eyes with cool running water. Remove contact lenses and
continue flushing with plenty of water for at least 15 minutes. Get medical attention if irritation
persists.
Flush contaminated skin with plenty of water. Wash clothing before reuse.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention.
Section 4. First-aid measures
Eye contact
Skin Contact
Inhalation
Ingestion
:
: : :
KEYSTONE WASH 'N WALK NO-RINSE FLOOR CLEANER Page: 2/5
Not available.
> 100°C
Section 5. Fire-fighting measures
Auto-ignition temperature
Flash point
Flammable limits
: :
Upper:
Lower:
Not available.
Use an extinguishing agent suitable for the surrounding fire.
Products of combustion
Fire-fighting media and
instructions
Dyke liquid for later disposal.
No specific hazard.
Special protective equipment
for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
: :
:
Risk of explosion of the product in the presence of mechanical impact: Not available.
Risk of explosion of the product in the presence of static discharge: Not available.
Not available.
Not available.
Ventilate area of leak or spill. Do not touch damaged containers or spilled material unless
wearing appropriate protective equipment (Section 8). Stop leak if without risk. Do not allow to
enter drains or watercourses.
If emergency personnel are unavailable, contain spilt material. For small spills, add absorbent
(soil may be used in the absence of other suitable materials), scoop up material and place in a
sealable, liquid-proof container for disposal. For large spills, dyke spilt material or otherwise
contain material to ensure runoff does not reach a waterway. Place spilt material in an
appropriate container for disposal.
Environmental
precautions
Section 6. Accidental release measures
: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers,
waterways, soil or air).
Personal
Precautions
:
Methods for
cleaning up
:
Keep out of the reach of children. Keep container tightly closed. Keep container in a cool, wellventilated
area.
Avoid contact with eyes. Do not breathe vapour or mist. Keep container closed. Use only with
adequate ventilation. Wash thoroughly after handling.
Section 7. Handling and storage
Handling
Storage
: :
Do not store above the following temperature: 40°C
Section 8. Exposure controls, personal protection
Name Exposure limits
Personal protection :
glycerin ACGIH TLV (United States, 1/2006).
TWA: 10 mg/m³ 8 hour(s). Form: Mist
boric acid ACGIH TLV (United States, 1/2006).
STEL: 6 mg/m³ 15 minute(s).
TWA: 2 mg/m³ 8 hour(s).
Wear appropriate respirator when ventilation is inadequate and occupational exposure limits
are exceeded.
Eye protection recommended.
No protective equipment is needed under normal use conditions.
Eyes
Skin
Respiratory
: : :
No protective equipment is needed under normal use conditions. Hands :
: Engineering measures Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits.
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Not available.
Liquid. [Liquid.]
9.1 [Conc. (% w/w): 100%]
Not available.
1.074
Not available.
Not available.
Not available.
Fragrance-like.
Green.
Boiling/condensation point
Melting/freezing point
Section 9. Physical and chemical properties
Physical state
pH
Specific gravity
Vapour pressure
Vapour density
Odour threshold
Evaporation rate
LogKow
Odour
Colour
: ::
::: ::
: ::
: Not available.
Not available.
The product is stable.
Section 10. Stability and reactivity
Stability :
Not available.
Not available.
Not available. Conditions of instability
Hazardous Decomposition
Products
: : :
Reactivity
Section 11. Toxicological information
Potential chronic health effects
Carcinogenic effects No known significant effects or critical hazards.
Mutagenic effects No known significant effects or critical hazards.
Teratogenic effects No known significant effects or critical hazards.
Toxicity data
Ingredient name Test Result Route Species
: : :
Contains material which causes damage to the following organs: kidneys, upper
respiratory tract, skin, eye, lens or cornea.
Target organs :
Potential acute health effects
Slightly irritating to the respiratory system. May cause sensitisation by inhalation.
Moderately irritating to eyes.
No known significant effects or critical hazards.
Slightly irritating to the skin.
Eyes
Skin
Inhalation
Ingestion
: : : :
Irritancy of Product : Hazardous by WHMIS criteria.
May cause sensitisation by inhalation. Sensitization to Product :
Synergistic products
(toxicologically)
:
Reproductive effects : Hazardous by WHMIS criteria.
Not available.
amines, coco alkyldimethyl, n-oxides LD50 Oral >2000 mg/kg Rat
propylene glycol LD50 Dermal 20800 mg/kg Rabbit
LD50 Oral 20 g/kg Rat
LD50 Oral 20300 mg/kg Mouse
LD50 Oral 18500 mg/kg Rabbit
LD50 Oral 18350 mg/kg Guinea pig
LDLo Oral 20000 mg/kg Rabbit
glycerin LD50 Dermal >10 g/kg Rabbit
LD50 Oral 12600 mg/kg Rat
LD50 Oral 4090 mg/kg Mouse
LD50 Oral 27 g/kg Rabbit
KEYSTONE WASH 'N WALK NO-RINSE FLOOR CLEANER Page: 4/5
Section 12. Ecological information
Ecotoxicity
Ingredient name Species Period Result
boric acid Daphnia 48 hours Acute EC50 777 mg/L
Daphnia 48 hours Acute EC50 226 mg/L
Daphnia 48 hours Acute EC50 133 mg/L
Fish 96 hours Acute LC50 >1100
mg/L
Fish 96 hours Acute LC50 >1021
mg/L
Fish 96 hours Acute LC50 >800 mg/L
amines, coco alkyldimethyl, n-oxides Daphnia 48 hours Acute EC50 8 mg/L
Daphnia 48 hours Acute EC50 4.4 mg/L
Algae 72 hours Acute EC50 <1 mg/L
Algae 72 hours Acute EC50 0.8 mg/L
Fish 96 hours Acute LC50 14 mg/L
Fish 96 hours Acute LC50 10 to 100
mg/L
propylene glycol Daphnia 48 hours Acute EC50 >10000
mg/L
Fish 96 hours Acute LC50 55770
mg/L
Fish 96 hours Acute LC50 >62000
mg/L
Fish 96 hours Acute LC50 710 mg/L
glycerin Fish 96 hours Acute LC50 54000
mg/L
The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of
spilt material and runoff and contact with soil, waterways, drains and sewers. Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements.
Waste disposal
Section 13. Disposal considerations
:
Consult your local or regional authorities.
Section 14. Transport information
Regulatory
information
UN number Proper shipping name Packing
group
Class Additional information
APPLIES ONLY DURING ROAD TRANSPORT
Any variation of the shipping description based on the packaging is not addressed.
TDG
Classification
Not
regulated.
- - - -
Section 15. Regulatory information
WHMIS Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
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Notice to reader
The above information is believed to be correct with respect to the formula used to manufacture the product
in the country of origin. As data, standards, and regulations change, and conditions of use and handling are
beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.
Date of issue
Date of previous issue
05-February-2007.
05-April-2006.
: :
Responsible name : Regulatory Affairs
Section 16. Other information